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11. 发明申请

US20080131609A1 Methods and materials for reducing damage from environmental electromagnetic effects 审中-公开
标题翻译：降低环境电磁效应造成损害的方法和材料
公开(公告)号：US20080131609A1
公开(公告)日：2008-06-05
申请号：US11807189
申请日：2007-05-26
申请人： Terrence G. Vargo , Timothy S. Koloski
发明人： Terrence G. Vargo , Timothy S. Koloski
IPC分类号： B05D1/36
CPC分类号： B32B15/08 , B32B15/02 , B32B15/14 , B32B27/304 , B32B27/322 , B32B2307/212 , B32B2605/08 , B32B2605/16 , B32B2605/18 , H05K9/0084
摘要： Disclosed is a method of reducing damage resulting from environmental electromagnetic effects on a non-metallic surface. The method includes disposing a polymeric sheet material over the non-metallic surface and disposing a metal layer between the non-metallic surface and the polymeric sheet material. Objects which includes a substrate having a non-metallic surface, a halopolymer sheet material disposed over the substrate's non-metallic surface, and a metal layer disposed between the halopolymer sheet material and the substrate's non-metallic surface are also described. Laminates are also disclosed. One such laminate includes a metal layer having a first surface and a second surface, a halopolymer sheet material bonded or adhered to the first surface of the metal layer, and an adhesive disposed on the second surface of the metal layer. Another such laminate includes a halopolymer fabric having a first surface and a second surface, a metal layer bonded or adhered to the first surface of the halopolymer fabric, and an adhesive disposed on the second surface of the halopolymer fabric.
摘要翻译：公开了一种在非金属表面上减少由环境电磁效应引起的损伤的方法。该方法包括在非金属表面上设置聚合物片材，并在非金属表面和聚合物片材之间设置金属层。还描述了包括具有非金属表面的基底的物体，设置在基底非金属表面上的卤素聚合物片材和设置在卤素聚合物片材和基底的非金属表面之间的金属层。还披露了层压板。一种这样的层压体包括具有第一表面和第二表面的金属层，结合或粘附到金属层的第一表面的卤素聚合物片材料和设置在金属层的第二表面上的粘合剂。另一种这样的层压体包括具有第一表面和第二表面的卤素聚合物织物，粘合或粘附到卤素聚合物织物的第一表面的金属层，以及设置在卤素聚合物织物的第二表面上的粘合剂。

12. 发明授权

US07223312B2 Methods and materials for reducing damage from environmental electromagnetic effects 失效
标题翻译：降低环境电磁效应造成损害的方法和材料
公开(公告)号：US07223312B2
公开(公告)日：2007-05-29
申请号：US10883481
申请日：2004-07-01
申请人： Terrence G. Vargo , Timothy S. Koloski
发明人： Terrence G. Vargo , Timothy S. Koloski
IPC分类号： B32B31/12 , B32B15/08
CPC分类号： B32B15/08 , B32B15/02 , B32B15/14 , B32B27/304 , B32B27/322 , B32B2307/212 , B32B2605/08 , B32B2605/16 , B32B2605/18 , H05K9/0084
摘要： Disclosed is a method of reducing damage resulting from environmental electromagnetic effects on a non-metallic surface. The method includes disposing a polymeric sheet material over the non-metallic surface and disposing a metal layer between the non-metallic surface and the polymeric sheet material. Objects which includes a substrate having a non-metallic surface, a halopolymer sheet material disposed over the substrate's non-metallic surface, and a metal layer disposed between the halopolymer sheet material and the substrate's non-metallic surface are also described. Laminates are also disclosed. One such laminate includes a metal layer having a first surface and a second surface, a halopolymer sheet material bonded or adhered to the first surface of the metal layer, and an adhesive disposed on the second surface of the metal layer. Another such laminate includes a halopolymer fabric having a first surface and a second surface, a metal layer bonded or adhered to the first surface of the halopolymer fabric, and an adhesive disposed on the second surface of the halopolymer fabric.
摘要翻译：公开了一种在非金属表面上减少由环境电磁效应引起的损伤的方法。该方法包括在非金属表面上设置聚合物片材，并在非金属表面和聚合物片材之间设置金属层。还描述了包括具有非金属表面的基底的物体，设置在基底的非金属表面上的卤素聚合物片材和设置在卤素聚合物片材和基底的非金属表面之间的金属层。还披露了层压板。一种这样的层压体包括具有第一表面和第二表面的金属层，结合或粘附到金属层的第一表面的卤素聚合物片材料和设置在金属层的第二表面上的粘合剂。另一种这样的层压体包括具有第一表面和第二表面的卤素聚合物织物，粘合或粘附到卤素聚合物织物的第一表面的金属层，以及设置在卤素聚合物织物的第二表面上的粘合剂。

