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11. 发明授权

US07041728B2 Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant 失效
标题翻译：具有少量氟化表面活性剂的聚四氟乙烯的水分散体
公开(公告)号：US07041728B2
公开(公告)日：2006-05-09
申请号：US10962633
申请日：2004-10-12
申请人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadalas , Gernot Loehr
发明人： Tilman Zipplies , Klaus Hintzer , Michael C. Dadalas , Gernot Loehr
IPC分类号： C08L27/12 , D06M15/277
CPC分类号： C09D127/18 , C08F6/16 , C08F214/26 , C08L27/18 , C08L71/02 , C08L2666/02 , C08L2666/22
摘要： The present invention provides a method of making an aqueous dispersion of non-melt processible polytetrafluoroethylene, the method comprising:(a) an aqueous emulsion polymerization of an amount of tetrafluoroethylene to produce a final amount of polytetrafluoroethylene solids and optionally up to 1% by weight based on the amount of tetrafluoroethylene of a perfluorinated comonomer, wherein said aqueous emulsion polymerization is initiated with a free radical initiator and the polymerization is carried out in the presence of a fluorinated surfactant, and wherein before completing the feeding of said amount of tetrafluoroethylene but after feeding at least 80% by weight of said amount of tetrafluoroethylene, free radicals capable of introducing ionic end groups or precursors thereof in the polytetrafluoroethylene polymer are caused to be formed at a rate that without counter measures would cause an increase in the polymerization rate of at least 20%;(b) reducing the amount of fluorinated surfactant in the thus obtained aqueous dispersion to an amount of not more than 200 ppm, preferably not more than 100 ppm and more preferably not more than 50 ppm based on the amount of polytetrafluoroethylene solids. The invention further provides an aqueous dispersion of polytetrafluoroethylene particles and the use thereof in coating a substrate.
摘要翻译：本发明提供了一种制备不熔融可加工聚四氟乙烯的水性分散体的方法，该方法包括：（a）一定量的四氟乙烯的水乳液聚合以产生最终量的聚四氟乙烯固体，并且任选地高达1重量％基于全氟化共聚单体的四氟乙烯的量，其中所述水性乳液聚合由自由基引发剂引发，并且聚合在氟化表面活性剂的存在下进行，并且其中在完成所述量的四氟乙烯之前但在加入至少80重量％的所述量的四氟乙烯，使得能够在聚四氟乙烯聚合物中引入离子端基或其前体的自由基以不加对策的方式形成，导致聚四氟乙烯聚合速率的升高至少20％; （b）将由此得到的水性分散体中的氟化表面活性剂的量减少到基于聚四氟乙烯固体量不超过200ppm，优选不超过100ppm，更优选不大于50ppm的量。本发明还提供聚四氟乙烯颗粒的水分散体及其在涂布基材中的用途。

12. 发明申请

US20100047585A1 PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLYMER DISPERSIONS USING AN ION-EXCHANGE RESIN AND DISPERSIONS OBTAINED THEREFROM 审中-公开
标题翻译：使用离子交换树脂和由其获得的分散体从荧光体分散液中除去氟化乳化剂的方法
公开(公告)号：US20100047585A1
公开(公告)日：2010-02-25
申请号：US12519220
申请日：2007-12-12
申请人： Klaus Hintzer , Michael C. Dadalas , Andreas R. Maurer , Tilman C. Zipplies
发明人： Klaus Hintzer , Michael C. Dadalas , Andreas R. Maurer , Tilman C. Zipplies
IPC分类号： B32B27/08 , C08L27/18
CPC分类号： C09D127/12 , C08F6/16 , Y10T428/3154 , C08L27/12
摘要： The present invention provides a process for reducing the amount of fluorinated emulsifier in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of amphoteric surfactants or anionic surfactants of low molecular weight and provides fluoropolymer dispersions containing low amounts of fluorinated emulsifier and no or only low amounts of non-ionic surfactants.
摘要翻译：本发明提供一种通过在两性表面活性剂或低分子量阴离子表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触来降低含氟聚合物分散体中氟化乳化剂的量的方法，并提供含有少量氟化乳化剂的含氟聚合物分散体和没有或只有少量的非离子表面活性剂。

13. 发明授权

US08466231B2 Process for removing fluorinated emulsifier from fluoropolymer dispersions using an anion-exchange resin and a pH-dependent surfactant and fluoropolymer dispersions containing a pH-dependent surfactant 有权
标题翻译：使用阴离子交换树脂和pH依赖性表面活性剂和含有pH依赖性表面活性剂的含氟聚合物分散体从含氟聚合物分散体中除去氟化乳化剂的方法
公开(公告)号：US08466231B2
公开(公告)日：2013-06-18
申请号：US12420108
申请日：2009-04-08
申请人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
发明人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
IPC分类号： C08F2/16 , C08F14/18 , C08G18/22
CPC分类号： F16C17/12 , C02F1/42 , C02F2101/14 , C02F2209/06 , C08F6/16 , C08F6/22 , C08F14/18 , Y10T428/3154 , C08L27/12 , C08F2/24
摘要： A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersion containing the pH-dependent surfactant and uses thereof.
摘要翻译：通过在pH依赖性表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触，以及含有pH依赖性表面活性剂的含氟聚合物分散体及其用途，来降低含氟聚合物分散体中的氟化乳化剂的量的方法。

