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    • 11. 发明授权
    • High molar mass polyurethane dispersions
    • 高摩尔质量的聚氨酯分散体
    • US07157519B2
    • 2007-01-02
    • US10256929
    • 2002-09-27
    • Markus A. SchafheutleAnton ArztJulius BurklMartina GlettlerGerlinde PetritschJoerg Wango
    • Markus A. SchafheutleAnton ArztJulius BurklMartina GlettlerGerlinde PetritschJoerg Wango
    • C08J3/03C08G18/10C08G18/12C08G18/34C08G18/38
    • C09D175/04C08G18/0823C08G18/12C08G18/6659C08G18/3206
    • A water-dispersible polyurethane resin comprising building blocks derived from polyisocyanates A, polyols B having a number-average molar mass Mn of at least 400 g/mol, where appropriate, low molar mass polyols C with Mn below 400 g/mol, compounds D which possess at least two groups which are reactive toward isocyanate groups and at least one group which is capable of forming anions, low molar mass polyols E which in relation to isocyanate groups carry no further reactive groups, compounds F, which are monofunctional toward isocyanates or contain active hydrogen of different reactivity and are different from the compounds E and also, where appropriate, compounds G, which are different from B, C, D, E and F and contain at least two groups which are reactive with NCO groups, wherein the number-average molar mass Mn of the polyurethane resin is at least 10 kg/mol, its weight-average molar mass Mw is at least 20 kg/mol, and its acid number is from 20 to 50 mg/g; a process for its preparation; and its use as a binder.
    • 一种水分散性聚氨酯树脂,其包含衍生自多异氰酸酯A的结构单元,数均摩尔质量M n至少为400g / mol的多元醇B,其中适当的是低摩尔质量多元醇C与M 低于400g / mol的化合物D具有至少两个对异氰酸酯基团具有反应性的基团和至少一个能够形成阴离子的基团,低摩尔质量多元醇E相对于异氰酸酯 基团不再具有反异构体的化合物F,它们对于异氰酸酯是单官能的或含有不同反应活性的活性氢,并且与化合物E不同,并且在适当的情况下也不同于B,C,D,E和 并且含有至少两个与NCO基团反应的基团,其中聚氨酯树脂的数均摩尔质量M n至少为10kg / mol,其重均摩尔质量M < 至少20kg / mol,其酸值为 m 20至50mg / g; 其准备过程; 并将其用作粘合剂。