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11. 发明申请

US20070225395A1 Thermally stable cationic photocurable compositions 审中-公开
标题翻译：耐热稳定的阳离子光固化组合物
公开(公告)号：US20070225395A1
公开(公告)日：2007-09-27
申请号：US11803274
申请日：2007-05-14
申请人： Jean-Pierre Wolf , Stephen Ilg , Jean-Luc Birbaum , Eugene Sitzman , David Bramer , Greg Losapio
发明人： Jean-Pierre Wolf , Stephen Ilg , Jean-Luc Birbaum , Eugene Sitzman , David Bramer , Greg Losapio
IPC分类号： C08F2/46
CPC分类号： G03F7/0037 , C08G59/18 , C08G59/24 , C08G59/68 , G03F7/038
摘要： Disclosed are cationic photocurable compositions with improved shelf life stability. The thermally stable compositions comprise at least one cationically polymerizable compound, for example an epoxy compound, at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers. Also disclosed is a cationic photoinitiator composition comprising at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers.
摘要翻译：公开了具有改善的保质期稳定性的阳离子光固化组合物。热稳定组合物包含至少一种阳离子可聚合化合物，例如环氧化合物，至少一种鎓盐光引发剂和至少一种选自有机磷稳定剂和受阻硝酰基稳定剂的化合物。还公开了包含至少一种鎓盐光引发剂和至少一种选自有机磷稳定剂和受阻硝酰基稳定剂的化合物的阳离子光引发剂组合物。

12. 发明授权

US6004724A Oxime sulfonates and the use thereof as latent sulfonic acids 失效
标题翻译：肟磺酸盐及其作为潜在磺酸的用途
公开(公告)号：US6004724A
公开(公告)日：1999-12-21
申请号：US104676
申请日：1998-06-25
申请人： Hitoshi Yamato , Hartmut Bleier , Jean-Luc Birbaum , Martin Kunz , Kurt Dietliker , Christoph De Leo , Toshikage Asakura
发明人： Hitoshi Yamato , Hartmut Bleier , Jean-Luc Birbaum , Martin Kunz , Kurt Dietliker , Christoph De Leo , Toshikage Asakura
IPC分类号： C07C309/65 , C07C309/66 , C07C309/73 , C07C323/63 , C07C381/00 , C07D207/44 , C07D213/90 , C07D333/34 , C07D333/36 , C07D333/44 , G03F7/004 , G03C1/725 , C07C249/04 , C07C251/32 , G03C1/72
CPC分类号： C07D207/44 , C07C309/65 , C07C309/66 , C07C309/73 , C07C323/63 , C07C381/00 , C07D213/90 , C07D333/44 , G03F7/0045 , Y10S430/114 , Y10S430/117 , Y10S430/12 , Y10S430/122
摘要： New oximsulfonate compounds of the formulae I or II, ##STR1## wherein m is 0 or 1; x is 1 or 2; R.sub.1 is, for example phenyl, which is unsubstituted or substituted or R.sub.1 is a heteroaryl radical that is unsubstituted or substituted, or, if m is 0, R.sub.1 additionally is C.sub.2 -C.sub.6 alkoxycarbonyl, phenoxycarbonyl or CN; R'.sub.1 is for example C.sub.2 -C.sub.12 alkylene, phenylene; R.sub.2 has for example one of the meanings of R.sub.1 ; n is 1 or 2; R.sub.3 is for example C.sub.1 -C.sub.18 alkyl, R'.sub.3 when x is 1, has one of the meanings given for R.sub.3, or R'.sub.3 in the formula IV and when x is 2 in the formula 1, is for example C.sub.2 -C.sub.12 alkylene, phenylene; R.sub.4 and R.sub.5 are independently of each other for example hydrogen, halogen, C.sub.1 -C.sub.6 alkyl; R.sub.6 is for example hydrogen, phenyl; R.sub.7 and R.sub.8 are independently of each other for example hydrogen or C.sub.1 -C.sub.12 -alkyl; R.sub.9 is for example C.sub.1 -C.sub.12 alkyl; A is S, O, NR.sub.6, or a group of formula A1, A2, A3 or A4 ##STR2## R.sub.10 and R.sub.11 independently of each other have one of the meanings given for R.sub.4 ; R.sub.12, R.sub.13, R.sub.14 and R.sub.15 independently of one another are for example hydrogen, C.sub.1 -C.sub.4 alkyl; Z is CR.sub.11 or N; Z.sub.1 is --CH.sub.2 --, S, O or NR.sub.6, are useful as latent sulfonic acids, especially in photoresist applications.
摘要翻译：式I或II的新的磺酸磺酸酯化合物，其中m为0或1; x为1或2; R1是例如未取代或取代的苯基，或R1是未取代或取代的杂芳基，或者如果m是0，则R1另外是C 2 -C 6烷氧基羰基，苯氧基羰基或CN; R'1例如为C 2 -C 12亚烷基，亚苯基; R2具有例如R1的含义之一; n为1或2; R3为例如C1-C18烷基，当x为1时为R'3，具有R3给出的含义之一，或式Ⅳ中的R'3，当式Ⅺ中x为2时，为例如C 2 -C 12亚烷基，亚苯基; R4和R5彼此独立，例如氢，卤素，C1-C6烷基; R6是例如氢，苯基; R 7和R 8彼此独立地为氢或C 1 -C 12 - 烷基; R 9为例如C 1 -C 12烷基; A是S，O，NR6或式A1，A2，A3或A4的基团，R10和R11彼此独立地具有对R4给出的含义之一; R 12，R 13，R 14和R 15彼此独立地是例如氢，C 1 -C 4烷基; Z为CR11或N; Z1是-CH2-，S，O或NR6，可用作潜在的磺酸，特别是在光刻胶应用中。

