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    • 13. 发明授权
    • Thermal coating materials and coating materials that can be cured thermally and using actinic radiation and the use thereof
    • 可以热固化并使用光化辐射的热涂层材料和涂层材料及其用途
    • US07446142B2
    • 2008-11-04
    • US10483698
    • 2002-08-10
    • Uwe MeisenburgHubert BaumgartDaniel Kussel
    • Uwe MeisenburgHubert BaumgartDaniel Kussel
    • C08K3/18
    • C09J151/08C08K3/36C08K9/04C08K9/06C08L2666/02C08L2666/24C09D4/00C09D7/61C09D7/67C09D151/06C09D151/08C09D153/00C09J151/003C09J151/06C08F220/36
    • Coating materials curable thermally, or thermally and with actinic radiation, comprising (A) binder selected from the group consisting of random, alternating and block, linear, branched and comb polyaddition resins, polycondensation resins, and addition (co)polymers of olefinically unsaturated monomers, curable physically, thermally, with actinic radiation, and thermally and with actinic radiation; and (B) nanoparticles selected from the group consisting of nanoparticles modified with at least one compound of the general formula I: [(S—)o-L-]n-M-(—X—R)m−n ,   (I)  where the indices and the variables have the following meanings: S is a reactive functional group having at least one bond which can be activated with actinic radiation; L is at least one divalent organic linking group; X independently at each occurrence is an oxygen atom, sulfur atom or>NR1, where R1=hydrogen atom or alkyl group having from 1 to 4 carbon atoms; M is a metal atom; R is a monovalent organic radical; o is an integer from 1 to 5; m is 3 or 4; n is 1 or 2 if m=3, and n is 1, 2 or 3 if m=4, and their use for producing clearcoat systems and multicoat color and/or effect paint systems or as adhesives and sealing compounds.
    • 包括(A)选自无规,交替和嵌段,直链,支链和梳状加聚树脂,缩聚树脂和烯属不饱和单体的加成(共))聚合物的粘合剂,其可热固化或热和光化辐射固化的涂层材料 可以物理,热,光化辐射,热和光化辐射固化; 和(B)纳米颗粒,其选自由至少一种通式I化合物修饰的纳米颗粒:<?in-line-formula description =“In-line Formulas”end =“lead”→> [(S- ) - ( - ) - ( - ) - ( - ) - ( - ) - (X) 索引和变量具有以下含义:S是具有至少一个可以用光化辐射活化的键的反应性官能团; L是至少一个二价有机连接基团; 在每次出现时X独立地为氧原子,硫原子或> NR 1,其中R 1 =氢原子或具有1至4个碳原子的烷基; M是金属原子; R是一价有机基团; o是1至5的整数; m为3或4; 如果m = 3,n为1或2,如果m = 4,n为1,2或3,以及它们用于生产透明涂层体系和多色彩和/或效果漆系统或粘合剂和密封剂的用途。
    • 18. 发明授权
    • Mixtures which contain carbamate groups and/or allophanate groups and can be cured thermally and by using actinic radiation
    • 含有氨基甲酸酯基和/或脲基甲酸酯基团的混合物可以热和通过光化辐射固化
    • US07129280B2
    • 2006-10-31
    • US10473728
    • 2002-06-18
    • Hubert BaumgartSandra HasseUwe MeisenburgVincent Cook
    • Hubert BaumgartSandra HasseUwe MeisenburgVincent Cook
    • C08K5/205C08K5/21C08J3/28
    • C09D201/025C08G18/6229C08G71/04C09D175/04C08L2666/16
    • Mixtures curable thermally and with actinic radiation and containing carbamate and/or allophanate groups, comprising (A) at least one of (A1) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (A2) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and additionally allophanate- and/or carbamate-reactive functional groups,  which are substantially or entirely free from reactive functional groups which contain at least one bond which can be activated with actinic radiation, and (C) at least one constituent containing on average per molecule at least one reactive functional group having at least one bond which can be activated with actinic radiation; with the proviso that if only (A1) is used, the mixtures further comprise (B) at least one of low molecular mass compounds, oligomers and polymers containing allophanate- and/or carbamate-reactive functional groups.
    • 包含(A)至少一种(A1)低分子量化合物,低聚物和包含脲基甲酸酯基团的聚合物,氨基甲酸酯基和氨基甲酸酯和脲基甲酸酯基团中的至少一种,和(A)含有氨基甲酸酯和/或脲基甲酸酯基团的混合物, A2)低分子量化合物,含有脲基甲酸酯基团的低聚物和聚合物,氨基甲酸酯基团和氨基甲酸酯和脲基甲酸酯基团,以及基本上或完全不含至少含有反应性官能团的脲基甲酸酯和/或氨基甲酸酯反应性官能团, 可以用光化辐射活化的一个键,和(C)每分子平均含有至少一个具有至少一个可以用光化辐射活化的键的反应性官能团的至少一种组分; 条件是如果仅使用(A1),混合物还包含(B)低分子量化合物,低聚物和含有脲基甲酸酯和/或氨基甲酸酯反应性官能团的聚合物中的至少一种。