13. 发明授权

US06790526B2 Oxyhalopolymer protective multifunctional appliqués and paint replacement films 有权
标题翻译：氧化聚合物保护性多功能贴花和油漆更换膜
公开(公告)号：US06790526B2
公开(公告)日：2004-09-14
申请号：US10211739
申请日：2002-08-02
申请人： Terrence G. Vargo , Timothy S. Koloski , John M. Brupbacher , Andrew W. Dalgleish , Garner S. Holdsworth
发明人： Terrence G. Vargo , Timothy S. Koloski , John M. Brupbacher , Andrew W. Dalgleish , Garner S. Holdsworth
IPC分类号： B32B900
CPC分类号： B32B7/12 , B32B15/08 , B32B2307/21 , B32B2307/30 , B32B2307/40 , B32B2319/00 , B32B2331/00 , B32B2361/00 , B32B2363/00 , B32B2367/00 , B32B2375/00 , B32B2605/00 , C09J5/02 , C09J7/245 , C09J2427/006 , Y10T428/28 , Y10T428/287 , Y10T428/31511 , Y10T428/31529 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551 , Y10T428/31678 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938
摘要： Novel appliqués comprising oxyhalopolymer-adhesive composites wherein the adhesive layer of the composite is chemically bonded to reactive sites on at least one side of the oxyhalopolymer layer, possess superior peel strengths, resistance to delamination and protective properties, including protection of surfaces from lightning strike to seamless protective liners for tanks. The appliques are suitable for printing architectural designs thereon. Multilayered specialty appliqués can be fabricated from the above fundamental oxyhalopolymer-adhesive composite structure, including layered adhesives for encapsulating tridimensional mechanical and electrical devices, such as RF, or microwave sensitive antennae for transmitting and receiving communications, providing protection from environmental electromagnetic effects (E3), shock and impact resistance, multidimensional deformable structures; housing for temperature control systems, etc. The properties of the appliqués can be modified by introducing various additives to the halopolymer and/or adhesive layers to customize electrical, and optical shielding, or reflectivity, corrosion resistance, and the like.
摘要翻译：包含含氧卤聚合物 - 粘合剂复合材料的新型贴花，其中复合材料的粘合剂层化学键合在羟基卤聚合物层的至少一侧上的反应位点，具有优异的剥离强度，抗分层性和保护性能，包括保护表面免受雷击坦克的无缝防护衬垫。贴花适用于印刷其上的建筑设计。多层专用贴花可以由上述基础氧基聚合物 - 粘合剂复合结构制成，包括用于封装三维机械和电气设备的分层粘合剂，例如用于发射和接收通信的RF或微波敏感天线，提供防止环境电磁效应的保护（E < 3>），冲击和抗冲击，多维可变形结构; 用于温度控制系统的壳体等。可以通过向卤代聚合物和/或粘合剂层中引入各种添加剂来定制贴花的性质，以定制电气，光学屏蔽或反射性，耐腐蚀性等。

14. 发明授权

US06329470B1 Fluorocarbon end-capped polymers and method of synthesis 有权
标题翻译：氟碳封端聚合物及其合成方法
公开(公告)号：US06329470B1
公开(公告)日：2001-12-11
申请号：US09675905
申请日：2000-09-29
申请人： Joseph A. Gardella, Jr. , Wesley Hicks, Jr. , Timothy Koloski , Ilario Losito , Won-Ki Lee , Terrence G. Vargo
发明人： Joseph A. Gardella, Jr. , Wesley Hicks, Jr. , Timothy Koloski , Ilario Losito , Won-Ki Lee , Terrence G. Vargo
IPC分类号： C08F25908
CPC分类号： C08G63/6822 , C08G63/912
摘要： The present invention provides novel surface modified biodegradable polyesters having fluorocarbon chains at the terminal end of the polyesters. The compounds of the present invention are obtained by the addition of fluorocarbon chains at the surface of the polyester. Any commonly used polyester material can be used in the present invention; however, polyglycolic or polylactic acids or co-polymers thereof are preferred.
摘要翻译：本发明提供了在聚酯末端具有氟碳链的新型表面改性生物降解聚酯。本发明的化合物是通过在聚酯表面添加碳氟化合物链得到的。任何常用的聚酯材料均可用于本发明; 然而，聚乙醇酸或聚乳酸或其共聚物是优选的。