13. 发明申请

US20050165141A1 Thermally stable cationic photocurable compositions 审中-公开
标题翻译：耐热稳定的阳离子光固化组合物
公开(公告)号：US20050165141A1
公开(公告)日：2005-07-28
申请号：US11040716
申请日：2005-01-21
申请人： Jean-Pierre Wolf , Stephen Ilg , Jean-Luc Birbaum , Eugene Sitzman , David Bramer , Greg Losapio
发明人： Jean-Pierre Wolf , Stephen Ilg , Jean-Luc Birbaum , Eugene Sitzman , David Bramer , Greg Losapio
IPC分类号： C08G59/18 , C08G59/68 , G03F7/00 , G03F7/038 , C08K5/34 , C08K5/49
CPC分类号： G03F7/0037 , C08G59/18 , C08G59/24 , C08G59/68 , G03F7/038
摘要： Disclosed are cationic photocurable compositions with improved shelf life stability. The thermally stable compositions comprise at least one cationically polymerizable compound, for example an epoxy compound, at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers. Also disclosed is a cationic photoinitiator composition comprising at least one onium salt photoinitiator and at least one compound selected from the group consisting of the organic phosphorus stabilizers and the hindered nitroxyl stabilizers.
摘要翻译：公开了具有改善的保质期稳定性的阳离子光固化组合物。热稳定组合物包含至少一种阳离子可聚合化合物，例如环氧化合物，至少一种鎓盐光引发剂和至少一种选自有机磷稳定剂和受阻硝酰基稳定剂的化合物。还公开了包含至少一种鎓盐光引发剂和至少一种选自有机磷稳定剂和受阻硝酰基稳定剂的化合物的阳离子光引发剂组合物。

