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11. 发明授权

US5302479A Crystals of hydroxygallium phthalocyanine, method of preparing the crystals, photoconductive material comprising the crystals, and electrophotographic photoreceptor comprising the material 失效
标题翻译：羟基镓酞菁的晶体，晶体的制备方法，包含晶体的光电导材料和包含该材料的电子照相感光体
公开(公告)号：US5302479A
公开(公告)日：1994-04-12
申请号：US873026
申请日：1992-04-24
申请人： Katsumi Daimon , Katsumi Nukada , Akira Imai , Masakazu Iijima , Kazuo Yamasaki , Kiyokazu Mashimo , Yasuo Sakaguchi , Toru Ishii
发明人： Katsumi Daimon , Katsumi Nukada , Akira Imai , Masakazu Iijima , Kazuo Yamasaki , Kiyokazu Mashimo , Yasuo Sakaguchi , Toru Ishii
IPC分类号： C09B67/12 , C09B67/50 , G03G5/06 , G03G5/00 , G03G15/00
CPC分类号： G03G5/0696 , C09B67/0016 , C09B67/0026
摘要： Crystals of hydroxygallium phthalocyanine, a method of preparing the crystals, a photoconductive material containing the crystals, and an electrophotographic photoreceptor having the material. The photoreceptor has excellent electrophotographic characteristics. The crystals of hydroxygallium phthalocyanine have distinct diffraction peaks at (i) 7.5.degree., 9.9.degree., 12.5.degree., 16.3.degree., 18.6.degree., 25.1.degree. and 28.3.degree., or (ii) 7.7.degree., 16.5.degree., 25.1.degree. and 26.6.degree., or (iii) 7.9.degree., 16.5.degree., 24.4.degree. and 27.6.degree., or (iv) 7.0.degree., 7.5.degree., 10.5.degree., 11.7.degree., 12.7.degree., 17.3.degree., 8.1.degree., 24.5.degree., 26.2.degree. and 27.1.degree., or (v) 6.8.degree., 12.8.degree., 15.8.degree. and 26.0.degree. or (vi) 7.4.degree., 9.9.degree., 25.0.degree., 26.0.degree., and 28.2.degree. of the Bragg angle (2.theta..+-.0.2) in the X-ray diffraction spectrum. The electrophotographic photoreceptor has a light-sensitive layer containing the photoconductive material of the crystals.
摘要翻译：羟基镓酞菁的晶体，晶体的制备方法，含有晶体的感光材料和具有该材料的电子照相感光体。感光体具有优异的电子照相特性。羟基镓酞菁的晶体在（i）7.5度，9.9度，12.5度，16.3度，18.6度，25.1度和28.3度，或（ii）7.7度，16.5度，25.1度和26.6度处具有不同的衍射峰，或（iii）7.9度，16.5度，24.4度和27.6度，或（iv）7.0度，7.5度，10.5度，11.7度，12.7度，17.3度，8.1度，24.5度，26.2度和27.1度，或（v）6.8度，12.8度，15.8度和26.0度，或（vi）布拉格角（2（θ）±0.2）的7.4度，9.9度，25.0度，26.0度和28.2度）射线衍射谱。电子照相感光体具有含有晶体光导材料的感光层。

12. 发明授权

US5302710A Phthalocyanine mixed crystal and electrophotographic photoreceptor containing the same 失效
标题翻译：酞菁混晶和含有它们的电子照相感光体
公开(公告)号：US5302710A
公开(公告)日：1994-04-12
申请号：US927967
申请日：1992-08-11
申请人： Katsumi Nukada , Akira Imai , Katsumi Daimon , Masakazu Iijima
发明人： Katsumi Nukada , Akira Imai , Katsumi Daimon , Masakazu Iijima
IPC分类号： C09B47/04 , C09B67/22 , G03G5/06 , C09B47/32
CPC分类号： C09B67/0035 , G03G5/0696
摘要： A phthalocyanine mixed crystal comprising a halogenated indium phthalocyanine and a halogenated gallium phthalocyanine and an electrophotographic photoreceptor containing the phthalocyanine mixed crystal. The phthalocyanine mixed crystal is a charge generating material which provides an electrophotographic photoreceptor excellent in sensitivity, stability on repeated use, and environmental stability.
摘要翻译：包含卤化铟酞菁和卤化镓酞菁的酞菁混合晶体和含有酞菁混合晶体的电子照相感光体。酞菁混合晶体是电荷产生材料，其提供敏感性优异，重复使用时的稳定性和环境稳定性优异的电子照相感光体。