15. 发明授权

US06232386B1 Polymer composites having an oxyhalo surface and methods for making same 失效
标题翻译：具有氧卤素表面的聚合物复合材料及其制备方法
公开(公告)号：US06232386B1
公开(公告)日：2001-05-15
申请号：US08997012
申请日：1997-12-23
申请人： Terrence G. Vargo , Timothy S. Koloski
发明人： Terrence G. Vargo , Timothy S. Koloski
IPC分类号： C08J510
CPC分类号： C08F283/00 , C09D5/1612 , H01M2/164 , H01M4/667 , H01M8/1004
摘要： Oxyhalopolymer composites which include an oxyhalopolymer having free volume therein and an inorganic or organic material disposed in the free volume of the oxyhalopolymer are disclosed. Also disclosed is a surface-oxyhalogenated non-halopolymer composite. The composite includes a surface-oxyhalogenated non-halopolymer having free volume therein and an inorganic or organic material disposed in the free volume of the surface-oxyhalogenated non-halopolymer. Methods for making and using these composites are also described.
摘要翻译：公开了包含其中具有自由体积的含氧卤聚合物和设置在氧基聚氧乙烯的自由体积中的无机或有机材料的氧基聚合物复合材料。还公开了表面 - 卤代卤代聚合物复合材料。复合材料包括其中具有自由体积的表面卤氧化非卤代聚合物和位于表面 - 卤代卤化非卤代聚合物的自由体积中的无机或有机材料。还描述了制备和使用这些复合材料的方法。

16. 发明授权

US5627079A Refunctionalized oxyfluorinated surfaces 失效
标题翻译：反氟化氧氟化表面
公开(公告)号：US5627079A
公开(公告)日：1997-05-06
申请号：US307919
申请日：1994-09-16
申请人： Joseph A. Gardella, Jr. , Terrence G. Vargo
发明人： Joseph A. Gardella, Jr. , Terrence G. Vargo
IPC分类号： A61L27/16 , A61L27/28 , B29C59/14 , C08F8/26 , C08J7/12 , G01N33/543 , B05D5/00 , B32B27/00 , H05H1/00
CPC分类号： C08J7/123 , A61L27/16 , A61L27/28 , B29C59/14 , C08F8/26 , C08J7/126 , G01N33/54353 , Y10T428/12493 , Y10T428/12514 , Y10T428/12528 , Y10T428/31507 , Y10T428/3154 , Y10T428/31551 , Y10T428/3158 , Y10T428/31612 , Y10T428/31678 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938
摘要： Permanently substituted oxyfluorinated surfaces can be formed on non-fluorinated substrates having a fluorinated surface or fluorocarbon coating applied by gas phase surface fluorination or plasma deposition. The oxyfluorinated surfaces can be refunctionalized by bonding organosilanes, isothiocyanate-containing fluorescent compounds and proteins, such as enzymes, antibodies and peptides directly to such surfaces. Surfaces refunctionalized with such protein based groups are useful in the fabrication of biological sensors, devices for separation of cell lines, filtration applications for selective binding of antigens. Masking techniques can be employed in forming a predetermined pattern of covered and exposed surfaces, for example, prior to oxyfluorination.
摘要翻译：永久取代的氟化氟化表面可以在具有通过气相表面氟化或等离子体沉积施加的氟化表面或氟碳涂层的非氟化基材上形成。通过将有机硅烷，含异硫氰酸酯的荧光化合物和蛋白质，例如酶，抗体和肽直接键合到这些表面，可以使氧氟化表面反应。用这种基于蛋白质的基团重新官能化的表面可用于制造生物传感器，用于分离细胞系的装置，用于选择性结合抗原的过滤应用。掩蔽技术可以用于形成覆盖和暴露表面的预定图案，例如在氟氧化之前。

17. 发明授权

US5266309A Refunctionalized oxyfluoropolymers 失效
标题翻译：反应性氧氟聚合物
公开(公告)号：US5266309A
公开(公告)日：1993-11-30
申请号：US522532
申请日：1990-05-11
申请人： Joseph A. Gardella, Jr. , Terrence G. Vargo
发明人： Joseph A. Gardella, Jr. , Terrence G. Vargo
IPC分类号： A61L27/16 , A61L27/28 , B29C59/14 , C08F8/26 , C08J7/12 , C08J9/36 , G01N33/543 , A61K31/74 , A61K31/80
CPC分类号： C08J7/123 , A61L27/16 , A61L27/28 , B29C59/14 , C08F8/26 , C08J7/126 , C08J9/36 , G01N33/54353 , C08J2327/12
摘要： Fluoropolymers modified by radio frequency glow discharge in the presence of vapor/gas plasma provides for permanent and controlled substitution of hydrogen and oxygen functionality for fluorine. The oxygen-containing sites of the modified fluoropolymer are highly reactive, enabling the material to be readily refunctionalized by the introduction of a new atom, functionality or macromolecular unit, such as organosilane, alkali metal or reactive fluorescent compound.
摘要翻译：在存在蒸汽/气体等离子体的情况下，通过射频辉光放电改性的含氟聚合物可提供持久的和可控的氟取代氢和氧官能团。改性含氟聚合物的含氧位点是高反应性的，使得材料可以通过引入新的原子，官能团或大分子单元如有机硅烷，碱金属或反应性荧光化合物而容易地进行反应。

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