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11. 发明申请

US20110054167A1 METHOD FOR PRODUCING AN AMINE 有权
标题翻译：生产氨的方法
公开(公告)号：US20110054167A1
公开(公告)日：2011-03-03
申请号：US12809653
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07D295/023 , C07C209/16 , B01J23/72
CPC分类号： B01J23/835 , B01J23/002 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/02 , C07D295/06 , C07C217/08
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, nickel and tin, and 0.5 to 8.0% by weight of an oxygen compound of cobalt, calculated as CoO, and wherein the catalytically active composition does not comprise any ruthenium.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，所述催化活性组合物在用氢还原之前包括锆，铜，镍和锡的氧化合物和0.5至8.0重量％的作为CoO计算的钴的氧化合物，并且其中催化活性组合物不包含任何钌。

12. 发明申请

US20100274011A1 METHOD FOR THE PRODUCTION OF AN AMINE 失效
标题翻译：生产胺的方法
公开(公告)号：US20100274011A1
公开(公告)日：2010-10-28
申请号：US12809657
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07D265/30 , C07C209/68 , C07C209/78 , C07D241/04 , B01J23/72
CPC分类号： B01J27/1853 , B01J23/002 , B01J23/755 , B01J23/825 , B01J23/835 , B01J23/84 , B01J23/8435 , B01J23/8474 , B01J27/055 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C209/78 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/17 , B01J2523/48 , B01J2523/56 , B01J2523/845 , B01J2523/847 , B01J2523/44 , B01J2523/53 , C07C211/10 , C07C217/08
摘要： Processes for preparing an amine, the processes comprising: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, 1.5 to 4.5% by weight of an oxygen compound of cobalt, calculated as CoO, and 0.2 to 5.0% by weight of at least one oxygen compound of niobium, sulfur, phosphorus, gallium, boron, lead or antimony, calculated in each case as Nb2O5, H2SO4, H3PO4, Ga2O3, B2O3, PbO and Sb2O3 respectively, and wherein the catalytically active composition does not comprise any molybdenum.
摘要翻译：用于制备胺的方法，所述方法包括：使选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，铜和镍的氧化合物，1.5至4.5重量％的作为CoO计算的氧化合物钴和0.2至5.0重量％的铌，硫，磷，镓，硼，铅或锑的至少一种氧化合物，分别以Nb 2 O 5，H 2 SO 4，H 3 PO 4，Ga 2 O 3，B 2 O 3，PbO和Sb 2 O 3计算，其中催化活性组合物不包含任何钼。

13. 发明授权

US07767855B2 Method for the continuous production of an amine 有权
标题翻译：连续生产胺的方法
公开(公告)号：US07767855B2
公开(公告)日：2010-08-03
申请号：US11993891
申请日：2006-06-21
申请人： Frank Haese , Joachim Wulff-Doering , Ulrich Koehler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
发明人： Frank Haese , Joachim Wulff-Doering , Ulrich Koehler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C211/00
CPC分类号： C07C209/18 , Y02P20/582 , C07C211/45
摘要： Processes comprising: providing an aromatic alcohol; and reacting the aromatic alcohol with ammonia at a temperature of 80 to 350° C. in the presence of hydrogen and a heterogeneous catalyst to form a crude reaction product comprising a corresponding primary aromatic amine, wherein the heterogeneous catalyst comprises a catalytically active composition which, prior to reduction with hydrogen, comprises 90 to 99.8% by weight of zirconium dioxide (ZrO2), 0.1 to 5.0% by weight of an oxygen-comprising compound of palladium, and 0.1 to 5.0% by weight of an oxygen-comprising compound of platinum.
摘要翻译：方法包括：提供芳族醇; 并在80至350℃的温度下在氢气和非均相催化剂存在下使芳族醇与氨反应形成包含相应的伯芳族胺的粗反应产物，其中非均相催化剂包含催化活性组合物，在用氢还原之前，包含90至99.8重量％的二氧化锆（ZrO 2），0.1至5.0重量％的含氧化合物的钯和0.1至5.0重量％的含氧化合物的铂。

