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11. 发明授权

US06458293B1 Polyurea coatings from dimethyl-substituted polyaspartic ester mixtures 失效
公开(公告)号：US06458293B1
公开(公告)日：2002-10-01
申请号：US09363174
申请日：1999-07-29
申请人： Richard R. Roesler , Edward P. Squiller
发明人： Richard R. Roesler , Edward P. Squiller
IPC分类号： C09K300
CPC分类号： C08G18/3821 , C07C229/24 , C09D175/02
摘要： A method for making a polyurea coating by: (a) coating a substrate with a coating composition containing effective coating-forming amounts of (i) a polyisocyanate component, and (ii) an polyaspartic ester mixture. The invention also relates to the coatings made by the method, the polyaspartic ester mixtures used to make the coatings, and methods to make the mixtures.

12. 发明授权

US06183870B2 Coating compositions containing polyisocyanates and aspartate-terminated urea/urethane prepolymers 失效
标题翻译：含有多异氰酸酯和天冬氨酸封端的脲/氨基甲酸酯预聚物的涂料组合物
公开(公告)号：US06183870B2
公开(公告)日：2001-02-06
申请号：US09389859
申请日：1999-09-02
申请人： P. Richard Hergenrother , Lyubov K. Gindin , Richard R. Roesler , Edward P. Squiller
发明人： P. Richard Hergenrother , Lyubov K. Gindin , Richard R. Roesler , Edward P. Squiller
IPC分类号： B32B2700
CPC分类号： C09D175/12 , C08G18/10 , C08G2105/02 , Y10T428/31551 , C08G18/3821
摘要： The present invention relates to coating compositions containing a) 15 to 35% by weight, based on the weight of components a) and b), of aspartate-terminated urea/urethane prepolymers that are based on the reaction products of i) NCO prepolymers having a functionality of 1.8 to 2.2 and based on linear or branched aliphatic diisocyanates and ii) diaspartates prepared from linear or branched aliphatic diamines, b) 65 to 85% by weight, based on the weight of components a) and b), of diaspartate ii) and c) a polyisocyanate adduct prepared from aliphatic diisocyanates and having an average functionality of 2.8 to 3.1, wherein components a), b) and c) are present in amounts sufficient to provide an equivalent ratio of aspartate groups to isocyanate groups of 1.2:1 to 1.0:1.3. The present invention also relates to coatings prepared from these coating compositions.
摘要翻译：本发明涉及涂料组合物，该组合物含有基于a）和b）组分重量的15至35重量％的天冬氨酸酯封端的脲/氨基甲酸酯预聚物，其基于以下反应产物：i）具有官能度的NCO预聚物基于直链或支链脂族二异氰酸酯和ii）由直链或支链脂族二胺制备的天冬氨酸盐，b）基于组分a）和b）的重量比为65至85重量％的二天冬氨酸盐ii）和c）由脂族二异氰酸酯制备并具有2.8至3.1的平均官能度的多异氰酸酯加合物，其中组分a），b）和c）以足以提供天冬氨酸酯基与异氰酸酯基的当量比为1.2:1至1.0:1的量存在： 1.3本发明还涉及由这些涂料组合物制备的涂料。

