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    • 14. 发明专利
    • CARBOXAMIDES OF ISOXAZOLE- AND ISOTHIAZOLE-CARBOXYLIC ACIDS
    • CA2025939C
    • 2002-02-19
    • CA2025939
    • 1990-09-21
    • MAYWALD VOLKERFREUND WOLFGANGHAMPRECHT GERHARDKUEKENHOEHNER THOMASPLATH PETERWUERZER BRUNOWESTPHALEN KARL-OTTO
    • MAYWALD VOLKERFREUND WOLFGANGHAMPRECHT GERHARDKUEKENHOEHNER THOMASPLATH PETERWUERZER BRUNOWESTPHALEN KARL-OTTO
    • A01N43/80C07D261/18C07D275/02C07D275/03C07D413/04C07D413/12C07D413/14C07D417/04C07D417/12C07D417/14C07D413/06C07D417/06
    • Carboxamides Ia, Ib, Ic and Id (X = 0, S; R1 = H, halogen, substituted or unsubstituted alkyl, substi- tuted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkyl- thio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl- substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R1' - cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R2 = CHO, 4,5-dihydrooxazol-2- yl, COYR5, CONR6R7; Y = 0, S; R5 = H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsub- stituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical contain- ing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthal- imido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y = 0: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe, ammonium and substituted ammonium, a radical -N=CR8R9 or -W-Z; R8, R9 = H, substituted or unsubstituted alkyl, substituted or unsubstituted halo- alkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R8+R9 = 4-7-membered methylene chain; W = alkylene chain, ethoxyethylen e chain, butylene, butynylene chain; Z = a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.- position of W; R6=H, alkyl, cycloalkyl; R7=H; alkyl; -C(0-alkyl)=N-H or -C(0-alkyl)=N- alkyl; R6+R7 = 4-5-membered methylene chain; R3 = H, substituted or unsub- stituted alkyl, substituted or unsubstituted cycloalkyl; R4 = H, OH, alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsub- stituted alkynyl, di-(C1-C4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, sub- stituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R3+R4 = 4-7-membered methylene chain which may be interrupted by 0, S o r N-CH3, or -(CH2) 3-CO-) and their environmentally tolerated salts. 40 The compounds Ia to Id are suitable as herbicides.
    • 16. 发明专利
    • CARBOXAMIDES OF ISOXAZOLE- AND ISOTHIAZOLE-CARBOXYLIC ACIDS
    • CA2025939A1
    • 1991-03-23
    • CA2025939
    • 1990-09-21
    • MAYWALD VOLKERFREUND WOLFGANGHAMPRECHT GERHARDKUEKENHOEHNER THOMASPLATH PETERWUERZER BRUNOWESTPHALEN KARL OTTO
    • MAYWALD VOLKERFREUND WOLFGANGHAMPRECHT GERHARDKUEKENHOEHNER THOMASPLATH PETERWUERZER BRUNOWESTPHALEN KARL-OTTO
    • A01N43/80C07D261/18C07D275/02C07D275/03C07D413/04C07D413/12C07D413/14C07D417/04C07D417/12C07D417/14C07D413/06C07D417/06
    • Carboxamides Ia, Ib, Ic and Id (X = 0, S; R1 = H, halogen, substituted or unsubstituted alkyl, substi- tuted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkyl- thio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl- substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R1' - cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R2 = CHO, 4,5-dihydrooxazol-2- yl, COYR5, CONR6R7; Y = 0, S; R5 = H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsub- stituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical contain- ing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthal- imido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y = 0: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe, ammonium and substituted ammonium, a radical -N=CR8R9 or -W-Z; R8, R9 = H, substituted or unsubstituted alkyl, substituted or unsubstituted halo- alkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R8+R9 = 4-7-membered methylene chain; W = alkylene chain, ethoxyethylen e chain, butylene, butynylene chain; Z = a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.- position of W; R6=H, alkyl, cycloalkyl; R7=H; alkyl; -C(0-alkyl)=N-H or -C(0-alkyl)=N- alkyl; R6+R7 = 4-5-membered methylene chain; R3 = H, substituted or unsub- stituted alkyl, substituted or unsubstituted cycloalkyl; R4 = H, OH, alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsub- stituted alkynyl, di-(C1-C4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, sub- stituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R3+R4 = 4-7-membered methylene chain which may be interrupted by 0, S o r N-CH3, or -(CH2) 3-CO-) and their environmentally tolerated salts. 40 The compounds Ia to Id are suitable as herbicides.
