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11. 发明授权

US4182697A Process for the preparation of boron-containing phenol-formaldehyde resins 失效
标题翻译：含硼酚醛树脂的制备方法
公开(公告)号：US4182697A
公开(公告)日：1980-01-08
申请号：US9121
申请日：1979-02-02
申请人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08G8/00 , C08G8/20 , C08G8/28 , C08L21/00 , C08G8/30 , C08G8/32
CPC分类号： C08G8/28 , C08L21/00
摘要： The invention relates to a process for the preparation of boron-containing phenol/formaldehyde resins be reacting diphenylol alkane novolaks with unsaturated fatty acids or fatty acid esters and boron compounds, characterized in that diphenylol alkane novolaks having a molecular weight of from 400 to 1600 are reacted with from 15 to 35 parts by weight of an unsaturated fatty acid or its esters, accompanied by the azeotropic removal of water, and then with from 20 to 100 parts by weight of a boric acid trialkyl ester containing from 1 to 4 carbon atoms per alkyl group or with 14 to 72 parts by weight of a boric acid alkyl ester anhydride of the general formula (RO).sub.2 B--O--B--(OR).sub.2 with 1 to 4 carbon atoms per alkyl group R or with from 10 to 50 parts by weight, preferably from 15 to 20 parts by weight of boron trioxide or with from 18 to 90 parts by weight, preferably from 25 to 36 parts by weight of boric acid in the presence of a C.sub.1 -C.sub.4 alcohol.
摘要翻译：本发明涉及一种制备含硼酚醛树脂的方法，是使二羟甲基烷烃酚醛清漆与不饱和脂肪酸或脂肪酸酯和硼化合物反应，其特征在于分子量为400至1600的二羟甲基烷烃酚醛清漆是与15至35重量份的不饱和脂肪酸或其酯反应，伴随着共沸除去水，然后与20至100重量份含有1至4个碳原子的硼酸三烷基酯或具有14至72重量份的通式（RO）2 BOB-（OR）2的硼酸烷基酯酸酐，每个烷基R为1至4个碳原子或10至50重量份，优选15至20重量份的三氧化硼或18至90重量份，优选25至36重量份的硼酸，在C1-C4醇的存在下。

12. 发明授权

US4170587A Statistical mixtures of halogenated bisphenols with halogen-free bisphenols, a process for their preparation and their use for the preparation of high-molecular weight thermoplastic polycarbonates 失效
标题翻译：卤化双酚与无卤双酚的统计混合物，其制备方法及其用于制备高分子量热塑性聚碳酸酯
公开(公告)号：US4170587A
公开(公告)日：1979-10-09
申请号：US849278
申请日：1977-11-07
申请人： Manfred Schmidt , Dieter Freitag , Werner Nouvertne
发明人： Manfred Schmidt , Dieter Freitag , Werner Nouvertne
IPC分类号： C07C43/295 , C08G59/30 , C08G63/682 , C08G64/08 , C08L69/00 , C08K7/14
CPC分类号： C08L69/00 , C07C43/295 , C08G59/30 , C08G63/682 , C08G64/08 , Y10S260/24
摘要： The invention relates to statistical mixtures of halogenated bisphenols with halogen-free bisphenols and to processes for their preparation. This invention further relates to new aromatic, bromine-containing and/or chlorine-containing, high-molecular weight thermoplastic polycarbonates with good resistance to fire (oxygen index .gtoreq. 36%) and good flow properties, to their preparation from the statistical mixtures of halogenated bisphenols and halogen-free bisphenols and to their use alone or as a mixture with halogen-free polycarbonates or with thermoplastic polyesters for the preparation of moldings, films and fibers.
摘要翻译：本发明涉及卤化双酚与无卤双酚的统计混合物及其制备方法。本发明还涉及具有良好耐火性（氧指数≥36％）和良好流动性的新的含芳族，含溴和/或含氯的高分子量热塑性聚碳酸酯从其统计混合物制备的卤化双酚和无卤双酚，并且它们单独使用或作为与无卤聚碳酸酯或与热塑性聚酯的混合物用于制备模制品，膜和纤维。