14. 发明申请

US20080264864A1 PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT 审中-公开
标题翻译：使用阴离子交换树脂和pH依赖性表面活性剂和含有pH依赖性表面活性剂的氟聚合物分散体从荧光体分散体中除去荧光体乳化剂的方法
公开(公告)号：US20080264864A1
公开(公告)日：2008-10-30
申请号：US11741289
申请日：2007-04-27
申请人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
发明人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
IPC分类号： C02F1/28 , C08F2/16
CPC分类号： F16C17/12 , C02F1/42 , C02F2101/14 , C02F2209/06 , C08F6/16 , C08F6/22 , C08F14/18 , Y10T428/3154 , C08L27/12 , C08F2/24
摘要： A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersions containing the pH-dependent surfactant and uses thereof.
摘要翻译：通过在pH依赖性表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触，以及含有pH依赖性表面活性剂的含氟聚合物分散体及其用途，来降低含氟聚合物分散体中氟化乳化剂的量的方法。

15. 发明申请

US20090192260A1 PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT 有权
标题翻译：使用阴离子交换树脂和pH依赖性表面活性剂和含有pH依赖性表面活性剂的氟聚合物分散体从荧光体分散体中除去荧光体乳化剂的方法
公开(公告)号：US20090192260A1
公开(公告)日：2009-07-30
申请号：US12420108
申请日：2009-04-08
申请人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
发明人： Michael C. Dadalas , Klaus Hintzer , Ludwig Mayer , Tilman C. Zipplies , James Arthur McDonell
IPC分类号： C08L27/18
CPC分类号： F16C17/12 , C02F1/42 , C02F2101/14 , C02F2209/06 , C08F6/16 , C08F6/22 , C08F14/18 , Y10T428/3154 , C08L27/12 , C08F2/24
摘要： A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersions containing the pH-dependent surfactant and uses thereof.
摘要翻译：通过在pH依赖性表面活性剂的存在下使含氟聚合物分散体与阴离子交换树脂接触，以及含有pH依赖性表面活性剂的含氟聚合物分散体及其用途，来降低含氟聚合物分散体中氟化乳化剂的量的方法。

16. 发明授权

US09139668B2 Fluoropolymer compositions containing a polyol compound and methods of making them 有权
标题翻译：含有多元醇化合物的含氟聚合物组合物及其制备方法
公开(公告)号：US09139668B2
公开(公告)日：2015-09-22
申请号：US13387889
申请日：2010-07-30
申请人： Tilman C. Zipplies , Klaus Hintzer , Michael C. Dadalas , Oliver Frey , Kai H Lochhaas
发明人： Tilman C. Zipplies , Klaus Hintzer , Michael C. Dadalas , Oliver Frey , Kai H Lochhaas
IPC分类号： C08F14/18 , C08F2/16 , C08L5/00 , C08L27/16 , C08L27/18 , C08L27/20 , C08K5/053 , C08K5/103 , C08K5/151
CPC分类号： C08F14/18 , C08F2/16 , C08K5/053 , C08K5/103 , C08K5/151 , C08L5/00 , C08L27/16 , C08L27/18 , C08L27/20 , C09D127/18 , C08L2666/26
摘要： There are provided compositions comprising (i) at least one non-aromatic polyol compound containing at least one polyol unit having at least two hydroxyl groups and at least one long chain unit containing at least 6 carbon atoms; and (ii) at least one fluoropolymer comprising repeating units derived from a fluorinated olefin. There are also provided methods of improving the shear stability of fluoropolymer dispersions, methods of coating substrates, and substrates coated with the above described composition.
摘要翻译：提供的组合物包含（i）至少一种含有至少一个具有至少两个羟基的多元醇单元和至少一个含有至少6个碳原子的长链单元的非芳族多元醇化合物; 和（ii）至少一种含有衍生自氟化烯烃的重复单元的含氟聚合物。还提供了提高含氟聚合物分散体的剪切稳定性，涂布基材的方法和用上述组合物涂布的基材的方法。