13. 发明授权

US5691439A Low surface energy polyisocyanates and their use in one- or two-component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
公开(公告)号：US5691439A
公开(公告)日：1997-11-25
申请号：US767056
申请日：1996-12-16
申请人： William E. Slack , Philip E. Yeske , Edward P. Squiller
发明人： William E. Slack , Philip E. Yeske , Edward P. Squiller
IPC分类号： C08G18/02 , C08G18/61 , C08G18/71 , C08G18/73 , C08G18/77 , C08G18/78 , C08G18/79 , C09D175/04
CPC分类号： C09D175/04 , C08G18/61 , C08G18/718 , C08G18/7831 , C08G18/7837
摘要： The present invention relates to polyisocyanate adducts containing allophanate groups, siloxane groups and optionally isocyanurate groups that are prepared by reacting compounds a) which i) are substantially free of hydroxyl groups and isocyanate groups, ii) have an average of at least two urethane groups per molecule and iii) contain 0 to 50% by weight of siloxane groups, based on the weight of the polyisocyanate adducts, with an excess quantity, based on the equivalents of urethane groups, of polyisocyanates b), which optionally contain siloxane groups, to form polyisocyanate adducts and optionally removing at least a portion of the unreacted excess polyisocyanates b), provided that compounds a) and polyisocyanates b) contain a total of at least 0.001% by weight, of siloxane groups, based on the weight of the polyisocyanate adducts. The present invention also relates to a process for preparing these polyisocyanates adducts, to blends of the polyisocyanates with other polyisocyanates that which do not contain siloxane groups and to the use of the polyisocyanate adducts or polyisocyanate blends, optionally in blocked form, in one- or two-component coating compositions.
摘要翻译：本发明涉及含有脲基甲酸酯基团，硅氧烷基团和任选的异氰脲酸酯基团的多异氰酸酯加合物，其通过使i）基本上不含羟基和异氰酸酯基团的化合物a）制备，ii）平均具有至少两个氨基甲酸酯基团分子和iii）包含0至50重量％的硅氧烷基团，基于多异氰酸酯加合物的重量，基于氨基甲酸酯基团的当量，任选地含有硅氧烷基团的多异氰酸酯b）的过量形成多异氰酸酯加合物和任选地除去至少一部分未反应的过量多异氰酸酯b），条件是化合物a）和多异氰酸酯b）基于多异氰酸酯加合物的重量含有至少0.001重量％的硅氧烷基团。本发明还涉及制备这些多异氰酸酯加合物的方法，多异氰酸酯与不含硅氧烷基团的其它多异氰酸酯的共混物，以及任选地以封闭形式使用多异氰酸酯加合物或多异氰酸酯共混物，双组分涂料组合物。

14. 发明授权

US5574122A Low surface energy polyisocyanates and their use in one- or two-component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
公开(公告)号：US5574122A
公开(公告)日：1996-11-12
申请号：US536556
申请日：1995-09-29
申请人： Philip E. Yeske , Edward P. Squiller , William E. Slack
发明人： Philip E. Yeske , Edward P. Squiller , William E. Slack
IPC分类号： C08G18/61 , C08G18/28 , C08G18/77 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C07C269/02 , C07F7/10
CPC分类号： C08G18/809 , C08G18/289 , C08G18/7837 , C08G18/791
摘要： The present invention is directed to a polyisocyanate mixturei) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate,ii) containing up to 25% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126),iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane or urea groups and such that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. andiv) containing siloxane groups (calculated as SiO, MW 44) in an amount of 0.002 to 50% by weight,wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing one isocyanate-reactive group directly attached to a carbon atom and one or more siloxane groups. The present invention is also directed to a process for the production of this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
摘要翻译：本发明涉及NCO含量为5-35重量％并由有机二异氰酸酯制备的多异氰酸酯混合物，ii）含有至多25重量％的异氰脲酸酯基（以N 3，C 3，O 3， MW 126），iii）含有脲基甲酸酯基团，其量使得比氨基甲酸酯或脲基团具有更多当量的脲基甲酸酯基团，并且使得多异氰酸酯混合物在25℃保存3个月时保持稳定和均匀，并且iv）含硅氧烷基团（以SiO，MW 44计），其量为0.002至50重量％，其中前述百分比是基于多异氰酸酯混合物的固体含量，不包括任何未反应的有机二异氰酸酯，并且其中硅氧烷基团通过使异氰酸酯基与含有直接连接到碳原子和一个或多个硅氧烷基团的一个异氰酸酯反应性基团的化合物反应。本发明还涉及在单组分或双组分涂料组合物中制备该多异氰酸酯混合物及其用途，任选为封闭形式的异氰酸酯组分的方法。

