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11. 发明授权

US5026787A Impact resistant thermoplastic resin composition 失效
标题翻译：耐冲击热塑性树脂组合物
公开(公告)号：US5026787A
公开(公告)日：1991-06-25
申请号：US466640
申请日：1990-01-17
申请人： Kiyoji Takagi , Koji Nishida
发明人： Kiyoji Takagi , Koji Nishida
IPC分类号： C08L71/12 , C08L77/00
CPC分类号： C08L71/123 , C08L77/00 , Y10S525/905
摘要： A composition comprising a polyphenylene ether, a polyamide resin and a compound having an unsaturated group and a polar group in combination in the same molecule kneaded therein, and optionally an impact resistance improving material kneaded in said kneaded product. Impact resistance can be greatly improved as compared with the composition having the all components kneaded at the same time.

12. 发明授权

US06746757B1 Multilayered molding 失效
标题翻译：多层成型
公开(公告)号：US06746757B1
公开(公告)日：2004-06-08
申请号：US09505468
申请日：2000-02-16
申请人： Kiyoji Takagi , Akihiro Kokubo , Koji Nishida
发明人： Kiyoji Takagi , Akihiro Kokubo , Koji Nishida
IPC分类号： B32B702
CPC分类号： B32B27/08 , B29C45/16 , B29L2031/3044 , B32B27/34 , B32B27/365 , B32B2262/0284 , B32B2307/546 , B32B2307/558 , B32B2307/734 , B32B2323/10 , B32B2325/00 , B32B2369/00 , B32B2377/00 , Y10T428/2495 , Y10T428/31504 , Y10T428/31507 , Y10T428/31743 , Y10T428/31746 , Y10T428/3175 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913 , Y10T428/31917 , Y10T428/31928
摘要： The present invention relates to a multilayered molding comprising at least two of a layer A and a layer B, in which the layers A are formed on both sides of the layer B, each layer A comprises a same or different thermoplastic resin compositions, the layer A has a flexural modulus according to ASTM D790 of not less than 5,000 kg/cm2, the layer B comprises a thermoplastic resin composition and has a flexural modulus according to ASTM D790 of not more than 5,000 kg/cm2, and the ratio of flexular modulus of the layer A to flexural modulus of the layer B is not less than 5.
摘要翻译：本发明涉及包含A层和B层中的至少两层的多层成型体，其中层A形成在层B的两侧，每层A包含相同或不同的热塑性树脂组合物，该层 A具有根据ASTM D790的挠曲模量不小于5,000kg / cm 2，层B包含热塑性树脂组合物，并且具有根据ASTM D790的挠曲模量不超过5,000kg / cm 2，层A的弯曲弹性模量与B层的挠曲模量的比率不小于5。

13. 发明授权

US5496885A Thermoplastic resin composition and process for preparing the same 失效
标题翻译：热塑性树脂组合物及其制备方法
公开(公告)号：US5496885A
公开(公告)日：1996-03-05
申请号：US67816
申请日：1993-05-27
申请人： Kiyoji Takagi , Koji Nishida , Tosio Itou
发明人： Kiyoji Takagi , Koji Nishida , Tosio Itou
IPC分类号： C08L51/04 , C08L67/00 , C08L69/00 , C08L71/12 , C08L65/02 , C08K5/03 , C08L67/02
CPC分类号： C08L71/12 , C08L51/04 , C08L67/00 , C08L69/00 , Y10S525/905
摘要： There are disclosed a thermoplastic resin composition which comprises(a) 4 to 95% by weight of a polyphenylene ether,(b) 95 to 4% by weight of a saturated polyester,(c) 0.5 to 40% by weight of an impact modifier and(d) 0.01 to 50% by weight of a compatibilizer and(e) 0.1 to 3 parts by weight of a polycarbonate based on 100 parts by weight of the above (a) to (d) in total; and a process for preparing a thermoplastic resin composition which comprises the steps of melting and kneading(a) 50 to 95% by weight of a polyphenylene ether,(e) 0.1 to 5% by weight of a polycarbonate, and(d) 5 to 50% by weight of a compatibilizer and(c) 0 to 35 parts by weight of an impact modifier based on 100 parts by weight of the above (a), (e) and (d) in total to obtain an intermediate composition (A), and then, melting and kneading 10 to 80% by weight of the intermediate composition (A) and (b) 90 to 20% by weight of a saturated polyester in a kneader equipped with vent ports each having a vacuum device while maintaining each vent port at a reduced pressure of 200 mmHg or less to prepare a thermoplastic resin composition.
摘要翻译：公开了一种热塑性树脂组合物，其包含（a）4〜95重量％的聚苯醚，（b）95〜4重量％的饱和聚酯，（c）0.5〜40重量％的抗冲改性剂和（d）0.01〜50重量％的增容剂和（e）基于100重量份上述（a）〜（d）的总计0.1〜3重量份的聚碳酸酯; 以及制备热塑性树脂组合物的方法，其包括以下步骤：（a）将50至95重量％的聚苯醚，（e）0.1-5重量％的聚碳酸酯，和（d）5至 50重量％的增容剂和（c）0至35重量份的基于100重量份上述（a），（e）和（d）的抗冲改性剂以获得中间体组合物（A ），然后在具有各自具有真空装置的排气口的捏合机中熔融捏合10至80重量％的中间体组合物（A）和（b）90至20重量％的饱和聚酯，同时保持每个通气口处于200mmHg以下的减压下，制备热塑性树脂组合物。

