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    • 15. 发明申请
    • BIODEGRADABLE PACKAGING FILM
    • 生物可拆装包装膜
    • WO2010001268A3
    • 2010-03-25
    • PCT/IB2009052014
    • 2009-05-14
    • KIMBERLY CLARK COWANG JAMES HFUNK SARA A
    • WANG JAMES HFUNK SARAH A
    • C08L67/04B65D65/46C08J5/18C08L3/02C08L67/02C08L67/03
    • C08J5/18B32B5/022B32B9/02B32B9/045B32B9/047B32B27/08B32B27/12B32B27/20B32B27/205B32B27/22B32B27/36B32B2264/102B32B2264/104B32B2270/00B32B2307/50B32B2307/516B32B2307/518B32B2307/54B32B2307/7163B32B2307/724B32B2439/70C08J2303/02C08J2367/02C08J2367/04C08K3/26C08L3/02C08L3/04C08L67/02C08L67/04C08L2666/02C08L2666/18
    • A biodegradable packaging film is provided. The film is formed from a blend that contains a thermoplastic starch and polylactic acid. Starch is a relatively inexpensive natural polymer that is also renewable and biodegradable. Polylactic acid is likewise an inexpensive synthetic polymer that is biodegradable and renewable, yet also capable of providing increased tensile strength to the film. Although providing a good combination of biodegradability/renewability and increased tensile strength, the polylactic acid is also relatively rigid and can result in films having a relatively high stiffness (e.g., high modulus of elasticity) and low ductility. While more ductile than polylactic acid, the thermoplastic starch is often difficult to melt process in film forming processes and very sensitive to moisture and water vapor, reducing its ability to be used as a stand alone packaging film. In an effort to counteract the effect of such polymers, an aliphatic-aromatic copolyester is also employed in the blend of the present invention. While such copolyesters are biodegradable, they also possess the melt properties and ductility that lend them well to the formation of films. Although the combination of these polymers may achieve a good balance between biodegradability/renewability, high tensile strength, and good ductility (e.g., high peak elongation), it is still often difficult to achieve a precise set of mechanical properties as desired for packaging films. In this regard, the blend also contains a filler. Due to its rigid nature, the amount of the filler may be readily adjusted to fine tune the blend to the desired degree of ductility (e.g., peak elongation) and stiffness (e.g., modulus of elasticity).
    • 提供可生物降解的包装膜。 该膜由含有热塑性淀粉和聚乳酸的共混物形成。 淀粉是一种相对便宜的天然聚合物,也是可再生的和可生物降解的。 聚乳酸同样是廉价的合成聚合物,其是可生物降解和可再生的,并且还能够为膜提供增加的拉伸强度。 虽然提供了生物降解性/可再生性和增加的拉伸强度的良好组合,但是聚乳酸也是相对刚性的,并且可以导致具有相对高刚度(例如高弹性模量)和低延展性的膜。 虽然比聚乳酸更具延展性,但是热塑性淀粉在成膜过程中通常难以熔化,对水分和水蒸汽非常敏感,降低了其作为独立包装膜使用的能力。 为了抵消这种聚合物的作用,脂肪族 - 芳族共聚酯也用于本发明的共混物中。 虽然这种共聚酯是可生物降解的,但是它们也具有熔融性能和延展性,使其很好地形成膜。 虽然这些聚合物的组合可以在生物降解性/可再生性,高拉伸强度和良好的延展性(例如高峰值伸长率)之间达到良好的平衡,但是通常难以实现包装膜所需的精确的机械性能。 在这方面,混合物还含有填料。 由于其刚性,可以容易地调整填料的量以将共混物微调至期望的延展性(例如,峰值伸长率)和刚度(例如弹性模量)。
    • 17. 发明申请
    • FRAGRANCED WATER-SENSITIVE FILM
    • 柔软的水敏感膜
    • WO2010001269A2
    • 2010-01-07
    • PCT/IB2009052015
    • 2009-05-14
    • KIMBERLY CLARK COFUNK SARA AWANG JAMES H
    • FUNK SARA AWANG JAMES H
    • C08J5/18B29C47/00B29D7/01
    • C08J5/18A61F13/8405A61L9/012B29C47/0021B29C47/0026B29C47/1063B29C47/1081B29C47/8845B29C47/8855B29C47/8865B29C47/887B29C47/8875B29C47/92B29C2947/92704B29K2105/0029C08J2303/02C08J2303/06C08J2303/08C08J2329/04C08K5/05C08K2201/007C08L3/02C08L3/06C08L3/08C08L29/04C08L67/00C08L2203/16Y10T428/31855
    • A film formed from a water-soluble polymer matrix within which is contained at least one fragrance is provided. The film is water-sensitive (e.g., water-soluble, water-dispersible, etc.) so that upon contact with a sufficient amount of water, the polymer matrix loses its integrity over time to increasingly expose the fragrance to the ambient environment for releasing its odor. The ability to incorporate a fragrance into the polymer matrix is achieved in the present invention by controlling a variety of aspects of the film construction, including the nature of the fragrance, the nature of the water-soluble polymer, the manner in which the polymer matrix and fragrance are melt processed, etc. For example, the fragrance may be injected directly into the extruder and melt blended with the water-soluble polymer. In this manner, the costly and time-consuming steps of pre-encapsulation or pre- compounding of the fragrance into a masterbatch are not required. Furthermore, to obtain a balance between the ability of the fragrance to release the desired odor during use and likewise to minimize the premature exhaustion of the odor during melt processing, the fragrance is selected to have a boiling point (at atmospheric pressure) within a certain range, such as from about 125°C to about 350°C.