15. 发明授权

US5154950A Rapid curing, light stable, two-component polyurethane coating compositions 失效
标题翻译：快速固化，光稳定，双组分聚氨酯涂料组合物
公开(公告)号：US5154950A
公开(公告)日：1992-10-13
申请号：US447331
申请日：1989-12-07
申请人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
发明人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
IPC分类号： C08G18/08 , C08G18/18
CPC分类号： C08G18/089 , C08G18/1891 , C08G2150/50
摘要： The present invention is directed to a process for the preparation of a polyurethane coating by a) preparing a coating composition having an improved potlife fromi) a compound containing at least two hydroxyl groups,ii) a polyisocyanate containing aliphatically-, cycloaliphatically- or araliphatically-bound isocyanate groups,iii) about 0.005 to 2.0 to weight percent, based on the weight of components i) and ii), of a tine catalyst andiv) at least about 50 mole percent, based on the tin catalyst, of hydrogen chloride,b) applying the coating composition to a substrate andc) curing the coating composition, optionally in the presence of an amine vapor, to form the polyurethane coating.
摘要翻译：本发明涉及一种制备聚氨酯涂层的方法，该方法是：a）制备具有改善的适用期的涂料组合物，其含有i）含有至少两个羟基的化合物，ii）含有脂族，脂环或芳烃的多异氰酸酯异氰酸酯基团，iii）基于催化剂组分i）和ii）的重量，约0.005至2.0重量％，和iv）基于锡催化剂的至少约50摩尔％的氯化氢 b）将涂料组合物施用到基材上，以及c）任选地在胺蒸气的存在下固化涂料组合物以形成聚氨酯涂层。

16. 发明授权

US5124447A Ambient temperature curable one-component polyurethane or polyurea compositions 失效
标题翻译：环境温度可固化单组分聚氨酯或聚脲组合物
公开(公告)号：US5124447A
公开(公告)日：1992-06-23
申请号：US558735
申请日：1990-07-27
申请人： Edward P. Squiller , Peter H. Markusch
发明人： Edward P. Squiller , Peter H. Markusch
IPC分类号： C08G18/10 , C08G18/32 , C08G18/80 , C09D175/00
CPC分类号： C08G18/10 , C08G18/3259 , C08G18/8067 , C09D175/00
摘要： The present invention is directed to a one-component polyurethane or polyurea composition which may be cured at either ambient or elevated temperature and is based ona) a liquid blocked polyisocyanate wherein the isocyanate groups have been blocked with a phenolic blocking agent.b) a solid polyamine salt which is insoluble in and dispersed throughout the liquid blocked polyisocyanate, the solid polyamine salt being based on the reaction product of a polyamine with an organic or inorganic acid.The present invention is also directed to a process for the preparation of a high molecular weight polymer by heating the one-component composition at elevated temperature or by adding a polar solvent to the above coating composition and allowing the composition to cure.
摘要翻译：本发明涉及一种单组分聚氨酯或聚脲组合物，其可以在环境温度或升高的温度下固化，并且基于a）液体封闭的多异氰酸酯，其中异氰酸酯基团已被酚封闭剂封闭。 b）固体多胺盐，其不溶于和分散在整个液体封闭的多异氰酸酯中，固体多胺盐基于多胺与有机或无机酸的反应产物。本发明还涉及通过在高温下加热单组分组合物或通过向上述涂料组合物中加入极性溶剂并使组合物固化来制备高分子量聚合物的方法。