    • 20. 发明专利
    • 1,8-NAPTHALENEDICARBOXIMIDES AS ANTIDOTES
    • CA2030129A1
    • 1991-05-30
    • CA2030129
    • 1990-11-16
    • SAUPE THOMASMEYER NORBERTPLATH PETERSCHIRMER ULRICHWUERZER BRUNOWESTPHALEN KARL OTTOPATSCH MANFREDPFISTER JUERGEN
    • SAUPE THOMASMEYER NORBERTPLATH PETERSCHIRMER ULRICHWUERZER BRUNOWESTPHALEN KARL-OTTOPATSCH MANFREDPFISTER JUERGEN
    • A01N25/32A01N39/02A01N39/04A01N43/42C07D221/14C07D401/12C07D405/12C07D409/12C07D471/06
    • 1,8-Naphthalanedicarbox-imides of the formula Ia I where R1 to R4 are each H, halogen, OH, SH, CN, SCN, NO2, alkyl which may be halogenated, alkenyl, alkynyl, cycloalkyl, cycloalkoxy, NH2, alkylamino, dialkylamino, aminoalkyl, alkylaminoalkyl, dialkylaminoalkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, COOH, hydroxycarbonylalkyl, hydroxycarbonylalkoxy, hydroxycarbonylalkylthio, SO3H, alkylsulfinyl, alkylsulfonyl, alkoxysulfonyl, SO2NH2, alkylaminosulfonyl, dialkylaminosulfonyl, unsubstituted or substituted NHNH2, C6H5, phenylalkyl, naphthyl, naphthylalkyl, hetaryl, hetarylalkyl, phenoxy, naphthyloxy, phenylthio, naphthylthio, phenoxycarbonyl, naphthyloxycarbonyl, phenylcarbonyl, naphthylcarbonyl, phenylcarbonyloxy, naphthylcarbonyloxy, phenylalkoxy, naphthylalkoxy, hetarylalkoxy, phenylsulfinyl, naphthylsulfinyl, hetarylsulfinyl, phenylsulfonyl, naphthylsulfonyl, hetarylsulfonyl, phenoxysulfonyl, naphthyloxysulfonyl or hetaryloxysulfonyl, where all aryl moieties may carry further substituents; X is an unsubstituted or substituted alkylene chain; R5 is H, CN, alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, alkoxyoarbonyl, acetyl, cycloalkyl, benzoyl, naphthoyl, hetaroyl, C6H5, naphthyl, phenylalkyl, naphthylalkyl, hetaryl or hetarylalkyl, where the aryl moieties of the six last-mentioned radicals may carry further substituents; R6 is H, CN, alkyl which may be halogenated, alkoxy, alkoxyalkyl, diazolylmethyl, triazolylmethyl, alkoxycarbonyl, furyl, tetrahydrofuryl, thienyl, tetrahydropyranyl, tetrahydrothiopyranyl, dihydropyranyl or dihydrothiopyranyl; R6 is C6H5 if R5 is H, CH3 or CH3CO; R5 and R6, together with the common carbon atom, form a cycloalkyl radical or an unsubstituted or substituted 5-membered or 6-membered ring which may be unsaturated and may contain O or S as hetero atoms, and Y and Z are each O and S, with the exception of compounds in which R3 and R4 are simultaneously H, and, where R1 to R4 are each an acidic group, the planttolerated salts of Ia, and herbicides which contain the 2-(4-hetaryloxy)- or 2-(4-aryloxy)-phenoxyacetic acid or -propionic acid derivatives and/or cyclohexenone derivatives as herbicidal active ingredients and 1,8naphthalenedicarboximides Ia and/or Ib Ib where R7 is an organic radical and may have different meanings, and/or Ic Ic and, in the case of acidic terminal groups, the planttolerated salts of Ia and/or Ib and/or Ic as antidotes.