14. 发明授权

US06306555B1 Iodonium salts as latent acid donors 有权
标题翻译：碘盐作为潜酸供体
公开(公告)号：US06306555B1
公开(公告)日：2001-10-23
申请号：US09740205
申请日：2000-12-18
申请人： Reinhard Schulz , Jean-Luc Birbaum , Jean-Pierre Wolf , Stephan Ilg , Hitoshi Yamato , Toshikage Asakura
发明人： Reinhard Schulz , Jean-Luc Birbaum , Jean-Pierre Wolf , Stephan Ilg , Hitoshi Yamato , Toshikage Asakura
IPC分类号： G03F7004
CPC分类号： G03F7/0382 , B33Y70/00 , C07C17/00 , C07C25/18 , C07C2601/14 , C08G59/68 , C08G65/105 , G03F7/0045 , G03F7/038 , G03F7/0392 , Y10S430/115
摘要： Radiation-sensitive compositions comprising (a1) a cationically or acid-catalytically polymerisable or crosslinkable compound or (a2) a compound that increases its solubility in a developer under the action of acid; and (b) at least one diaryliodonium salt of formula I X is branched C3-C20alkyl or C3-C8cycloalkyl; X1 is hydrogen, linear C1-C20alkyl, branched C3-C20alkyl or C3-C8cycloalkyl; with the proviso that the sum of the carbon atoms in X and X1 is at least 4; Y is linear C1-C10alkyl, branched C3-C10alkyl or C3-C8cycloalkyl; A− is a non-nucleophilic anion, selected from the group (BF4)−, (SbF6)−, (PF6)−, (B(C6F5))4−, C1-C20alkylsulfonate, C2-C20haloalkylsulfonate, unsubstituted C6-C10arylsulfonate, camphorsulfonate, and C6-C10arylsulfonate substituted by halogen, NO2, C1-C12alkyl, C1-C12halo-alkyl, C1-C12alkoxy or by COOR1; and R1 is C1-C20alkyl, phenyl, benzyl; or phenyl mono- or poly-substituted by C1-C12alkyl, C1-C12alkoxy or by halogen; with the proviso that the two phenyl rings on the iodine atom are not identically substituted.
摘要翻译：辐射敏感性组合物，其包含（a1）阳离子或酸可催化聚合或交联的化合物或（a2）在酸的作用下增加其在显影剂中的溶解度的化合物; 和（b）式IX的至少一种二芳基碘鎓盐是支链C 3 -C 20烷基或C 3 -C 8环烷基; X 1是氢，直链C 1 -C 20烷基，支链C 3 -C 20烷基或C 3 -C 8环烷基; 条件是X和X 1中的碳原子总数至少为4; Y为直链C 1 -C 10烷基，支链C 3 -C 10烷基或C 3 -C 8环烷基; A-为非亲核阴离子，选自（BF 4 ） - ，（SbF 6） - ，（PF 6） - ，（B（C 6 F 5））4-，C 1 -C 20烷基磺酸酯，C 2 -C 20卤代烷基磺酸酯，未取代的C 6 -C 10芳基磺酸酯，樟脑磺酸酯和C 6 -C 10芳基磺酸酯，被卤素，，C 1 -C 12卤代烷基，C 1 -C 12烷氧基或COOR 1; 并且R 1是C 1 -C 20烷基，苯基，苄基; 或被C 1 -C 12烷基，C 1 -C 12烷氧基或卤素单取代或多取代的苯基;条件是碘原子上的两个苯环不同等取代。

15. 发明授权

US08012672B2 Sulphonium salt photoinitiators 有权
标题翻译：锍盐光引发剂
公开(公告)号：US08012672B2
公开(公告)日：2011-09-06
申请号：US12442823
申请日：2007-09-24
申请人： Pascal Hayoz , Jean-Luc Birbaum , Stephan Ilg
发明人： Pascal Hayoz , Jean-Luc Birbaum , Stephan Ilg
IPC分类号： C07C381/12 , G03F7/004 , G03F7/039 , G03C1/73
CPC分类号： C07C381/12 , B33Y70/00 , B33Y80/00 , C07C2601/14 , C08K5/375 , C09D7/63 , G03F7/0045 , G03F7/038
摘要： Compounds of the formula (I), wherein L1, L2, L3 and L4 independently of one another are hydrogen or an organic substituent; R is for example C1-C20alkyl, C5-C12cycloalkyl, C2-C20alkenyl, substituted C1-C20alkyl; X is O, S, NRa or NCORa; Ra is for example hydrogen or C1-C20alkyl; and Y is an inorganic or organic anion; are suitable as photolatent acid generators.
摘要翻译：式（I）的化合物，其中L1，L2，L3和L4彼此独立地是氢或有机取代基; R是例如C 1 -C 20烷基，C 5 -C 12环烷基，C 2 -C 20烯基，取代的C 1 -C 20烷基; X为O，S，NRa或NCORa; R a是例如氢或C 1 -C 20烷基; Y为无机或有机阴离子; 适合作为光潜酸产生剂。