17. 发明授权

US5646227A Low surface energy polyisocyanates and their use in one- or two-component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
公开(公告)号：US5646227A
公开(公告)日：1997-07-08
申请号：US593129
申请日：1996-02-01
申请人： William E. Slack , Edward P. Squiller , Philip E. Yeske
发明人： William E. Slack , Edward P. Squiller , Philip E. Yeske
IPC分类号： C08G18/70 , C08G18/61 , C08G18/77 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/04 , C08G77/04
CPC分类号： C08G18/61 , C08G18/7837 , C08G18/791 , C08G18/8054
摘要： The present invention is directed to a polyisocyanate mixturei) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate,ii) containing up to 25% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126),iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane and urea groups and such that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. andiv) containing siloxane groups (calculated as SiO, MW 44) in an amount of 0.002 to 50% by weight,wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein the siloxane groups are incorporated by reacting an isocyanate group with a compound containing two or more isocyanate-reactive groups directly attached to carbon atoms and one or more siloxane groups. The present invention is also directed to a process for the production of this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
摘要翻译：本发明涉及NCO含量为5-35重量％并由有机二异氰酸酯制备的多异氰酸酯混合物，ii）含有至多25重量％的异氰脲酸酯基（以N 3，C 3，O 3， MW 126），iii）含有脲基甲酸酯基团，其量使得比氨基甲酸酯和脲基团具有更多当量的脲基甲酸酯基团，并且使得多异氰酸酯混合物在25℃保存3个月并保持稳定和均匀，以及iv）含硅氧烷基团（以SiO，MW 44计），其量为0.002至50重量％，其中前述百分比是基于多异氰酸酯混合物的固体含量，不包括任何未反应的有机二异氰酸酯，并且其中硅氧烷基团通过使异氰酸酯基团与含有直接连接到碳原子上的两个或多个异氰酸酯反应性基团和一个或多个硅氧烷基团的化合物反应。本发明还涉及在单组分或双组分涂料组合物中制备该多异氰酸酯混合物及其用途，任选为封闭形式的异氰酸酯组分的方法。

18. 发明授权

US5576411A Low surface energy polyisocyanates and their use in one-or two component coating compositions 失效
标题翻译：低表面能多异氰酸酯及其在一种或两种组分涂料组合物中的用途
公开(公告)号：US5576411A
公开(公告)日：1996-11-19
申请号：US306553
申请日：1994-09-14
申请人： Philip E. Yeske , Edward P. Squiller , William E. Slack
发明人： Philip E. Yeske , Edward P. Squiller , William E. Slack
IPC分类号： C08G18/77 , C07D251/34 , C08G18/50 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C08G18/28
CPC分类号： C08G18/8087 , C07D251/34 , C08G18/5015 , C08G18/7837 , C08G18/791 , C08G18/8054
摘要： The present invention is directed to a polyisocyanate mixturei) having an NCO content of 5 to 35% by weight and prepared from an organic diisocyanate,ii) containing at least 1% by weight of isocyanurate groups (calculated as N.sub.3, C.sub.3, O.sub.3, MW 126),iii) containing allophanate groups in an amount such that there are more equivalents of allophanate groups than urethane groups andiv) containing fluorine (calculated as F, AW 19) in an amount of 0.001 to 50% by weight,wherein the preceding percentages are based on the solids content of the polyisocyanate mixture, excluding any unreacted organic diisocyanate, and wherein fluorine is incorporated by reacting an isocyanate group with a compound containing two or more carbon atoms, one or more hydroxyl groups and one or more fluorine atoms to form urethane groups and converting a sufficient amount of these urethane groups to allophanate groups to satisfy the requirements of iii), provided that the polyisocyanate mixture contains sufficient allophanate groups to ensure that the polyisocyanate mixture remains stable and homogeneous in storage for 3 months at 25.degree. C. The present invention is also directed to a process for the production this polyisocyanate mixture and to its use, optionally in blocked form, as an isocyanate component in one- or two-component coating compositions.
摘要翻译：本发明涉及NCO含量为5至35重量％并由有机二异氰酸酯制备的多异氰酸酯混合物i），ii）含有至少1重量％的异氰脲酸酯基（以N 3，C 3，O 3， MW 126），iii）含有脲基甲酸酯基团，其量使得比氨基甲酸酯基团具有更多当量的脲基甲酸酯基，和iv）含有0.001至50重量％的氟（以F，AW 19计算），其中前述百分数是基于多异氰酸酯混合物的固体含量，不包括任何未反应的有机二异氰酸酯，并且其中氟通过使异氰酸酯基团与含有两个或更多个碳原子，一个或多个羟基和一个或多个氟原子的化合物反应而引入以形成氨基甲酸酯基团并将足够量的这些氨基甲酸酯基团转化为脲基甲酸酯基团以满足iii）的要求，条件是多异氰酸酯混合物包含足够的全部以确保多异氰酸酯混合物在25℃下储存3个月时保持稳定和均匀。本发明还涉及一种制备该多异氰酸酯混合物的方法及其用途，任选以封闭形式作为异氰酸酯组分在一种或两种组分的涂料组合物中。