13. 发明授权

US4260704A Resins based on novolaks, their production and their use as tackifiers 失效
标题翻译：基于酚醛清漆的树脂，其生产和作为增粘剂的用途
公开(公告)号：US4260704A
公开(公告)日：1981-04-07
申请号：US949417
申请日：1978-10-10
申请人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Theo Kemperman , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/04 , C08G8/12 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L61/12 , C08L101/00 , C08G8/28 , C08L61/14
CPC分类号： C08L21/00 , C08G8/04 , C08L61/12
摘要： Resins having a softening point of from 50.degree. to 130.degree. C., an OH-number of from 250 to 400 and an iodine number of from 90 to 160, obtainable by reacting an alkyl phenol-formaldehyde novolak or an alkyl phenol mixture-formaldehyde novolak under acid-catalysed conditions with a polunuclear phenol or polynuclear phenol mixture and formaldehyde and/or an aliphatic aldehyde or aliphatic aldehyde mixture, the ratio by weight of the alkyl phenol or alkyl phenol mixture to the polynuclear phenol or polynyclear phenol mixture being from 2.2:1 to 1:10.
摘要翻译：软化点为50〜130℃，OH值为250〜400，碘值为90〜160的树脂，可通过使烷基酚 - 甲醛酚醛清漆或烷基苯酚混合物 - 甲醛酚醛清漆在酸催化条件下用聚核苯酚或多核酚混合物和甲醛和/或脂族醛或脂族醛混合物，烷基苯酚或烷基苯酚混合物与多核苯酚或多环苯酚混合物的重量比为2.2 1：1:10。

14. 发明授权

US4073757A Hardenable, boron-containing reinforcing resins for rubber 失效
标题翻译：用于橡胶的可固化的含硼增强树脂
公开(公告)号：US4073757A
公开(公告)日：1978-02-14
申请号：US749456
申请日：1976-12-10
申请人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
发明人： Manfred Schmidt , Dieter Freitag , Hermann Fries , Erich Esch
IPC分类号： C08L7/00 , C08G8/00 , C08G8/20 , C08G8/28 , C08G79/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08C4/00 , C08G8/32
CPC分类号： C08G8/28 , C08L21/00
摘要： Boron-containing resins suitable for reinforcing rubber are obtained by reacting diphenylol alkane novolaks with boron compounds and unsaturated fatty acids or fatty acid esters.
摘要翻译：适用于增强橡胶的含硼树脂通过二羟甲基烷烃酚醛清漆与硼化合物和不饱和脂肪酸或脂肪酸酯反应获得。

15. 发明授权

US5269887A Process for the purification of bisphenols 失效
标题翻译：双酚纯化方法
公开(公告)号：US5269887A
公开(公告)日：1993-12-14
申请号：US833105
申请日：1992-02-10
申请人： Wolfgang Jakob , Manfred Schmidt , Dieter Freitag , Klaus D. Berg
发明人： Wolfgang Jakob , Manfred Schmidt , Dieter Freitag , Klaus D. Berg
IPC分类号： C07C37/74 , C07C37/84 , C07C39/16 , B01D3/10
CPC分类号： C07C37/74
摘要： A process for the purification of bisphenols by distillation.
摘要翻译：通过蒸馏纯化双酚的方法。

16. 发明授权

US4668720A Flame resistant moulding compounds based on styrene polymers 失效
标题翻译：基于苯乙烯聚合物的阻燃模塑料
公开(公告)号：US4668720A
公开(公告)日：1987-05-26
申请号：US762946
申请日：1985-08-06
申请人： Hermann Kauth , Hubert Bosshammer , Manfred Schmidt , Dieter Freitag
发明人： Hermann Kauth , Hubert Bosshammer , Manfred Schmidt , Dieter Freitag
IPC分类号： C08L25/00 , C08K5/00 , C08K5/49 , C08K5/51 , C08K5/5399 , C08L7/00 , C08L21/00 , C08L25/04 , C08L25/06 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L85/00 , C08K5/34
CPC分类号： C08K5/0066 , C08K5/5399 , C08L25/04 , C08L2201/02 , C08L85/00
摘要： This invention relates to flame resistant moulding compounds produced from mixtures of styrene polymers halogenated organic compounds, special polyphosphonic acid amides and optionally conventional additives.
摘要翻译：本发明涉及由苯乙烯聚合物卤化有机化合物，特殊聚膦酸酰胺和任选的常规添加剂的混合物制备的阻燃模塑料。