13. 发明授权

US5292604A Phthalocyanine crystal of mixed pigments and electrophotographic photoreceptor using the same 失效
标题翻译：混合颜料的酞菁结晶和使用其的电子照相感光体
公开(公告)号：US5292604A
公开(公告)日：1994-03-08
申请号：US898010
申请日：1992-06-16
申请人： Katsumi Nukada , Akira Imai , Katsumi Daimon , Masakazu Iijima
发明人： Katsumi Nukada , Akira Imai , Katsumi Daimon , Masakazu Iijima
IPC分类号： C09B47/04 , C09B67/22 , C09B67/50 , G03G5/06 , G03G5/00 , G03G15/00
CPC分类号： G03G5/0696 , C09B67/0026 , C09B67/0035
摘要： A phthalocyanine crystal of mixed pigments of oxytitanium phthalocyanine and a halogenated gallium phthalocyanine or a halogenated indium phthalocyanine is disclosed. The phthalocyanine crystal of mixed pigments is used as a charge generating material which provides an electrophotographic photoreceptor excellent in sensitivity, stability on repeated use, and environmental stability.
摘要翻译：公开了氧钛酞菁和卤化镓酞菁或卤化铟酞菁的混合颜料的酞菁结晶。混合颜料的酞菁晶体用作电荷产生材料，其提供敏感性优异，重复使用时的稳定性和环境稳定性优异的电子照相感光体。

14. 发明授权

US5463044A Process for preparing chlorogallium phthalocyanine crystal 失效
标题翻译：制备氯镓酞菁晶体的方法
公开(公告)号：US5463044A
公开(公告)日：1995-10-31
申请号：US107977
申请日：1993-08-18
申请人： Katsumi Nukada , Akira Imai , Masakazu Iijima
发明人： Katsumi Nukada , Akira Imai , Masakazu Iijima
IPC分类号： C07D487/22 , C09B47/067 , C09B47/073 , C09B47/08 , C09B67/12 , C09B67/50 , G03G5/06
CPC分类号： G03G5/0696 , C09B67/0016 , C09B67/0026
摘要： A process for preparing chlorogallium phthalocyanine comprising the steps of: reacting gallium trichloride and phthalonitrile or diiminoisoindoline in an aromatic hydrocarbon solvent; and treating the resulting chlorogallium phthalocyanine with a second solvent different from the aromatic hydrocarbon solvent.
摘要翻译：制备氯镓酞菁的方法，包括以下步骤：将三氯化镓和邻苯二甲腈或二亚氨基异吲哚啉在芳烃溶剂中反应; 并用不同于芳烃溶剂的第二溶剂处理所得氯镓酞菁。

15. 发明授权

US5416207A Dichlorotin phthalocyanine crystal, process for producing the same, and electrophotographic photoreceptor using the same 失效
标题翻译：二氯酞菁结晶，其制造方法和使用其的电子照相感光体
公开(公告)号：US5416207A
公开(公告)日：1995-05-16
申请号：US144012
申请日：1993-11-01
申请人： Akira Imai , Katsumi Nukada , Satsumi Daimon , Masakazu Iijima , Toru Ishii , Yasuo Sakaguchi , Kiyokazu Mashimo
发明人： Akira Imai , Katsumi Nukada , Satsumi Daimon , Masakazu Iijima , Toru Ishii , Yasuo Sakaguchi , Kiyokazu Mashimo
IPC分类号： C09B67/00 , C09B67/12 , C09B67/50 , G03G5/06
CPC分类号： C09B67/0016 , C09B67/0023 , C09B67/0026 , G03G5/0696
摘要： A dichlorotin phthalocyanine crystal showing, in the X-ray diffractometry using a CuK.sub..alpha. ray, a peak at a Bragg angle (2.theta..+-.0.2.degree.) of 28.2.degree. with any other peak(s) observed at a Bragg angle(s) between 25.degree. and 30.degree. having an intensity of not more than 30% of that of the peak at 28.2.degree.. The crystal is useful as a photoconductive material having sensitivity in the longer wavelength region. The electrophotographic photoreceptor containing the crystal exhibits high sensitivity and excellent durability.
摘要翻译：在使用CuKα射线的X射线衍射中显示出在布拉格角（2θ+/- 0.2°）为28.2°的峰和在布拉格角（s）处观察到的任何其它峰的二氯鎓酞菁晶体）在25°和30°之间，强度不大于28.2℃峰值的30％。该晶体可用作在较长波长区域具有灵敏度的光电导材料。含有晶体的电子照相感光体具有高灵敏度和优异的耐久性。

