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    • 13. 发明授权
    • Stabilization of fluorinated silicone fuser release agents using mercapto functional silicones
    • US07381514B2
    • 2008-06-03
    • US11054086
    • 2005-02-08
    • Lynn J. BluettSamuel KaplanAlexander N. Klymachyov
    • Lynn J. BluettSamuel KaplanAlexander N. Klymachyov
    • G03G13/20B32B25/20
    • G03G15/2057G03G2215/2048Y10T428/3154Y10T428/31663
    • A fuser member having a substrate, an outer layer with a fluoropolymer, and a release agent material coating on the outer layer, wherein the release agent material coating contains (a) a blend with a mercapto functional release agent having the following formula II: wherein A represents —R4—X, wherein R4 represents an alkyl group having from about 1 to about 10 carbons, X represents —SH; R1 and R2 are the same or different and each is selected from the group consisting of an alkyl having from about 1 to about 25 carbons, an aryl having from about 4 to about 10 carbons, and an arylalkyl; R3 is selected from the group consisting of an alkyl having from about 1 to about 25 carbons, an aryl having from about 4 to about 10 carbons, an arylalkyl, and a substituted diorganosiloxane chain having from about 1 to about 500 siloxane units; b and c are numbers and are the same or different and each satisfy the conditions of 1≦b≦10 and 10≦c≦1,000 d and d′ are numbers and are the same or different and are 2 or 3, and e and e′ are numbers and are the same or different and are 0 or 1 and satisfy the conditions that d+e=3 and d′+e′=3 and (b) a fluorinated silicone release agent having the following Formula I: wherein m is a number of from about 0 to about 25 and n is a number of from about 1 to about 25; x/(x+y) is from about 1 percent to about 100 percent; R1 and R2 are selected from the group consisting of alkyl, aryl, arylalkyl, and alkylamino groups; and R3 is selected from the group consisting of alkyl, aryl, arylalkyl, alkylamino, a polyorganosiloxane, and a fluoro-chain of the formula —(CH2)o—(CF2)p—CF3 wherein o is a number of from about 0 to about 25 and p is a number of from about 1 to about 25.
    • 16. 发明授权
    • T-type amino functional release agent for fuser members
    • 用于定影器构件的T型氨基功能性脱模剂
    • US07186462B2
    • 2007-03-06
    • US10877473
    • 2004-06-25
    • David J. GervasiAlexander N. KlymachyovSamuel KaplanSantokh S. BadeshaDouglas B. WilkinsGeorge A. Gibson
    • David J. GervasiAlexander N. KlymachyovSamuel KaplanSantokh S. BadeshaDouglas B. WilkinsGeorge A. Gibson
    • G03G15/20
    • C09D183/08C08L83/08Y10T428/31663
    • A fuser member component to fuse the transferred developed image to the copy substrate, wherein the fuser member includes a substrate, an outer polymeric layer, and a release agent material coating on the outer polymeric layer, and the release agent material coating includes a T-type amino-functional siloxane release agent material having amino-functional groups, and the T-type amino-functional siloxane release agent material has the following Formula I: wherein A represents —R4—X, wherein R4 represents an alkyl group having from about 1 to about 10 carbons, X represents —NH2 or —NHR5NH2 with R5 representing an alkyl group having from about 1 to about 10 carbons; R1 and R2 are the same or different and each is selected from the group consisting of an alkyl having from about 1 to about 25 carbons, an aryl having from about 4 to about 10 carbons, and an arylalkyl; R3 is a substituted diorganosiloxane chain having from about 1 to about 500 siloxane units; b and c are numbers and are the same or different and each satisfy the conditions of 1≦b≦10 and 10≦c≦1,000, d and d′ are numbers and are the same or different and are 1 or 2, and e and e′ are numbers and are the same or different and are 1 or 2 and satisfy the conditions that d+e=3 and d′+e′=3.
    • 一种定影器构件,用于将转印的显影图像熔合到复印基板,其中定影器构件包括涂层在外部聚合物层上的基底,外部聚合物层和脱模剂材料,并且脱模剂材料涂层包括T- 具有氨基官能团的氨基官能的硅氧烷脱模剂材料,T型氨基官能的硅氧烷脱模剂材料具有下式I:其中A表示-R 4 -X,其中R 4表示具有约1至约10个碳的烷基,X表示-NH 2或-NHR 5 NH 2, 其中R 5表示具有约1至约10个碳原子的烷基; R 1和R 2相同或不同,并且各自选自具有约1至约25个碳的烷基,具有约4个碳原子的芳基 至约10个碳原子,和芳基烷基; R 3是具有约1至约500个硅氧烷单元的取代的二有机硅氧烷链; b和c是数字并且相同或不同,并且各自满足1 <= b <= 10和10 <= c <= 1,000的条件,d和d'是数字,并且相同或不同,为1或2 ,e和e'是数字,并且相同或不同,为1或2并满足d + e = 3和d'+ e'= 3的条件。
    • 17. 发明申请
    • T-type amino functional release agent for fuser members
    • 用于定影器构件的T型氨基功能性脱模剂
    • US20060228567A1
    • 2006-10-12
    • US11447643
    • 2006-06-05
    • David GervasiAlexander KlymachyovSamuel KaplanSantokh BadeshaDouglas WilkinsGeorge Gibson
    • David GervasiAlexander KlymachyovSamuel KaplanSantokh BadeshaDouglas WilkinsGeorge Gibson
    • B32B25/00G03G15/20G03G16/00
    • C09D183/08C08L83/08Y10T428/31663
    • A fuser member component to fuse the transferred developed image to the copy substrate, wherein the fuser member includes a substrate, an outer polymeric layer, and a release agent material coating on the outer polymeric layer, and the release agent material coating includes a T-type amino-functional siloxane release agent material having amino-functional groups, and the T-type amino-functional siloxane release agent material has the following Formula I: wherein A represents —R4—X, wherein R4 represents an alkyl group having from about 1 to about 10 carbons, X represents —NH2 or —NHR5NH2 with R5 representing an alkyl group having from about 1 to about 10 carbons; R1 and R2 are the same or different and each is selected from the group consisting of an alkyl having from about 1 to about 25 carbons, an aryl having from about 4 to about 10 carbons, and an arylalkyl; R3 is a substituted diorganosiloxane chain having from about 1 to about 500 siloxane units; b and c are numbers and are the same or different and each satisfy the conditions of 1≦b≦10 and 10≦c≦1,000, d and d′ are 2, and e and e′ are 1.
    • 一种定影器构件,用于将转印的显影图像熔合到复印基板,其中定影器构件包括涂层在外部聚合物层上的基底,外部聚合物层和脱模剂材料,并且脱模剂材料涂层包括T- 具有氨基官能团的氨基官能的硅氧烷脱模剂材料,T型氨基官能的硅氧烷脱模剂材料具有下式I:其中A表示-R 4 -X,其中R 4表示具有约1至约10个碳的烷基,X表示-NH 2或-NHR 5 NH 2, 其中R 5表示具有约1至约10个碳原子的烷基; R 1和R 2相同或不同,并且各自选自具有约1至约25个碳的烷基,具有约4个碳原子的芳基 至约10个碳原子,和芳基烷基; R 3是具有约1至约500个硅氧烷单元的取代的二有机硅氧烷链; b和c是数字并且相同或不同,并且各自满足1 <= b <= 10和10 <= c <= 1,000的条件,d和d'是2,e和e'是1。