14. 发明授权

US5717014A Polyphenylene ether resin composition 失效
标题翻译：聚苯醚树脂组合物
公开(公告)号：US5717014A
公开(公告)日：1998-02-10
申请号：US737596
申请日：1996-11-25
申请人： Ichiro Ohkawachi , Kiyoji Takagi , Koji Nishida
发明人： Ichiro Ohkawachi , Kiyoji Takagi , Koji Nishida
IPC分类号： C08K5/524 , C08K5/52 , C08L53/00 , C08L53/02 , C08L67/00 , C08L69/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08K5/49
CPC分类号： C08L53/02 , C08L53/025 , C08L71/123 , C08L67/00 , C08L69/00 , C08L77/00
摘要： A polyphenylene ether resin composition containing the following Components (A) to (D) according at the following formulation ratio. (A) 50 to 99.5 parts by weight of a polyphenylene ether (B) 0.5 to 50 parts by weight of a partially hydrogenated aromatic alkenyl compound-conjugated diene block copolymer having a hydroxy group and based on 100 parts by weight of the above resin composition, (C) 0 to 950 parts by weight of a thermoplastic resin and (D) 0 to 10 parts by weight of a phosphorous acid triester.
摘要翻译： PCT No.PCT / JP95 / 00960 Sec。 371日期：1996年11月25日 102（e）日期1996年11月25日PCT提交1995年5月19日PCT公布。出版物WO95 / 32244 日期：1995年11月30日根据以下配比，含有以下成分（A）〜（D）的聚苯醚树脂组合物。（A）50〜99.5重量份聚苯醚（B）0.5〜50重量份具有羟基的部分氢化芳香族链烯基化合物 - 共轭二烯嵌段共聚物，相对于上述树脂组合物100重量份，（C）0〜950重量份的热塑性树脂和（D）0〜10重量份的亚磷酸三酯。

15. 发明申请

US20110009538A1 Thermoplastic resin composition and resin molded product 有权
标题翻译：热塑性树脂组合物和树脂模塑制品
公开(公告)号：US20110009538A1
公开(公告)日：2011-01-13
申请号：US12923341
申请日：2010-09-15
申请人： Makoto Nakamura , Hiroshi Nakano , Kiyoji Takagi , Kouji Iwaki
发明人： Makoto Nakamura , Hiroshi Nakano , Kiyoji Takagi , Kouji Iwaki
IPC分类号： C08K3/34 , C08K5/49 , C08K5/54
CPC分类号： C08K9/08 , C08K3/34 , C08K5/524 , C08K9/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02 , C08L2666/18
摘要： The present invention relates to a thermoplastic resin composition comprising an aromatic polycarbonate resin (component A) [which may comprise an aromatic polycarbonate resin (component A1) and a thermoplastic resin other than the aromatic polycarbonate resin (component A2)], a granular talc (component B) having a bulk density of 0.4 to 1.5 g/mL which is obtained by granulating a talc having an average particle size of 0.1 to 10 μm, a rubber polymer (component C; optional component), a flame retardant (component E; optional component) and a fluorinated polyolefin (component F; optional component), wherein the granular talc (component B) has a particle size in which a proportion of a 500 μm-mesh screen residue thereof is not less than 55% by weight; as well as a resin molded product obtained by molding the thermoplastic resin composition. The thermoplastic resin composition and the resin molded product are excellent in extrusion moldability, rigidity, flame retardant, impact resistance and thermal stability, and exhibit an excellent balance between these properties.
摘要翻译：本发明涉及包含芳族聚碳酸酯树脂（组分A）[其可以包含芳族聚碳酸酯树脂（组分A1）和除芳族聚碳酸酯树脂（组分A2）之外的热塑性树脂）]的热塑性树脂组合物，颗粒滑石（成分B），其通过造粒平均粒度为0.1〜10μm的滑石，橡胶聚合物（C成分，任意成分），阻燃剂（E成分）而得到的堆积密度为0.4〜1.5g / 任选组分）和氟化聚烯烃（组分F;任选组分），其中所述颗粒滑石（组分B）具有其500μm筛网残余物的比例不小于55重量％的粒径; 以及通过模塑该热塑性树脂组合物获得的树脂模制产品。热塑性树脂组合物和树脂成型体的挤出成型性，刚性，阻燃性，耐冲击性和热稳定性优异，在这些特性之间表现出极好的平衡。

