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    • 11. 发明授权
    • Mass spectrometer using plasma ion source
    • 使用等离子体源的质谱仪
    • US5148021A
    • 1992-09-15
    • US630554
    • 1990-12-20
    • Yukio OkamotoSatoshi ShimuraKonosuke OishiMasataka KogaMakoto YasudaTakahashi Iino
    • Yukio OkamotoSatoshi ShimuraKonosuke OishiMasataka KogaMakoto YasudaTakahashi Iino
    • G01N27/62H01J49/06H01J49/12H01J49/26
    • H01J49/06
    • A mass spectrometer using a plasma ion source for analyzing an ultra-trace element includes a plasma generation system for generating a plasma including the composition of a sample, an ion beam formation system for extracting ions in the form of a beam from the plasma generating the ions, a mass spectrometry system for performing mass spectrometry of the ion beamn, and an ion detection system for detecting the ions subjected to the mass spectrometry, in which a lens system made up of a cylindrical first electrode, a cylindrical second electrode with a photon stopper disposed on the central axis thereof, and a cylindrical third electrode is further provided between the ion beam formation system and the mass spectrometry system. By the provision of the lens system, the ions generated in the plasma are transported more efficiently to the side of the mass spectrometry system and by the provision of the photon stopper in the above described position, it is achieved, with a simpler structure, to prevent photons from entering the ion detection system.
    • 使用等离子体离子源分析超微量元素的质谱仪包括:等离子体产生系统,用于产生包含样品组成的等离子体;离子束形成系统,用于从等离子体中提取离子的形式, 离子,用于进行离子束的质谱分析的质谱系统和用于检测进行质谱分析的离子的离子检测系统,其中由圆柱形第一电极构成的透镜系统,具有光子的圆柱形第二电极 止动件设置在其中心轴上,并且在离子束形成系统和质谱系统之间还设置有圆柱形的第三电极。 通过设置透镜系统,在等离子体中产生的离子更有效地传输到质谱系统的侧面,并且通过在上述位置提供光子停止器,以更简单的结构实现 防止光子进入离子检测系统。
    • 12. 发明授权
    • Atomic absorption spectrophotometer
    • 原子吸收分光光度计
    • US4728189A
    • 1988-03-01
    • US6170
    • 1987-01-23
    • Konosuke OishiKoichi UchinoHideo YamadaSeigo KamitakeMasao Hashimoto
    • Konosuke OishiKoichi UchinoHideo YamadaSeigo KamitakeMasao Hashimoto
    • G01N21/31G01J3/42G01N21/74
    • G01N21/3103
    • An absorption profile indicative of a relation in atomic absorption spectroscopy between the absorbance of a desired element and time has a constant half-width independent of the concentration of the desired element in a sample, and hence the half-width of absorption profile with respect to the desired element can be previously determined from data which is obtained by the measurement of a standard sample. In an atomic absorption spectrophotometer herein disclosed, the half-width of absorption profile is previously determined in the above-mentioned manner, and the true peak value of an absorption profile obtained by measuring a sample which contains the desired element at a high concentration, is calculated using the time width of this absorption profile at a predetermined absorbance and the previously-determined half-width.
    • 指示所需元素的吸光度与时间之间的原子吸收光谱中的关系的吸收曲线具有与样品中期望元素的浓度无关的恒定半宽,因此吸收曲线的半宽相对于 可以从通过测量标准样品获得的数据预先确定所需要的元素。 在本文公开的原子吸收分光光度计中,预先按照上述方式确定吸收曲线的半宽度,通过以高浓度测量含有所需元素的样品而获得的吸收曲线的真实峰值为 使用该吸收曲线的时间宽度以预定吸光度和预先确定的半宽度计算。
    • 14. 发明授权
    • Atomic absorption spectrophotometer
    • 原子吸收分光光度计
    • US4948250A
    • 1990-08-14
    • US621464
    • 1984-06-18
    • Konosuke OishiHideaki KoizumiMasataka Koga
    • Konosuke OishiHideaki KoizumiMasataka Koga
    • G01J3/42G01N21/31
    • G01N21/3103G01N2021/3111
    • In atomic absorption spectrophotometers such as Zeeman atomic absorption spectrophotometer, the present invention is characterized in that the correction timing of background absorption in sample light is made to coincide with that of reference light so as to improve the accuracy of the output signals of the spectrophotometer. To accomplish this object, the present invention constitutes a calculation processing unit for storing and calculating signals by means for separating one signal consisting of sample signals and reference signals applied thereto from amplification means for amplifiying photoelectrically converted signals into sample and reference signals, and storing them, means for calculating respectively the mean values of two time adjacent signals of one of the sample and reference signals to prepare a signal of the mean values, and means for calculating the difference of the logarithmic converted values of the signals of the other of the sample and reference signals and those of the signals of the signal of the mean values at the same points of time, and obtaining correction signals of background absorption.