    • 提供由其中含有至少一种香料的水溶性聚合物基质形成的膜。 该膜具有水敏性(例如水溶性,水分散性等),使得在与足量的水接触时,聚合物基体随时间失去其完整性,以使香料逐渐暴露于周围环境以释放 其气味 通过控制膜结构的各个方面,包括香料的性质,水溶性聚合物的性质,聚合物基质的性质,在本发明中实现将香料引入聚合物基质中的能力 并且香料被熔融加工等。例如,香料可以直接注入挤出机中并与水溶性聚合物熔融共混。 以这种方式,不需要将预先包封或预混合成母料的昂贵且耗时的步骤。 此外,为了获得香料在使用期间释放所需气味的能力之间的平衡,并且同样使熔体加工期间气味的过早耗尽最小化,香味被选择为在一定程度上具有沸点(大气压) 范围,例如约125℃至约350℃。
    • 18. 发明申请
    • WIPE COATED WITH A BOTANICAL EMULSION HAVING ANITMICROBIAL PROPERTIES
    • 用具有抗微生物特性的植物乳液涂布的擦拭物
    • WO2012077001A2
    • 2012-06-14
    • PCT/IB2011054787
    • 2011-10-26
    • KIMBERLY CLARK COLEE JAEHONGTOPOLKARAEV VASILY AKOENIG DAVID WSCHOLL NEIL TKIM YOUNGSOOKWANG JAMES H
    • LEE JAEHONGTOPOLKARAEV VASILY AKOENIG DAVID WSCHOLL NEIL TKIM YOUNGSOOKWANG JAMES H
    • A01N25/34A01N65/00A01P1/00A47K7/02A47L13/17A61K9/70C09G1/04C11D17/04
    • A01N65/00A01N31/08A01N2300/00A01N25/04A01N25/10A01N25/22A01N25/34A01N65/22
    • An oil-in-water emulsion that is environmentally friendly and also exhibits antimicrobial activity is provided. More specifically, the oil phase of the emulsion includes a botanical oil derived from a plant (e.g., thymol, carvacrol, etc.). Because the botanical oil tends to leach out of the emulsion during storage and before it is used in the desired application, a water-dispersible polymer is also employed in the aqueous phase of the emulsion to enhance long term stability of the oil and, in turn, antimicrobial efficacy. Without intending to be limited by theory, it is believed that the water-dispersible polymer can effectively encapsulate the botanical oil within the emulsion and inhibit its premature release. Once the emulsion is formed, water can then be removed so that it becomes a substantially anhydrous concentrate. In this manner, the water-dispersible polymer will not generally disperse before use and prematurely release the botanical oil. When it is desired, moisture may simply be re-applied to the concentrate to disperse the polymer and activate the release of the botanical oil. Of course, to provide the optimum degree of biocompatibility, the water-dispersible polymer is also a "biopolymer" that is biodegradable and/or renewable.
    • 提供对环境友好并且还显示出抗微生物活性的水包油乳液。 更具体地说,乳剂的油相包括来源于植物的植物油(例如百里酚,香芹酚等)。 由于植物油倾向于在储存过程中以及在用于所需应用之前浸出乳液,因此在乳液的水相中也使用水分散性聚合物以增强油的长期稳定性,并且反过来 ,抗菌功效。 不受理论限制,认为水分散性聚合物可以有效地将植物油包封在乳液中并且抑制其过早释放。 一旦形成乳液,就可以除去水,使其变成基本上无水的浓缩物。 以这种方式,水分散性聚合物在使用前通常不会分散并过早地释放植物油。 当需要时,可以简单地将水分重新施加到浓缩物上以分散聚合物并激活植物油的释放。 当然,为了提供最佳的生物相容性,水分散性聚合物也是可生物降解和/或可再生的“生物聚合物”。