16. 发明授权

US08304481B2 Thermoplastic resin composition and resin molded product 有权
标题翻译：热塑性树脂组合物和树脂模塑制品
公开(公告)号：US08304481B2
公开(公告)日：2012-11-06
申请号：US12923341
申请日：2010-09-15
申请人： Makoto Nakamura , Hiroshi Nakano , Kiyoji Takagi , Kouji Iwaki
发明人： Makoto Nakamura , Hiroshi Nakano , Kiyoji Takagi , Kouji Iwaki
IPC分类号： C08K3/32 , C08K9/08 , C08K9/04
CPC分类号： C08K9/08 , C08K3/34 , C08K5/524 , C08K9/04 , C08L55/02 , C08L67/02 , C08L69/00 , C08L2666/02 , C08L2666/18
摘要： Process for preparing a thermoplastic resin composition containing an aromatic polycarbonate resin which may include a thermoplastic resin other than the aromatic polycarbonate resin, a granular talc, and optionally a rubber polymer, a flame retardant or a fluorinated polyolefin. The granular talc has a particle size in which a proportion of a 500 μm-mesh screen residue thereof is not less than 55% by weight.
摘要翻译：制备含有芳族聚碳酸酯树脂的热塑性树脂组合物的方法，其可以包括除芳族聚碳酸酯树脂之外的热塑性树脂，粒状滑石，以及任选的橡胶聚合物，阻燃剂或氟化聚烯烃。粒状滑石的粒径为500μm筛网残留物的比例不小于55重量％。

17. 发明申请

US20070117901A1 Thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物
公开(公告)号：US20070117901A1
公开(公告)日：2007-05-24
申请号：US11635798
申请日：2006-12-08
申请人： Masami Suzuki , Morio Tsunoda , Hajime Ohyama , Makoto Nakamura , Kiyoji Takagi
发明人： Masami Suzuki , Morio Tsunoda , Hajime Ohyama , Makoto Nakamura , Kiyoji Takagi
IPC分类号： C08K3/34
CPC分类号： C08L77/02 , C08K3/34 , C08L23/0861 , C08L29/04 , C08L53/00 , C08L53/02 , C08L53/025 , C08L77/00 , C08L77/06 , C08L2205/02 , C08L2205/035 , C08L2666/02 , C08L2666/04 , C08L2666/24
摘要： The present invention relates to a thermoplastic resin composition which excels in impact resistance, dimension stability and rigidity, and also excels in appearance, fluidity and paint film adhesion property, and further which is very useful as manufacturing materials for exterior parts of automobile. A thermoplastic resin composition comprising component (A): a polyamide resin; component (B): a hydrogenated product of block copolymer comprising vinyl aromatic polymer block (a) and conjugated diene based polymer block (b), and/or ethylene-α-olefin based block copolymer; component (C): a modified hydrogenated product of block copolymer comprising the vinyl aromatic polymer block (a) and the conjugated diene based polymer block (b), which hydrogenated product is modified by addition of an unsaturated acid and/or derivative thereof; component (D): a plate-like and/or needle-like inorganic filler; and component (F): an ethylene-vinyl alcohol copolymer and/or a partial saponified product of ethylene-vinyl acetate copolymer.
摘要翻译：本发明涉及耐冲击性，尺寸稳定性和刚性优异的外观，流动性和漆膜附着性优异的热塑性树脂组合物，进一步作为汽车用外装件的制造材料非常有用。一种热塑性树脂组合物，其包含组分（A）：聚酰胺树脂; 组分（B）：包含乙烯基芳族聚合物嵌段（a）和共轭二烯基聚合物嵌段（b）的嵌段共聚物的氢化产物和/或乙烯-α-烯烃基嵌段共聚物; 组分（C）：包含乙烯基芳族聚合物嵌段（a）和共轭二烯基聚合物嵌段（b）的嵌段共聚物的改性氢化产物，该加氢产物通过加入不饱和酸和/或其衍生物进行改性; 组分（D）：板状和/或针状无机填料; 和组分（F）：乙烯 - 乙烯醇共聚物和/或乙烯 - 乙酸乙烯酯共聚物的部分皂化产物。