14. 发明申请

US20090131722A9 METHODS OF TREATING TRIETHANOLAMINE WITH ACID COMPONENTS AND BASIC COMPONENTS, AND TRIETHANOLAMINE COMPOSITIONS CONTAINING THE SAME 失效
标题翻译：用酸组分和基本组分处理三乙醇胺的方法和含有它们的三乙醇胺组合物
公开(公告)号：US20090131722A9
公开(公告)日：2009-05-21
申请号：US11661544
申请日：2005-08-04
申请人： Frank Haese , Johan-Peter Melder , Roman Dostalek , Manfred Julius
发明人： Frank Haese , Johan-Peter Melder , Roman Dostalek , Manfred Julius
IPC分类号： C07C213/10 , C07C215/02
CPC分类号： C07C213/10 , C07C215/08
摘要： Methods for improving color properties of triethanolamine, and triethanolamine compositions treated thereby, are disclosed, wherein the methods comprise: (a) providing a composition comprising triethanolamine; and (b) contacting the composition with an acid component and a basic component; wherein the acid component comprises an acid selected from the group consisting of phosphorous acid, hypophosphorous acid and mixtures thereof; and wherein the basic component comprises a compound selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, ammonium hydroxides according to general formula (I), and mixtures thereof: [R1R2R3(2-hydroxyethyl)ammonium]hydroxide (I) wherein R1, R2 and R3 each independently represents a C1-30 alkyl or a C2-10 hydroxyalkyl; with the proviso that where the basic component comprises an alkali metal hydroxide, the molar ratio of acid component:basic component is 1:0.1 to 1:1, and where the basic component comprises an alkaline earth metal hydroxide, the molar ratio of acid component:basic component is 1:0.05 to 1:0.5.
摘要翻译：公开了用于改善三乙醇胺的颜色特性和由此处理的三乙醇胺组合物的方法，其中所述方法包括：（a）提供包含三乙醇胺的组合物; 和（b）使组合物与酸组分和碱性组分接触; 其中所述酸组分包含选自亚磷酸，次磷酸及其混合物的酸; 并且其中所述碱性组分包括选自碱金属氢氧化物，碱土金属氢氧化物，根据通式（I）的氢氧化铵的化合物及其混合物：<？在线公式描述=“在线公式“end =”lead“→> [R1R2R3（2-羟乙基）铵]氢氧化物（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中R1，R2和R3 各自独立地表示C1-30烷基或C2-10羟基烷基; 条件是碱性成分含有碱金属氢氧化物时，酸成分：碱成分的摩尔比为1:0.1〜1:1，碱性成分为碱土金属氢氧化物时，酸成分基本成分为1:0.05〜1:0.5。

15. 发明授权

US09345988B2 Devices and method for continuous distillative separation of a mixture containing one or more alkanolamine(s) 有权
标题翻译：用于连续蒸馏分离含有一种或多种链烷醇胺的混合物的装置和方法
公开(公告)号：US09345988B2
公开(公告)日：2016-05-24
申请号：US14057017
申请日：2013-10-18
申请人： Willi Schmidt , Gerd Kaibel , Elke Geiβler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
发明人： Willi Schmidt , Gerd Kaibel , Elke Geiβler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
IPC分类号： B01D3/32 , B01D3/14 , B01D3/42 , C07C213/04 , C07C213/10
CPC分类号： B01D3/32 , B01D3/14 , B01D3/42 , C07C213/04 , C07C213/10 , Y02P20/582 , C07C215/08 , C07C215/10
摘要： Apparatus and processes for continuous distillative separation of a mixture comprising one or more alkanolamine(s) are described. The separation is performed in one or more dividing wall column(s) and the alkanolamine or the alkanolamines is/are withdrawn as a side draw stream or side draw streams (side fraction(s)).
摘要翻译：描述了包含一种或多种链烷醇胺的混合物的连续蒸馏分离的装置和方法。分离在一个或多个分隔壁柱中进行，并且链烷醇胺或链烷醇胺作为侧馏分流或侧馏分流（侧馏分）排出。