17. 发明授权

US4508890A Process for the preparation of thermoplastic aromatic polyphosphonatocarbonates with improved heat-aging resistance, and their use 失效
标题翻译：具有改善耐热老化性的热塑性芳族聚碳酸亚烃酯的制备方法及其用途
公开(公告)号：US4508890A
公开(公告)日：1985-04-02
申请号：US493793
申请日：1983-05-12
申请人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag
发明人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag
IPC分类号： C08G63/00 , C08G64/00 , C08G79/04 , C08G63/62
CPC分类号： C08G64/00 , C08G79/04
摘要： Thermoplastic polyphosphonatocarbonates prepared by polycondensing at least one aromatic dihydroxy compound with a diaryl carbonate and a phosphonic acid diaryl ester in the presence of a catalyst selected from the group consisting of (a) tetra-C.sub.1 -C.sub.18 -alkyl titanates, (b) di-C.sub.2 -C.sub.4 -alkyl-tin oxides, (c) di-C.sub.2 -C.sub.4 -alkyl-di-C.sub.1 -C.sub.4 -alkoxy-tin compounds, (d) tetra-C.sub.3 -C.sub.18 -alkyl zirconates, (e) tri-C.sub.2 -C.sub.18 -alkyl vanadylates and (f) mixtures of germanium dioxide or titanium dioxide and at least one of (a) to (e) in a weight ratio of 1:3 to 3:1 at a temperature of from 80.degree.-340.degree. C. and under a pressure of 600 to 0.1 mm Hg in an inert gaseous atmosphere, the molar ratio of diaryl carbonate to phosphonic diaryl ester being from 5:95 to 95:5 and the molar ratio of aromatic dihydroxy compound to the sum of diaryl carbonates and phosphonic diaryl ester being from 0.91:1 to 0.99:1.
摘要翻译：在选自以下的催化剂存在下，将至少一种芳族二羟基化合物与碳酸二芳酯和膦酸二芳基酯缩聚制备的热塑性聚膦酸碳酸酯：（a）四-C1-烷基钛酸酯，（b）二 - （c）二-C2-C4-烷基 - 二-C1-C4烷氧基锡化合物，（d）四-C 3 -C 18烷基锆酸盐，（e）三-C2-烷基 - C18烷基氧钒酸酯和（f）二氧化锗或二氧化钛与至少一种（a）至（e）的混合物，重量比为1:3至3:1，温度为80-340℃ 并且在惰性气体气氛中在600至0.1mm Hg的压力下，碳酸二芳酯与膦酸二芳基酯的摩尔比为5:95至95:5，芳族二羟基化合物与碳酸二芳基酯的摩尔比和膦酸二芳基酯为0.91:1至0.99:1。

18. 发明授权

US4450249A Internal antistatic agents for polycarbonates and for polycarbonate films 失效
标题翻译：用于聚碳酸酯和聚碳酸酯膜的内部抗静电剂
公开(公告)号：US4450249A
公开(公告)日：1984-05-22
申请号：US409463
申请日：1982-08-19
申请人： Manfred Schmidt , Joachim Wank , Eckart Reese , Dieter Freitag , Klaus Wangermann , Wolfgang Cohnen
发明人： Manfred Schmidt , Joachim Wank , Eckart Reese , Dieter Freitag , Klaus Wangermann , Wolfgang Cohnen
IPC分类号： C08K3/00 , C08K5/36 , C08K5/42 , C08K5/52 , C08K5/5317 , C08L69/00
CPC分类号： C08K5/42 , C08K5/5317 , C08L69/00 , Y10S524/91 , Y10S524/912
摘要： The present invention relates to polycarbonate articles and films characterized by their antistatic properties comprising polycarbonate resin and alkali, or alkali earth, salts of specific aromatic sulfonic acids, specific aromatic phosphonic acids or aromatic partial phosphoric acid esters.
摘要翻译：本发明涉及聚碳酸酯制品和膜，其特征在于其抗静电性能包括聚碳酸酯树脂和碱，碱土金属，特定芳族磺酸的盐，特定的芳香族膦酸或芳族部分磷酸酯。

