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    • 16. 发明授权
    • Process for removing vanadium residues from polymer solutions
    • 从聚合物溶液中除去钒残留物的方法
    • US4016349A
    • 1977-04-05
    • US627460
    • 1975-10-30
    • James Michael McKenna
    • James Michael McKenna
    • C08F6/02C08F6/08
    • C08F6/02
    • Vanadium catalyst residues can be removed from solutions of organic solvents of homopolymers of .alpha.-olefins or their copolymers with hydrocarbon monomers by first contacting at a temperature of about room temperature to about 140.degree. C. the polymer solutions with polar liquid extractants supported on an inert, finely divided, solid material, such as diatomaceous silica, silica gel, alumina, or molecular sieves, then separating the solution from the solid material. Water is the preferred polar liquid, and diatomaceous silica is the preferred supporting material. Polymers recovered from solutions treated according to the process of this invention have a much lesser proportion of vanadium contaminants than those recovered from untreated solutions. This vanadium removal process is simple and inexpensive.
    • 可以在约室温至约140℃的温度下首先接触α-烯烃均聚物或其与烃单体的共聚物的有机溶剂的溶液中,将钒催化剂残余物除去,负载在惰性气体上的极性液体萃取剂的聚合物溶液 精细分散的固体材料,例如硅藻土,硅胶,氧化铝或分子筛,然后将溶液与固体材料分离。 水是优选的极性液体,硅藻土是优选的支撑材料。 从根据本发明方法处理的溶液中回收的聚合物的钒污染物比从未处理溶液中回收的那些少得多。 这种钒去除工艺简单而便宜。