16. 发明授权

US08268995B2 Processes for preparing amines and catalysts for use therein 失效
标题翻译：用于制备胺和催化剂的方法
公开(公告)号：US08268995B2
公开(公告)日：2012-09-18
申请号：US12809645
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07D265/30 , B01J21/06 , C07C209/16 , C07C209/26
CPC分类号： B01J23/835 , B01J23/002 , B01J23/8435 , B01J23/8437 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/17 , B01J2523/44 , B01J2523/48 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/53 , B01J2523/43 , C07C217/08
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, and nickel, and 0.2 to 40% by weight of an oxygen compound of cobalt, calculated as CoO, 0.1 to 5% by weight of an oxygen compound of iron, calculated as Fe2O3, and 0.1 to 5% by weight of at least one oxygen compound of lead, tin, bismuth or antimony, calculated as PbO, SnO, Bi2O3 and Sb2O3 respectively.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，铜和镍的氧化合物和0.2至40重量％的以COO计为0.1至5重量％的钴氧化合物的铁氧化合物，以Fe 2 O 3计，和0.1〜5重量％的至少一种铅，锡，铋或锑的氧化合物分别以PbO，SnO，Bi 2 O 3和Sb 2 O计算。

17. 发明申请

US20110168542A1 DEVICES AND METHOD FOR CONTINUOUS DISTILLATIVE SEPARATION OF A MIXTURE CONTAINING ONE OR MORE ALKANOLAMINE(S) 失效
标题翻译：含有一种或多种烷基胺的混合物的连续分离的装置和方法（S）
公开(公告)号：US20110168542A1
公开(公告)日：2011-07-14
申请号：US13119511
申请日：2009-09-16
申请人： Willi Schmidt , Gerd Kaibel , Elke Geissler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
发明人： Willi Schmidt , Gerd Kaibel , Elke Geissler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
IPC分类号： B01D3/14
CPC分类号： B01D3/32 , B01D3/14 , B01D3/42 , C07C213/04 , C07C213/10 , Y02P20/582 , C07C215/08 , C07C215/10
摘要： Apparatus and processes for continuous distillative separation of a mixture comprising one or more alkanolamine(s), wherein the separation is performed in one or more dividing wall column(s) and the alkanolamine or the alkanolamines is/are withdrawn as a side draw stream or side draw streams (side fraction(s)).
摘要翻译：将包含一种或多种烷醇胺的混合物的连续蒸馏分离的装置和方法，其中在一个或多个分隔壁塔和链烷醇胺或链烷醇胺中进行分离作为侧馏分流或侧馏分流（侧馏分）。

18. 发明申请

US20100274055A1 METHOD FOR PRODUCING AN AMINE 有权
标题翻译：生产氨的方法
公开(公告)号：US20100274055A1
公开(公告)日：2010-10-28
申请号：US12809649
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/44 , B01J27/185 , B01J23/883 , B01J23/755 , B01J23/835 , B01J23/745
CPC分类号： B01J23/883 , B01J23/002 , B01J23/76 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/44 , B01J2523/48 , B01J2523/842 , B01J2523/847 , B01J2523/68 , B01J2523/51 , B01J2523/43 , B01J2523/53 , B01J2523/54
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, nickel, and iron, and 0.2 to 5.5% by weight of at least one oxygen compound of tin, lead, bismuth, molybdenum, antimony or phosphorus, calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 and H3PO4 respectively; and wherein the catalytically active composition of the catalyst does not comprise any copper.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆和含镍催化剂存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，镍和铁的氧化合物和0.2至5.5重量％的至少一种氧化合物的锡，铅，铋，钼，锑或磷，分别计算为SnO，PbO，Bi2O3，MoO3，Sb2O3和H3PO4; 并且其中催化剂的催化活性组合物不包含任何铜。