19. 发明授权

US4374971A Process for the preparation of thermoplastic aromatic polyphosphonates with improved thermal ageing resistance 失效
标题翻译：具有改善耐热老化性能的热塑性芳族聚磷酸酯的制备方法
公开(公告)号：US4374971A
公开(公告)日：1983-02-22
申请号：US201254
申请日：1980-10-27
申请人： Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch
发明人： Manfred Schmidt , Dieter Freitag , Ludwig Bottenbruch
IPC分类号： C08G79/00 , C08G79/02 , C08G79/04
CPC分类号： C08G79/04
摘要： A process for the preparation of a linear or branched-chain thermoplastic aromatic polyphosphonate having an average molecular weight (number average M.sub.n) in the range of from 11,000 to 200,000, which comprises solvent-free ester interchange of at least one diaryl phosphonate or at least one diaryl phosphonate and at least one triaryl phosphate with at least one aromatic dihydroxy compound or at least one aromatic dihydroxy compound and at least one aromatic tri- or tetra-hydroxy compound or a mixture thereof in an oxygen-free gas atmosphere at atmospheric pressure or reduced pressure, with removal of the volatile constituents by distillation, and in the presence of a catalytic quantity of an ester interchange catalyst which comprises at least one compound taken from the group, C.sub.1 -C.sub.18 tetraalkyl titanates, C.sub.2 -C.sub.4 dialkyl tin oxides, C.sub.2 -C.sub.4 -di-alkyl-C.sub.1 -C.sub.4 -dialkoxy tin compounds, C.sub.3 -C.sub.18 tetraalkyl zirconates and C.sub.2 -C.sub.18 trialkyl vanadylates, antimony or bismuth salts, C.sub.2 -C.sub.4 dialkyl stannic acid esters, C.sub.2 -C.sub.4 trialkyl stannic acid esters, or a mixture of at least one compound from the above group and germanium dioxide or titanium dioxide.
摘要翻译：一种制备平均分子量（数均Mn）在11,000至200,000范围内的直链或支链热塑性芳族聚膦酸酯的方法，其包括至少一种二芳基膦酸酯的无溶剂酯交换，或至少一种二芳基膦酸盐和至少一种磷酸三芳基酯与至少一种芳族二羟基化合物或至少一种芳族二羟基化合物和至少一种芳族三 - 或四 - 羟基化合物或其混合物在无氧气体气氛中在大气压下或通过蒸馏除去挥发性成分，并且在催化量的酯交换催化剂存在下，包含至少一种取自C1-C18四烷基钛酸酯，C2-C4二烷基锡氧化物，C2 -C 4 - 二烷基-C 1 -C 4 - 二烷氧基锡化合物，C 3 -C 18四烷基锆酸酯和C 2 -C 18三烷基钒酸盐，锑或铋盐，C 2 -C 4二烷基锡碳酸酯，C2-C4三烷基锡酸酯，或至少一种上述化合物与二氧化锗或二氧化钛的混合物。

20. 发明授权

US4331614A Aromatic polyphosphonates and a process for their production 失效
标题翻译：芳香族聚膦酸酯及其生产工艺
公开(公告)号：US4331614A
公开(公告)日：1982-05-25
申请号：US160646
申请日：1980-06-18
申请人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
发明人： Manfred Schmidt , Ludwig Bottenbruch , Dieter Freitag , Klaus Reinking , Harry Rohr , Hans-Dieter Block
IPC分类号： C08G79/00 , C08G79/02 , C08G79/04 , C07F9/40
CPC分类号： C08G79/04
摘要： Thermoplastic, branched aromatic polyphosphonates with average molecular weights (number average M.sub.n) of from 11,000 to more than 200,000, obtainable by transesterifying (a) from 97 to 100 moles of at least one diaryl phosphonate, and (b) from 0 to 3 moles of at least one triaryl phosphate--the sum of the moled of (a) and (b) being 100--with (c) from 90 to 99 moles of at least one aromatic dihydroxy compound, and (d) from 0 to 3 moles of at least one aromatic trihydroxy or tetrahydroxy compound--with the proviso that at least one of the components (b) and (d) is present in a quantity of at least 0.001 mole and that, where (b) and (d) are used, the maximum limit on the moles is 3.0.
摘要翻译：平均分子量（数均Mn）为11,000至大于200,000的热塑性支链芳族聚膦酸酯，可通过（a）97-100摩尔的至少一种二芳基膦酸酯和（b）0-3摩尔的至少一种磷酸三芳基酯，（a）和（b）的衍生物的总和为100-（c）90-99摩尔的至少一种芳族二羟基化合物，和（d）0-3摩尔的至少一种芳族三羟基或四羟基化合物 - 条件是组分（b）和（d）中的至少一种以至少0.001摩尔的量存在，并且使用（b）和（d）时，摩尔数的最大限度为3.0。

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