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    • 17. 发明授权
    • Partially neutralized polyhydroxy acids for well treatments
    • 部分中和的多羟基酸进行良好的处理
    • US07981845B2
    • 2011-07-19
    • US12541311
    • 2009-08-14
    • Mathew M. SamuelBalkrishna GadiyarSai Aung Zaw Min
    • Mathew M. SamuelBalkrishna GadiyarSai Aung Zaw Min
    • C09K8/60E21B43/16
    • C09K8/68C09K8/12C09K8/487C09K8/508C09K8/512C09K8/685C09K8/88C09K8/887
    • This relates to a method and composition for forming and utilizing a fluid in the oilfield services industry including exposing a polyacid and/or polyacid derivative to a preparation method, introducing the prepared polyacid and/or polyacid derivative to a fluid to form a treatment fluid, and treating a subterranean formation and/or a wellbore with the treatment fluid, wherein the viscosity of the treatment fluid is not observably reduced by introducing the prepared polyacid and/or polyacid derivative to a treatment fluid. This also relates to a method and composition for use in the oil field services industry including a prepared polyacid and/or polyacid derivative, a fluid, and a viscosity control agent, wherein the viscosity of the composition is not observably lower than if the prepared polyacid and/or polyacid derivative were not present.
    • 这涉及用于在油田服务业中形成和利用流体的方法和组合物,包括将多酸和/或多元酸衍生物暴露于制备方法,将制备的多元酸和/或多元酸衍生物引入流体中以形成处理流体, 以及用所述处理流体处理地下地层和/或井眼,其中通过将制备的多元酸和/或多元酸衍生物引入到处理流体中,所述处理流体的粘度不可观察地降低。 这也涉及用于油田服务行业的方法和组合物,包括制备的多元酸和/或多酸衍生物,流体和粘度控制剂,其中组合物的粘度不可观察地低于制备的多元酸 和/或多酸衍生物不存在。
    • 18. 发明授权
    • Methods of perforation using viscoelastic surfactant fluids and associated compositions
    • 使用粘弹性表面活性剂流体和相关组合物穿孔的方法
    • US07878246B2
    • 2011-02-01
    • US12323675
    • 2008-11-26
    • Mathew M. SamuelYerik BalabatyrovFrank F. ChangMartin GriffithLiz Morris
    • Mathew M. SamuelYerik BalabatyrovFrank F. ChangMartin GriffithLiz Morris
    • E21B43/25
    • E21B43/1195C09K8/64C09K8/68C09K8/72C09K2208/30
    • The invention provides a method for perforating a well with a perforating fluid comprising a viscoelastic surfactant that essentially stops fluid leak-off after perforation in an overbalanced condition. Another aspect of the invention provides the perforating fluid in itself. The well has a wellbore defined by a generally cylindrical casing in at least a portion of the wellbore (i.e., the wellbore is cased, although it is not necessary cased in its entire length). The wellbore passes through a subterranean formation that comprises hydrocarbon formation fluids (such as oil and/or gas), at least in certain strata. The method comprises placing a perforating device in a wellbore which includes at least one explosive perforating charge that can be detonated in order to perforate the casing and allow the formation fluids to enter the wellbore. The casing is located between the subterranean formation and the perforating device. A perforating fluid including at least one viscoelastic surfactant is placed in the wellbore between the perforating device and the casing, in at least a portion of the wellbore. In other words, the perforating fluid is present in the wellbore adjacent to the perforating device. The explosive charge(s) in the perforating device is detonated, such that the perforating device forms at least one perforation in the casing that permits the flow of hydrocarbon formation fluids from the subterranean formation into the wellbore. As a result of the detonation, at least a portion of the perforating fluid is put in communication with the subterranean formation.
    • 本发明提供了一种用穿孔流体穿孔的方法,该穿孔流体包括粘弹性表面活性剂,其基本上在过平衡状态下穿孔后阻止流体泄漏。 本发明的另一方面本身提供穿孔流体。 井具有在井眼的至少一部分中的大致圆柱形的壳体限定的井筒(即,井眼套管,尽管不需要在其整个长度上套管)。 至少在某些地层中,井眼穿过包含烃地层流体(如油和/或气)的地下地层。 该方法包括将穿孔装置放置在井眼中,其包括至少一个可爆炸的爆炸穿孔装置,以便使壳体穿孔并允许地层流体进入井筒。 套管位于地层和穿孔装置之间。 包括至少一种粘弹性表面活性剂的穿孔流体在井眼的至少一部分中放置在穿孔装置和壳体之间的井筒中。 换句话说,穿孔流体存在于与穿孔装置相邻的井眼中。 穿孔装置中的爆炸装料被引爆,使得穿孔装置在壳体中形成至少一个穿孔,其允许烃地层流体从地层将流体流入井眼。 作为爆炸的结果,穿孔流体的至少一部分与地下地层连通。
    • 19. 发明申请
    • METAL FREE CROSSLINKING OF GALACTOMANNAN
    • 金属矿物的金属免费交联
    • US20100056403A1
    • 2010-03-04
    • US12539243
    • 2009-08-11
    • Carlos AbadMathew M. SamuelKevin W. England
    • Carlos AbadMathew M. SamuelKevin W. England
    • C09K8/68
    • C09K8/685C08B15/005C08B15/02C08B37/0096C08J3/24C08L5/00C09K8/887C09K8/90
    • Methods of treating a subterranean formation are disclosed, using a fluid including an essentially metal-free organic crosslinker selected from amines, diamines, poly amines, polyamino polymers, alcohols, polyols, polyhydroxy polymers, hydroxyl amines, peptides and proteins, combined with a polysaccharide or cellulosic material having oxidized functional groups. The fluid is then introduced into a wellbore penetrating the formation to contact the formation. The polysaccharide or cellulosic material may have aldehyde groups as one example of an oxidized group, or any other suitable oxidized functional group. The polysaccharide or the cellulosic material may be oxidized using at least one of an enzymes, oxidizers, photooxidation, bacteria, catalyst, or other suitable technique. The fluid may also further include an inorganic crosslinker.
    • 公开了使用包含基本上不含金属的有机交联剂的流体的方法,该有机交联剂选自胺,二胺,聚胺,聚氨基聚合物,醇,多元醇,多羟基聚合物,羟胺,肽和蛋白质,与多糖组合 或具有氧化官能团的纤维素材料。 然后将流体引入穿透地层的井筒中以接触地层。 多糖或纤维素材料可以具有作为氧化基团或任何其它合适的氧化官能团的一个实例的醛基。 多糖或纤维素材料可以使用酶,氧化剂,光氧化,细菌,催化剂或其它合适的技术中的至少一种来氧化。 流体还可以进一步包括无机交联剂。