    • 在诸如塞曼原子吸收分光光度计的原子吸收分光光度计中,本发明的特征在于使得样品光中的背景吸收的校正时间与参考光的校正时间一致,以提高分光光度计的输出信号的精度。 为了实现该目的,本发明构成了一种计算处理单元,用于通过用于将由采样信号和从其施加的参考信号组成的一个信号分离出来,用于存储和计算信号,该放大装置用于将光电转换的信号放大为采样和参考信号,并将它们存储 分别计算采样和参考信号之一的两个时间相邻信号的平均值以准备平均值的信号的装置,以及用于计算另一个样本的信号的对数转换值之差的装置 参考信号和相同时间点的平均值信号的信号,得到背景吸收的校正信号。
    • 16. 发明授权
    • Spectrophotometric analyzer having dual monochromators
    • 具有双色单色仪的分光光度分析仪
    • US4468121A
    • 1984-08-28
    • US361381
    • 1982-03-24
    • Hideaki KoizumiKonosuke Oishi
    • Hideaki KoizumiKonosuke Oishi
    • G01N21/27G01J3/18G01N21/25
    • G01N21/255G01J3/18
    • A spectrophotometric analyzer disclosed by this invention has two monochromators capable of operating independently of each other. In each monochromator, a light beam from a light source is made to be incident on an entrance slit, and, after dispersed and wavelength scanned, issued from an exit slit as an analyzed light beam. These analyzed light beams are detected by detectors. The entrance slits and the exit slits of the two monochromators are disposed rotation symmetrically. This can simplify the operation of switching between a series mode where the analyzed light from the exit slit of the one monochromator is made to be incident on the entrance slit of the other monochromator and a parallel mode where the both monochromators operate for detection independently from each other.
    • 本发明公开的分光光度计分析仪具有能够彼此独立操作的两个单色仪。 在每个单色仪中,来自光源的光束被入射到入口狭缝上,并且在分散和波长扫描之后,作为分析光束从出口狭缝发出。 这些分析的光束被检测器检测。 两个单色仪的入口狭缝和出口狭缝对称地设置。 这可以简化在一个单色仪的出射狭缝处分析的光被入射在另一个单色仪的入射狭缝上的串联模式之间切换的操作以及两个单色仪独立于每个单独仪进行检测的并行模式 其他。
    • 17. 发明授权
    • Spectral source, particularly for atomic absorption spectrometry
    • 光谱源,特别是原子吸收光谱
    • US4198589A
    • 1980-04-15
    • US871807
    • 1978-01-24
    • Shinji MayamaMasataka KogaYoji AraiKonosuke Oishi
    • Shinji MayamaMasataka KogaYoji AraiKonosuke Oishi
    • H01J61/66H05B41/24
    • H01J61/66
    • A spectral source comprises a lamp containing an anode and a cathode in an inert gas. The anode and cathode are different in shape and connected to a high-frequency power source to produce a high-frequency discharge between the anode and cathode to cause both sputtering of the cathode and excitation of a radiation having the spectrum according to the material sputtered from the cathode. The application of solely high-frequency power prevents adherence of the sputtered material to the interior walls of the lamp bulb thereby allowing a reduction of the dimensions of the lamp bulb, prolongating the life time of the lamp and increasing the stability and intensity of the radiation. A magnetic field may be applied to the radiation for Zeeman modulation. Due to the relatively small dimensions of the lamp bulb, relatively small and inexpensive magnets may be used.
    • 光谱源包括在惰性气体中含有阳极和阴极的灯。 阳极和阴极的形状不同,并连接到高频电源,以在阳极和阴极之间产生高频放电,使得阴极溅射和具有根据溅射的材料的光谱的辐射 阴极。 单独使用高频功率可防止溅射材料对灯泡内壁的粘附,从而可以减小灯泡的尺寸,延长灯泡的使用寿命并增加辐射的稳定性和强度 。 可以将磁场施加到用于塞曼调制的辐射。 由于灯泡的尺寸相对较小,所以可以使用相对较小和便宜的磁体。