17. 发明申请

US20120129982A1 FLUOROPOLYMER COMPOSITIONS CONTAINING A POLYOL COMPOUND AND METHODS OF MAKING THEM 有权
标题翻译：包含多元醇化合物的氟聚合物组合物及其制备方法
公开(公告)号：US20120129982A1
公开(公告)日：2012-05-24
申请号：US13387889
申请日：2010-07-30
申请人： Tilman C. Zipplies , Klaus Hintzer , Michael C. Dadalas , Oliver Frey , Kai H. Lochhaas
发明人： Tilman C. Zipplies , Klaus Hintzer , Michael C. Dadalas , Oliver Frey , Kai H. Lochhaas
IPC分类号： C08K5/1545 , C09D127/20 , C09D127/18 , C08L27/18 , C08L27/20
CPC分类号： C08F14/18 , C08F2/16 , C08K5/053 , C08K5/103 , C08K5/151 , C08L5/00 , C08L27/16 , C08L27/18 , C08L27/20 , C09D127/18 , C08L2666/26
摘要： There are provided compositions comprising (i) at least one non-aromatic polyol compound containing at least one polyol unit having at least two hydroxyl groups and at least one long chain unit containing at least 6 carbon atoms; and (ii) at least one fluoropolymer comprising repeating units derived from a fluorinated olefin. There are also provided methods of improving the shear stability of fluoropolymer dispersions, methods of coating substrates, and substrates coated with the above described composition.
摘要翻译：提供的组合物包含（i）至少一种含有至少一个具有至少两个羟基的多元醇单元和至少一个含有至少6个碳原子的长链单元的非芳族多元醇化合物; 和（ii）至少一种含有衍生自氟化烯烃的重复单元的含氟聚合物。还提供了提高含氟聚合物分散体的剪切稳定性，涂布基材的方法和用上述组合物涂布的基材的方法。

18. 发明授权

US08598267B2 Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant 有权
标题翻译：不含或少量低分子量氟化表面活性剂的含氟聚合物分散体
公开(公告)号：US08598267B2
公开(公告)日：2013-12-03
申请号：US11851431
申请日：2007-09-07
申请人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
发明人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
IPC分类号： C08L27/12
CPC分类号： C09D127/12 , C08K5/42
摘要： The present invention provides a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or contains the fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.025% by weight based on the total weight of solids in the dispersion. The dispersion further comprises a non-ionic surfactant and an anionic surfactant selected from fluorinated anionic surfactants having a molecular weight of at least 1000 g/mol, non-fluorinated anionic surfactants and mixtures thereof.
摘要翻译：本发明提供一种氟聚合物分散体，其含有平均粒径为10〜400nm的含氟聚合物颗粒，其分散在水中，由此该分散体不含分子量小于1000g / mol的氟化表面活性剂，或含有具有分子量重量小于1000g / mol，其量不得大于0.025％（重量），基于分散体中固体的总重量。分散体还包含非离子表面活性剂和选自分子量至少为1000g / mol的氟化阴离子表面活性剂，非氟化阴离子表面活性剂及其混合物的阴离子表面活性剂。

19. 发明申请

US20080287599A1 FLUOROPOLYMER DISPERSION CONTAINING NO OR LITTLE LOW MOLECULAR WEIGHT FLUORINATED SURFACTANT 有权
标题翻译：含有低分子量氟分解表面活性剂的氟聚合物分散体
公开(公告)号：US20080287599A1
公开(公告)日：2008-11-20
申请号：US11851431
申请日：2007-09-07
申请人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
发明人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
IPC分类号： C08L27/12
CPC分类号： C09D127/12 , C08K5/42
摘要： The present invention provides a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or contains the fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.025% by weight based on the total weight of solids in the dispersion. The dispersion further comprises a non-ionic surfactant and an anionic surfactant selected from fluorinated anionic surfactants having a molecular weight of at least 1000 g/mol, non-fluorinated anionic surfactants and mixtures thereof.
摘要翻译：本发明提供一种氟聚合物分散体，其含有平均粒径为10〜400nm的含氟聚合物颗粒，其分散在水中，由此该分散体不含分子量小于1000g / mol的氟化表面活性剂，或含有具有分子量重量小于1000g / mol，其量不得大于0.025％（重量），基于分散体中固体的总重量。分散体还包含非离子表面活性剂和选自分子量至少为1000g / mol的氟化阴离子表面活性剂，非氟化阴离子表面活性剂及其混合物的阴离子表面活性剂。

20. 发明授权

US07279522B2 Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant 有权
标题翻译：不含或少量低分子量氟化表面活性剂的含氟聚合物分散体
公开(公告)号：US07279522B2
公开(公告)日：2007-10-09
申请号：US10486860
申请日：2002-08-06
申请人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
发明人： Michael C. Dadalas , Rebekka Epsch , Friedrich Kloos , Leonard W. Harvey
IPC分类号： C08L27/12
CPC分类号： C09D127/12 , C08K5/42
摘要： The present invention provides a fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of 10 to 400 nm dispersed in water whereby the dispersion is free of fluorinated surfactant having a molecular weight of less than 1000 g/mol or contains the fluorinated surfactant having a molecular weight of less than 1000 g/mol in an amount of not more than 0.025% by weight based on the total weight of solids in the dispersion. The dispersion further comprises a non-ionic surfactant and an anionic surfactant selected from fluorinated anionic surfactants having a molecular weight of at least 1000 g/mol, non-fluorinated anionic surfactants and mixtures thereof.
摘要翻译：本发明提供一种氟聚合物分散体，其含有平均粒径为10〜400nm的含氟聚合物颗粒，其分散在水中，由此该分散体不含分子量小于1000g / mol的氟化表面活性剂，或含有具有分子量重量小于1000g / mol，其量不得大于0.025％（重量），基于分散体中固体的总重量。分散体还包含非离子表面活性剂和选自分子量至少为1000g / mol的氟化阴离子表面活性剂，非氟化阴离子表面活性剂及其混合物的阴离子表面活性剂。

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