16. 发明授权

US06187919B1 Stabilized organic material 失效
标题翻译：稳定有机材料
公开(公告)号：US06187919B1
公开(公告)日：2001-02-13
申请号：US08591419
申请日：1996-01-19
申请人： Jean-Luc Birbaum , Jean Rody , Mario Slongo , Andreas Valet , Roland A. E. Winter
发明人： Jean-Luc Birbaum , Jean Rody , Mario Slongo , Andreas Valet , Roland A. E. Winter
IPC分类号： C07D25124
CPC分类号： C07D405/12 , C07D251/24 , C07F9/6521 , C08K5/3435 , C08K5/3492 , C08K5/34926 , C09D7/48
摘要： o-Hydroxyphenyl-s-triazines of the formula I in which n is 1 to 4 and R1 to R7 are as defined in claim 1, can be used, in combination with sterically hindered amines of the polyalkylpiperidine type, for stabilizing organic polymers. Some of these compounds ate novel and can also be used without polyalkylpiperidine.
摘要翻译： n为1至4且R 1至R 7如权利要求1所定义的式Iin的邻羟基苯基-s-三嗪可与聚烷基哌啶类型的空间位阻胺一起用于稳定有机聚合物。这些化合物中的一些具有新颖性，并且也可以不使用聚烷基哌啶来使用。

17. 发明授权

US5753729A Coating compositions stabilized against damage by light, heat, and oxygen 失效
标题翻译：涂料组合物稳定，防止光，热和氧气的损伤
公开(公告)号：US5753729A
公开(公告)日：1998-05-19
申请号：US665041
申请日：1996-06-07
申请人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
发明人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
IPC分类号： C07D239/26 , C07D401/12 , C08K5/3442 , C08K5/3462 , C08K5/3472 , C08K5/3475 , C08K5/3477 , C08K5/3492 , C09D7/12 , C09K3/00 , C08K5/3495
CPC分类号： C07D239/26 , C07D401/12 , C08K5/3462 , C09D7/1241
摘要： Coatings comprising A) a binder based on an organic polymer and B) as stabilizer against damage by light, heat and oxygen, a 2-(2'-hydroxyphenyl)-1,3-pyrimidine of the formula I ##STR1## in which the radicals R.sub.1 to R.sup.6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
摘要翻译：包含A）基于有机聚合物的粘合剂和B）作为防止光，热和氧损伤的稳定剂的式I（I）的2-（2'-羟基苯基）-1,3-嘧啶，其中基团R 1至R 6如权利要求1中所定义，具有突出的抗光，氧和热的破坏作用的抗性。权利要求18中定义的式Ib化合物通常适用于有机材料的稳定化。

18. 发明授权

US5229512A Compounds formed from o-hydroxyphenyl-1,3,5-triazines and sterically hindered amines 失效
标题翻译：由O-羟基苯基-1,3,5-三嗪和异丁醇胺形成的化合物
公开(公告)号：US5229512A
公开(公告)日：1993-07-20
申请号：US685367
申请日：1991-04-15
申请人： Mario Slongo , Jean-Luc Birbaum , Jean Rody , Andreas Valet
发明人： Mario Slongo , Jean-Luc Birbaum , Jean Rody , Andreas Valet
IPC分类号： C07D491/113 , C07D401/12 , C07D401/14 , C07D471/10 , C07D491/22 , C07D498/10 , C08K5/3477 , C08K5/3492 , C08K5/35 , C08K5/353 , C09D7/12
CPC分类号： C07D401/12 , C07D401/14 , C08K5/34926 , C09D7/1241
摘要： Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilisers for organic materials against damage by light, oxygen and heat.
摘要翻译：包含至少一种式I或II（I）的化合物（II）和至少一种式III（III）的聚烷基哌啶基团，其中R和R 1至R 6具有权利要求1中所示的含义是有机材料的有效稳定剂，以防止光，氧和热的损害。