19. 发明申请

US20100084257A1 METHOD FOR THE CONTINUOUS SEPARATION OF MIXTURES COMPRISING MORPHOLINE (MO), MONOAMINODIGLYCOL (ADG), AMMONIA AND WATER BY MEANS OF DISTILLATION 有权
标题翻译：通过蒸馏法连续分离包含摩尔（MO），单胺基（ADG），氨和水的混合物的方法
公开(公告)号：US20100084257A1
公开(公告)日：2010-04-08
申请号：US12443563
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Bussmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Bussmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： C07C213/10 , C07D295/02 , B01D3/14 , C07C217/08
CPC分类号： C07D295/027
摘要： Processes for the continuous fractional distillation of a mixture comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process comprising: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from K10 to a second distillation column K20 in which water and organic products are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar, (iii) feeding a bottom fraction from K20 to a third distillation column K30, wherein the column K30 is a dividing wall column (DWC) which preferably has a dividing wall (DW) in the longitudinal direction of the column to form an upper combined column region (1), a lower combined column region (6), an inflow part (2, 4) having an enrichment section (2) and a stripping section (4), and also an offtake part (3, 5) having an enrichment section (3) and a stripping section (5), with the bottoms from K20 being fed in in the upper or middle third of the inflow part (2, 4), based on the number of theoretical plates of the inflow part, ADG and organic products having a boiling point of >190° C. (1.013 bar) being discharged at the bottom, organic products having a boiling point of ≦128° C. (1.013 bar) being discharged at the top and MO being discharged from the middle or lower third of the offtake part (3, 5) (side offtake), based on the number of theoretical plates of the offtake part.
摘要翻译：用于从二甘醇（DEG）与氨的反应连续分馏含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在第一蒸馏塔K10顶部; （ii）将底部馏分从K10进料至第二蒸馏塔K20，其中水和有机产物在顶部分离出，顶部温度为45-98℃，压力范围为 0.1至15巴，（iii）从K20向第三蒸馏塔K30供给底部馏分，其中塔K30是分隔壁塔（DWC），其优选在塔的纵向方向上具有分隔壁（DW）至形成上部组合列区域（1），下部组合列区域（6），具有浓缩部分（2）和剥离部分（4）的流入部分（2,4），以及出口部分（3， 5）具有富集部分（3）和汽提部分（5），其中来自K20的底部在流入部分（2,4）的上部或中部三分之一中被输入，基于理论塔板的数量流入部件，ADG和沸点> 190℃（1.013巴）的有机产物在底部排出，有机原料沸点为＆nlE; 128℃（1.013巴）在顶部排出，MO从出料部（3,5）的中部或下部三分之一（出口侧）排出，基于理论板的出口部分。

20. 发明授权

US07518020B2 Method for controlling the reactor admission temperature during the production of methylamine 有权
标题翻译：在甲胺生产过程中控制反应器入口温度的方法
公开(公告)号：US07518020B2
公开(公告)日：2009-04-14
申请号：US10573185
申请日：2004-09-24
申请人： Werner Reutemann , Rolf Wambsganβ , Frank Poplow , Theodor Weber , Karl-Heinz Roβ , Manfred Julius
发明人： Werner Reutemann , Rolf Wambsganβ , Frank Poplow , Theodor Weber , Karl-Heinz Roβ , Manfred Julius
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C211/04
摘要： The invention relates to a process for preparing methylamines by gas-phase reaction of methanol and ammonia as starting materials at a pressure in the range from 15 to 30 bar in the presence of heterogeneous catalyst. The starting materials are vaporized in one or more heat exchangers (1, 2, 3), superheated to produce a feed gas stream and subsequently fed into a reactor (4), with the mixing of the starting materials being able to be carried out in the feed stream to one of the heat exchangers (1, 2, 3) or at any desired position in a heat exchanger (1, 2, 3). A product gas stream comprising monomethylamine, dimethylamine and trimethylamine and also reaction by-products is taken off from the reactor (4). To control the reactor inlet temperature of the starting materials to a temperature in the range from 360° C. to 370° C., all or some of the feed gas stream or the product gas stream is passed through an adjustable valve (5) in order to vary the pressure and thus the condensation temperature.
摘要翻译：本发明涉及通过甲醇和氨作为起始原料在非均相催化剂存在下在15至30巴的压力下气相反应制备甲胺的方法。起始材料在一个或多个热交换器（1,2,3）中蒸发，过热以产生进料气流，并随后进料到反应器（4）中，原料的混合能够进行到一个热交换器（1,2,3）或在热交换器（1,2,3）中的任何期望位置的进料流。从反应器（4）中取出包含一甲胺，二甲胺和三甲胺以及反应副产物的产物气流。为了将原料的反应器入口温度控制在360℃至370℃的温度范围内，所有或一些进料气流或产物气流通过可调节阀（5），其中以改变压力，从而改变冷凝温度。

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