16. 发明授权

US5336578A Phthalocyanine mixed crystal and electrophotographic photoreceptor containing the same 失效
标题翻译：酞菁混晶和含有它们的电子照相感光体
公开(公告)号：US5336578A
公开(公告)日：1994-08-09
申请号：US2251
申请日：1993-01-08
申请人： Katsumi Nukada , Akira Imai , Katsumi Damion , Masakazu Iijima
发明人： Katsumi Nukada , Akira Imai , Katsumi Damion , Masakazu Iijima
IPC分类号： C09B67/50 , G03G5/05 , G03G5/06
CPC分类号： G03G5/0696 , G03G5/0564 , G03G5/0614
摘要： A novel phthalocyanine mixed crystal comprising a dihalogenotin phthalocyanine and a halogenogallium phthalocyanine and an electrophotographic photoreceptor containing the same are disclosed. The phthalocyanine mixed crystal preferably has an intense X-ray diffraction peak at a Bragg angle (2.theta..+-.0.2.degree.) of 26.9. The phthalocyanine mixed crystal is useful as a charge generating material which provides an electrophotographic photoreceptor excellent in sensitivity, stability on repeated use, and environmental stability.
摘要翻译：公开了包含二卤代锡酞菁和卤素镓酞菁的新型酞菁混合晶体和含有它们的电子照相感光体。酞菁混晶优选在布拉格角（2θ+/- 0.2°）为26.9时具有强烈的X射线衍射峰。酞菁混晶可用作电荷产生材料，其提供敏感性优异，重复使用时的稳定性和环境稳定性优异的电子照相感光体。

17. 发明授权

US5734003A Charge transporting polymer, process for producing the same, and organic electronic device containing the same 失效
标题翻译：电荷输送性聚合物，其制造方法以及含有它们的有机电子器件
公开(公告)号：US5734003A
公开(公告)日：1998-03-31
申请号：US763887
申请日：1996-12-11
申请人： Masahiro Iwasaki , Akira Imai , Katsumi Nukada , Katsuhiro Sato
发明人： Masahiro Iwasaki , Akira Imai , Katsumi Nukada , Katsuhiro Sato
IPC分类号： C08G65/34 , G03G5/06 , G03G5/07 , C08G59/68
CPC分类号： C08G65/34 , G03G5/075 , G03G5/076 , G03G5/0696
摘要： A charge transporting polymer represented by formula ##STR1## wherein R represents a hydrogen atom, an alkyl group, an acyl group or --CONH--R, wherein R' represents an alkyl group or a substituted or unsubstituted aryl group; R.sub.1 and R.sub.2, which may be the same or different, each represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or unsubstituted aryl group; X represents a substituted or unsubstituted divalent aromatic group; y represents 0 or 1; m represents 0 or 1; n represents an integer of 1 to 5; and p represents an integer of 5 to 5000,a process for producing the same, and an organic electron device containing the same, such as an electrophotographic photoreceptor are disclosed. The charge transporting polymer is excellent in solubility, film-forming properties, mechanical strength, positive hole mobility, and stability to repeated use.
摘要翻译：由式（I）表示的电荷传输性聚合物其中R表示氢原子，烷基，酰基或-CONH-R，其中R'表示烷基或取代或未取代的芳基 ; 可以相同或不同的R 1和R 2各自表示氢原子，烷基，烷氧基，取代的氨基，卤素原子或取代或未取代的芳基; X表示取代或未取代的二价芳基; y表示0或1; m表示0或1; n表示1〜5的整数， p表示5〜5000的整数，其制造方法和含有该电子照相感光体的有机电子元件被公开。电荷输送性聚合物的溶解性，成膜性，机械强度，空穴迁移率以及重复使用的稳定性优异。

18. 发明授权

US5654119A Organic electronic device comprising charge-transporting polyester and image forming apparatus 失效
标题翻译：包含电荷传输聚酯和成像设备的有机电子器件
公开(公告)号：US5654119A
公开(公告)日：1997-08-05
申请号：US628766
申请日：1996-04-05
申请人： Toru Ishii , Fumio Ojima , Kiyokazu Mashimo , Tomozumi Uesaka , Tomoo Kobayashi , Katsumi Nukada , Akira Imai , Masahiro Iwasaki
发明人： Toru Ishii , Fumio Ojima , Kiyokazu Mashimo , Tomozumi Uesaka , Tomoo Kobayashi , Katsumi Nukada , Akira Imai , Masahiro Iwasaki
IPC分类号： G03G5/07 , G03G5/147 , G03G5/047
CPC分类号： G03G5/1476 , G03G5/075 , G03G5/076 , G03G5/14752 , G03G5/14756 , G03G5/14769
摘要： An organic electronic device comprises a layer containing a charge-transporting polyester comprising a repeating unit comprising at least one of partial structural units represented by the following formulae (I-a) and (I-b) as a partial structure of repeating unit: ##STR1## where the symbols in the above formulae are defined in the specification.
摘要翻译：有机电子器件包括含有电荷输送聚酯的层，其包含重复单元，该重复单元包含由下式（Ia）和（Ib）表示的部分结构单元中的至少一种作为重复单元的部分结构：（Ia ）（Ib）其中上述公式中的符号在说明书中定义。