18. 发明授权

US08193282B2 Thermoplastic resin composition 有权
标题翻译：热塑性树脂组合物
公开(公告)号：US08193282B2
公开(公告)日：2012-06-05
申请号：US11635798
申请日：2006-12-08
申请人： Masami Suzuki , Morio Tsunoda , Hajime Ohyama , Makoto Nakamura , Kiyoji Takagi
发明人： Masami Suzuki , Morio Tsunoda , Hajime Ohyama , Makoto Nakamura , Kiyoji Takagi
IPC分类号： C08K3/04 , C08K3/34 , C08L53/02 , C08L77/00
CPC分类号： C08L77/02 , C08K3/34 , C08L23/0861 , C08L29/04 , C08L53/00 , C08L53/02 , C08L53/025 , C08L77/00 , C08L77/06 , C08L2205/02 , C08L2205/035 , C08L2666/02 , C08L2666/04 , C08L2666/24
摘要： The present invention relates to a thermoplastic resin composition which excels in impact resistance, dimension stability and rigidity, and also excels in appearance, fluidity and paint film adhesion property, and further which is very useful as manufacturing materials for exterior parts of automobile.A thermoplastic resin composition comprising component (A): a polyamide resin; component (B): a hydrogenated product of block copolymer comprising vinyl aromatic polymer block (a) and conjugated diene based polymer block (b), and/or ethylene-α-olefin based block copolymer; component (C): a modified hydrogenated product of block copolymer comprising the vinyl aromatic polymer block (a) and the conjugated diene based polymer block (b), which hydrogenated product is modified by addition of an unsaturated acid and/or derivative thereof; component (D): a plate-like and/or needle-like inorganic filler; and component (F): an ethylene-vinyl alcohol copolymer and/or a partial saponified product of ethylene-vinyl acetate copolymer.
摘要翻译：本发明涉及耐冲击性，尺寸稳定性和刚性优异的外观，流动性和漆膜附着性优异的热塑性树脂组合物，进一步作为汽车外用部件的制造材料非常有用。一种热塑性树脂组合物，其包含组分（A）：聚酰胺树脂; 组分（B）：包含乙烯基芳族聚合物嵌段（a）和共轭二烯基聚合物嵌段（b）的嵌段共聚物的氢化产物和/或乙烯-α-烯烃基嵌段共聚物; 组分（C）：包含乙烯基芳族聚合物嵌段（a）和共轭二烯基聚合物嵌段（b）的嵌段共聚物的改性氢化产物，该加氢产物通过加入不饱和酸和/或其衍生物进行改性; 组分（D）：板状和/或针状无机填料; 和组分（F）：乙烯 - 乙烯醇共聚物和/或乙烯 - 乙酸乙烯酯共聚物的部分皂化产物。