19. 发明授权

US07381842B2 Oxime ester photoinitiators 有权
公开(公告)号：US07381842B2
公开(公告)日：2008-06-03
申请号：US11103194
申请日：2005-04-11
申请人： Kazuhiko Kunimoto , Hidetaka Oka , Masaki Ohwa , Junichi Tanabe , Hisatoshi Kura , Jean-Luc Birbaum
发明人： Kazuhiko Kunimoto , Hidetaka Oka , Masaki Ohwa , Junichi Tanabe , Hisatoshi Kura , Jean-Luc Birbaum
IPC分类号： C07C251/60
CPC分类号： C07D207/335 , A61K6/083 , B33Y70/00 , B41M3/003 , C07C251/66 , C07C251/68 , C07C317/32 , C07C323/47 , C07C327/30 , C07D209/86 , C07D333/20 , C07D335/16 , C07D339/08 , G03F7/0007 , G03F7/0045 , G03F7/031
摘要： Compounds of the formulae I, II, III, IV and V wherein R1 i.a. is C4-C9cycloalkanoyl, C1-C12alkanoyl, C4-C6alkenoyl, or benzoyl; R2 is for example phenyl, C1-C20alkyl, C3-C8cycloalkyl, C2-C20alkanoyl, or benzoyl; Ar1 is R4S-phenyl or NR5R6-phenyl, each of which optionally is substituted; or Ar1 i.a. is optionally substituted; or Ar1 is naphthyl or anthracyl each of which is unsubstituted or substituted; or Ar1 is benzoyl, naphthalenecarbonyl, phenanthrenecarbonyl, anthracenecarbonyl or pyrenecarbonyl, each of which is unsubstituted or substituted, or Ar1 is 3,4,5-trimethoxyphenyl, phenoxyphenyl or biphenyl; Ar2 i.a. is optionally substituted, or naphthyl or anthracyl, each of which is unsubstituted or substituted, x is 2 or 3; M1 when x is 2, for example is phenylene, naphthalene, anthracylene, each of which optionally is substituted; M1, when x is 3, is a trivalent radical; M2 for example is M3 is for example C1-C12alkylene, cyclohexylene, or phenylene; n is 1-20; R3 is for example hydrogen or C1-C12alkyl; R3′ i.a. is C1-C12alkyl; substituted or —O-interrupted C2-C6alkyl; R4 is for example hydrogen, or C1-C12alkyl; and R5 and R6 independently of each other i.a. are hydrogen, C1-C12alkyl, or phenyl; are suitable as photoinitiators in particular in resist applications.

20. 发明申请

US20070248782A1 High-Capacity Optical Storage Media 失效
标题翻译：大容量光存储介质
公开(公告)号：US20070248782A1
公开(公告)日：2007-10-25
申请号：US11659993
申请日：2005-07-06
申请人： Jean-Pierre Bacher , Gisele Baudin , Frederique Wendeborn , Jean-Marie Adam , Urs Lehmann , Jean-Luc Birbaum
发明人： Jean-Pierre Bacher , Gisele Baudin , Frederique Wendeborn , Jean-Marie Adam , Urs Lehmann , Jean-Luc Birbaum
IPC分类号： C09B45/34 , C09B69/02 , G11B7/24
CPC分类号： G11B7/2467 , C09B45/20 , C09B45/34 , C09B69/045 , G11B7/246 , G11B7/247 , G11B7/2472 , G11B7/2492 , G11B7/2495 , G11B7/2498 , G11B7/2531 , G11B7/2533 , G11B7/2534 , G11B7/2535 , G11B7/256 , G11B7/2575 , G11B7/259 , G11B2007/25706 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715 , G11B2007/25716
摘要： The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula preferably a compound of formula or a mesomeric or tautomeric form thereof, wherein Ah+ is an organic cation having h quaternary ammonium or phosphonium groups; Q1 is N or CR15, Q2 is N or CR16, Q3, Q5 and Q7 are each independently of the other CR17R18, O, S or NR19, Q4 is CR13 or N and Q6 is CR14 or N; and one of R1 and R3 is OR17, OR20, SR17, SR20, NR17R18, NR18R20 or NR20R21, and the other of R1 and R3 is O−, S− or N−R22. The compounds of formula (I) and (II) are novel and also claimed, as well as mixtures thereof with metal complexes. The optical recording media are remarkably suitable for DVD±R (658 nm), especially at high recording speeds.
摘要翻译：本发明涉及一种包括基底，反射层和记录层的光学记录介质，其中记录层包含式（I）化合物，优选式（I）化合物或其互变异构体或互变异构形式，其中A h + SUP>是具有h个季铵或鏻基团的有机阳离子; Q 1是N或CR 15，Q 2是N或CR 16，Q 3， Q 3，Q 5和Q 7各自独立于另一个CR 17 R 18，O， S或NR 19，Q 4是CR 13或N和Q 6是CR 14， / SUB>或N; 并且R 1和R 3中的一个是OR 17，OR 20，SR 17， 20 20，NR 17，R 18，NR 18，R 20，或NR 20 R 21，而R 1和R 3中的另一个为O - / SUP>，或或 R 22。式（I）和（II）的化合物是新的并且还要求保护的，以及它们与金属络合物的混合物。光学记录介质非常适用于DVD±R（658nm），特别是在高记录速度下。

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