19. 发明授权

US5559204A Polyisocyanate/polyamine mixtures and their use for the production of polyurea coatings 失效
标题翻译：多异氰酸酯/多胺混合物及其在聚脲涂料生产中的应用
公开(公告)号：US5559204A
公开(公告)日：1996-09-24
申请号：US449037
申请日：1995-05-24
申请人： Edward P. Squiller , Christian Zweiner
发明人： Edward P. Squiller , Christian Zweiner
IPC分类号： C08G18/30 , C07C251/08 , C09D175/00 , C09D175/04 , C08G18/34
CPC分类号： C07C251/08 , C07C2101/14
摘要： The present invention relates to an aldimine/aspartate corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sub.1 and R.sub.2 may be the same or different and represent optionally substituted hydrocarbon radicals, or R.sub.1 and R.sub.2 together with the .beta.-carbon atom form a cycloaliphatic or heterocyclic ring andR.sub.3 and R.sub.4 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sub.5 and R.sub.6 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less, anda and b represent integers with a value of 1 to 5, provided that the sum of a and b is 2 to 6.The present invention also relates to coating compositions containing these aldimine aspartates and polyisocyanates, and to the use of these coating compositions for the production of polyurea coatings.
摘要翻译：本发明涉及对应于式（I）的醛亚胺/天冬氨酸，其中X表示在100℃或更低的温度下具有n价并且对异氰酸酯基具有惰性的有机基团，R1和 R 2可以相同或不同，表示任选取代的烃基，或者R 1和R 2与β-碳原子一起形成脂环族或杂环，并且R 3和R 4可以相同或不同，表示对于异氰酸酯基团是惰性的有机基团在100℃以下的温度下，R 5和R 6可以相同或不同，表示在100℃以下对异氰酸酯基具有惰性的氢或有机基团，a和b表示与值为1〜5，条件是a和b的总和为2〜6。本发明还涉及含有这些醛二胺天冬氨酸酯和多异氰酸酯的涂料组合物，以及这些涂料组合物的用途用于生产聚脲涂料的产品。

20. 发明授权

US5539006A Rigid foams with improved insulation and physical properties 失效
标题翻译：具有改善绝缘和物理性能的刚性泡沫
公开(公告)号：US5539006A
公开(公告)日：1996-07-23
申请号：US167371
申请日：1993-12-15
申请人： Herman P. Doerge , Edward E. Ball , Steven L. Schilling , Edward P. Squiller
发明人： Herman P. Doerge , Edward E. Ball , Steven L. Schilling , Edward P. Squiller
IPC分类号： C08G18/48 , C08J9/14 , C08J9/06
CPC分类号： C08J9/149 , C08G18/4883 , C08J9/144 , C08G2101/0025 , C08J2375/04 , Y10S521/909
摘要： Rigid polyurethane foams are produced by reacting an organic polyisocyanate with a sucrose-based polyether polyol in the presence of a catalyst and a blowing agent selected from hydrogen-containing chlorofluorocarbons, hydrogen-containing fluorocarbons, hydrocarbons and mixtures thereof. These foams are characterized by good demold and insulation properties.
摘要翻译：通过在催化剂和选自含氢氯氟烃，含氢氟代烃，烃及其混合物的催化剂和发泡剂的存在下使有机多异氰酸酯与蔗糖基聚醚多元醇反应制备刚性聚氨酯泡沫体。这些泡沫的特点是具有良好的脱模和绝缘性能。

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