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12. 发明授权

US5627259A Amidation of ester functionalized hydrocarbon polymers 失效
标题翻译：酯官能化烃聚合物的酰胺化
公开(公告)号：US5627259A
公开(公告)日：1997-05-06
申请号：US563518
申请日：1995-11-28
申请人： Warren A. Thaler , Stephen Zushma , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Jacob I. Emert , Keith R. Gorda , Antonio Gutierrez
发明人： Warren A. Thaler , Stephen Zushma , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Jacob I. Emert , Keith R. Gorda , Antonio Gutierrez
IPC分类号： C08F8/32 , C10L1/236 , C10L1/238 , C10L1/2387 , C10L10/00 , C10M133/56 , C08F20/10 , C08G69/26
CPC分类号： C10M133/56 , C08F8/32 , C10L1/2364 , C10L1/2366 , C10L1/238 , C10L1/2387 , C10L10/00 , C10M2215/04 , C10M2215/26 , C10M2217/046 , C10M2217/06
摘要： The present invention is directed to a process for preparing a polymeric amide which comprises the steps of:(A) reacting a mixture of (i) functionalized hydrocarbon polymer containing ester functional groups comprising at least one member selected from the group consisting of substituted alkyl ester functional groups, the substituted alkyl moiety containing at least one electron withdrawing substituent group, and aryl ester functional groups, the hydrocarbon polymer having a number average molecular weight of at least about 500 prior to functionalization, and (ii) an amine having at least one reactive --NH.sub.2 moiety, for a time and under conditions sufficient to form amide groups; and(B) removing from the mixture during step (A) hydroxyl compound released from the ester functional groups in forming the amide groups.The polymeric amides so produced are useful as fuel additives (e.g., detergents) and lubricating oil additives (e.g., dispersants).
摘要翻译：本发明涉及一种制备聚合酰胺的方法，其包括以下步骤：（A）使（i）含有酯官能团的官能化烃聚合物的混合物反应，所述酯官能团含有至少一种选自取代的烷基酯官能团，含有至少一个吸电子取代基的取代的烷基部分和芳基酯官能团，所述烃聚合物在官能化之前具有至少约500的数均分子量，和（ii）具有至少一个反应性-NH 2部分，在足以形成酰胺基团的时间和条件下; 和（B）在步骤（A）期间从混合物中除去在形成酰胺基团时从酯官能团释放的羟基化合物。如此生产的聚合酰胺可用作燃料添加剂（例如洗涤剂）和润滑油添加剂（例如分散剂）。

13. 发明授权

US6037445A Process for the continuous production of functionalized polymers 失效
标题翻译：用于连续生产官能化聚合物的方法
公开(公告)号：US6037445A
公开(公告)日：2000-03-14
申请号：US996
申请日：1997-12-30
申请人： David C. Dankworth , Chris F. Meyer , William B. Eckstrom , Ramesh R. Hemrajani , Salvatore Rea , Jon E. Stanat
发明人： David C. Dankworth , Chris F. Meyer , William B. Eckstrom , Ramesh R. Hemrajani , Salvatore Rea , Jon E. Stanat
IPC分类号： B01J10/00 , B01J19/24 , C08F8/00 , C07C67/00 , C08F6/00 , C08G67/00 , C08J3/00
CPC分类号： B01J19/242 , C08F8/18 , B01J2219/00094 , B01J2219/00103 , B01J2219/00159 , B01J2219/00162 , B01J2219/00166
摘要： A continuous process for functionalizing polymers is disclosed, wherein (A) a liquid comprising the polymer and a gas comprising a functionalizing agent are continuously introduced into a dispersing zone operated in laminar flow with high intensity mixing of the liquid and the gas under functionalization conditions, wherein the mixing is conducted for a period of the dispersing zone residence time at a shear rate effective to form a stable gas-liquid dispersion in which the gas is substantially dissolved or dispersed in the liquid for functionalization, and wherein the shear rate is less than about 5 s.sup.-1 for no more than about 30% of the residence time; (B) the gas-liquid dispersion is continuously passed to a blending zone operated in laminar flow with low intensity mixing under functionalization conditions, wherein the mixing is conducted at a shear rate effective to further dissolve the gas into the liquid for further functionalization; and (C) continuously recovering functionalized polymer. The process can be used to carbonylate unsaturated polymers, and is particularly useful in reacting unsaturated polymers with carbon monoxide in the presence of a catalyst and a co-reactant selected from water, H.sub.2 S, alcohols, and thiols to produce functionalized polymer containing carboxylic (thio)acid or carboxylic (thio)ester functional groups.
摘要翻译：公开了一种用于官能化聚合物的连续方法，其中（A）包含聚合物的液体和包含官能化试剂的气体在功能化条件下以液体和气体的高强度混合连续引入层流操作的分散区中，其中混合在有效形成稳定的气液分散体的剪切速率下进行分散区停留时间，其中气体基本上溶解或分散在用于官能化的液体中，并且其中剪切速率小于约5 s-1不超过约30％的停留时间; （B）在功能化条件下，将气液分散体连续地通过低强度混合层流运行的混合区，其中以有效进一步将气体溶解到液体中以进一步官能化的剪切速率进行混合; 和（C）连续回收官能化聚合物。该方法可用于羰基化不饱和聚合物，并且在催化剂和选自水，H 2 S，醇和硫醇的共反应物存在下使不饱和聚合物与一氧化碳反应以产生含羧酸（硫代）的官能化聚合物）酸或羧基（硫代）酯官能团。

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