19. 发明授权

US5639581A Charge transporting polymer, process for producing the same, and organic electronic device containing the same 失效
标题翻译：电荷输送性聚合物，其制造方法以及含有它们的有机电子器件
公开(公告)号：US5639581A
公开(公告)日：1997-06-17
申请号：US543913
申请日：1995-10-17
申请人： Masahiro Iwasaki , Akira Imai , Katsumi Nukada , Katsuhiro Sato
发明人： Masahiro Iwasaki , Akira Imai , Katsumi Nukada , Katsuhiro Sato
IPC分类号： C08G65/34 , G03G5/06 , G03G5/07 , G03G5/047
CPC分类号： C08G65/34 , G03G5/075 , G03G5/076 , G03G5/0696
摘要： A charge transporting polymer represented by formula (I): ##STR1## wherein R represents a hydrogen atom, an alkyl group, an acyl group or --CONH--R' wherein R' represents an alkyl group or a substituted or unsubstituted aryl group; R.sub.1 and R.sub.2, which may be the same or different, each represent a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group, a halogen atom, or a substituted or unsubstituted aryl group; X represents a substituted or unsubstituted divalent aromatic group; y represents 0 or 1; m represents 0 or 1; n represents an integer of 1 to 5; and p represents an integer of 5 to 5000,a process for producing the same, and an organic electron device containing the same, such as an electrophotographic photoreceptor are disclosed. The charge transporting polymer is excellent in solubility, film-forming properties, mechanical strength, positive hole mobility, and stability to repeated use.
摘要翻译：由式（I）表示的电荷输送聚合物：其中R表示氢原子，烷基，酰基或-CONH-R'，其中R'表示烷基或取代的或未取代的芳基; 可以相同或不同的R 1和R 2各自表示氢原子，烷基，烷氧基，取代的氨基，卤素原子或取代或未取代的芳基; X表示取代或未取代的二价芳基; y表示0或1; m代表0或1; n表示1〜5的整数， p表示5〜5000的整数，其制造方法和含有该电子照相感光体的有机电子元件被公开。电荷输送性聚合物的溶解性，成膜性，机械强度，空穴迁移率以及重复使用的稳定性优异。

20. 发明授权

US5817739A Charge transporting polymer and organic electronic device containing the same 失效
标题翻译：电荷传输聚合物和含有它的有机电子器件
公开(公告)号：US5817739A
公开(公告)日：1998-10-06
申请号：US732977
申请日：1996-10-16
申请人： Katsumi Nukada , Masahiro Iwasaki , Akira Imai
发明人： Katsumi Nukada , Masahiro Iwasaki , Akira Imai
IPC分类号： C08G63/685 , G03G5/05 , G03G5/07 , G03G5/147 , C08G69/08 , G03G5/047
CPC分类号： C08G63/6856 , G03G5/056 , G03G5/0575 , G03G5/073 , G03G5/076 , G03G5/14752 , G03G5/14769
摘要： A charge transporting polymer represented by formula (I-1) or (I-2) and an electrophotographic photoreceptor containing the same: ##STR1## wherein Y and Z each represents a divalent hydrocarbon group; A represents a group represented by formula: ##STR2## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an alkoxy group, a substituted amino group or a halogen atom; X represents a substituted or unsubstituted divalent aromatic group; n represents an integer of 1 to 5; and k represents 0 or 1; B and B' each represents --O--(Y--O).sub.m --H or --O--(Y--O).sub.m --CO--Z--CO--OR' (wherein R' represents a hydrogen atom, an alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group; Y and Z are as defined above; and m represents an integer of 1 to 5); m represents an integer of 1 to 5; and p represents an integer of 5 to 5000.The charge transporting polymer has excellent solubility and film-forming properties and can have its ionizing potential controlled.
摘要翻译：由式（I-1）或（I-2）表示的电荷输送聚合物和含有它的电子照相感光体：（I-1）表示二价烃基; A表示由下式表示的基团：其中R 1和R 2各自表示氢原子，烷基，烷氧基，取代的氨基或卤原子; X表示取代或未取代的二价芳基; n表示1〜5的整数，并且k表示0或1; B和B'各自表示-O-（YO）mH或-O-（YO）m -CO-Z-CO-OR'（其中R'表示氢原子，烷基，取代或未取代的芳基或取代或未取代的芳烷基; Y和Z如上所定义; m表示1〜5的整数）; m表示1〜5的整数， p表示5〜5000的整数。电荷输送性聚合物的溶解性和成膜性优异，可以控制电离电位。

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