19. 发明授权

US08062557B2 Thermoplastic resin composition for producing automobile exterior parts 有权
标题翻译：用于生产汽车外部件的热塑性树脂组合物
公开(公告)号：US08062557B2
公开(公告)日：2011-11-22
申请号：US12299910
申请日：2007-05-08
申请人： Kiyoji Takagi , Morio Tsunoda , Masami Suzuki , Takayuki Nagai , Yasumitsu Isobe
发明人： Kiyoji Takagi , Morio Tsunoda , Masami Suzuki , Takayuki Nagai , Yasumitsu Isobe
IPC分类号： H01B1/22
CPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/524 , C08K5/5393 , C08L51/04 , C08L53/02 , C08L2666/24
摘要： Thermoplastic resin composition containing 18-80 weight % of a polyamide 6 resin with specific viscosity number and specific ratio of terminal carboxyl groups content to terminal amino groups content (component (A)); 5-25 weight % of a hydrogenated product of a block copolymer having a vinyl aromatic compound polymer block and a conjugated diene compound polymer block (component (B)); 3-15 weight % of a graft-modified hydrogenated product of such block copolymer (component (C)), said hydrogenated product being graft-modified with maleic anhydride in an amount of 2.6-5.0 weight % based on 100 weight % of said graft-modified hydrogenated product; 1-5 weight % conductive carbon black with specific BET specific surface area and specific DBP oil absorption (component (D)); 10-30 weight % talc having a specific average particle diameter (component (E)); 0.1-2 weight % of a phosphonite compound (component (F)); 0.5-5 weight % of an ethylene-vinyl alcohol resin (component (G)); 0-1 weight % of a pentaerythritol based phosphite (component (H)).
摘要翻译：含有18-80重量％的具有特定粘度数和末端羧基含量与末端氨基含量比例（组分（A））的聚酰胺6树脂的热塑性树脂组合物; 5-25重量％的具有乙烯基芳族化合物聚合物嵌段和共轭二烯化合物聚合物嵌段（组分（B））的嵌段共聚物的氢化产物; 3-15重量％的这种嵌段共聚物（组分（C））的接枝改性的氢化产物，所述氢化产物以2.6-5.0重量％的量接枝改性马来酸酐，基于100重量％的所述接枝改性氢化产物; 1-5重量％具有特定BET比表面积和特定DBP吸油量的导电炭黑（组分（D））; 10-30重量％具有特定平均粒径的滑石（组分（E））; 0.1-2重量％的亚膦酸酯化合物（组分（F））; 0.5-5重量％的乙烯 - 乙烯醇树脂（组分（G））; 0-1重量％的季戊四醇基亚磷酸酯（组分（H））。

20. 发明申请

US20090309073A1 THERMOPLASTIC RESIN COMPOSITION FOR PRODUCING AUTOMOBILE EXTERIOR PARTS 有权
公开(公告)号：US20090309073A1
公开(公告)日：2009-12-17
申请号：US12299910
申请日：2007-05-08
申请人： Kiyoji Takagi , Morio Tsunoda , Masami Suzuki , Takayuki Nagai , Yasumitsu Isobe
发明人： Kiyoji Takagi , Morio Tsunoda , Masami Suzuki , Takayuki Nagai , Yasumitsu Isobe
IPC分类号： H01B1/24
CPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/524 , C08K5/5393 , C08L51/04 , C08L53/02 , C08L2666/24
摘要： To provide a resin composition having highly balanced properties of fluidity, impact resistance, dimensional stability, rigidity, heat-resistant rigidity, electrical conductivity, coating adhesion and appearance, which properties are required as a thermoplastic resin material for producing automobile exterior parts, and being excellent in retention stability, and a thermoplastic resin composition for producing automobile exterior parts obtained by molding the resin composition followed by electrostatic coating.A thermoplastic resin composition for producing automobile exterior parts, including the following components (A) to (H) in the following weight percentage ranges based on 100% by weight of the sum of the entire components constituting the composition: 18 to 80% by weight of component (A) which is a polyamide 6 resin having a viscosity number, as measured in accordance with ISO-307, of 80 to 120 ml/g and a ratio of a content of terminal carboxyl groups (unit: μeq/g) to a content of terminal amino groups (unit: μeq/g) of 2≦(terminal carboxyl group content/terminal amino group content)≦6; 5 to 25% by weight of component (B) which is a hydrogenated product of a block copolymer comprising a vinyl aromatic compound polymer block and a conjugated diene compound polymer block; 3 to 15% by weight of component (C) which is a graft-modified hydrogenated product of a block copolymer comprising a vinyl aromatic compound polymer block and a conjugated diene compound polymer block, said hydrogenated product being graft-modified with maleic anhydride in an amount of 2.6 to 5.0% by weight based on 100% by weight of said graft-modified hydrogenated product; 1 to 5% by weight of component (D) which is conductive carbon black having a BET specific surface area of not less than 600 m2/g and a DBP oil absorption of not less than 300 ml/100 g; 10 to 30% by weight of component (E) which is talc having an average particle diameter of 0.5 to 10 μm; 0.1 to 2% by weight component (F) which is a phosphonite compound; 0.5 to 5% by weight of component (G) which is an ethylene-vinyl alcohol resin; and 0 to 1% by weight of component (H) which is a pentaerythritol based phosphite.

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