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    • 18. 发明授权
    • Siloxane copolymer and solid polymer electrolyte comprising such siloxane copolymers
    • 硅氧烷共聚物和包含这种硅氧烷共聚物的固体聚合物电解质
    • US08796406B2
    • 2014-08-05
    • US13208864
    • 2011-08-12
    • Neeraj GuptaAnantharaman DhanabalanNagendiran ShanmugamVivek Khare
    • Neeraj GuptaAnantharaman DhanabalanNagendiran ShanmugamVivek Khare
    • C08F130/08
    • C08F230/08C08F220/18C08F290/148C08G77/20C08G77/46H01M8/1037H01M10/0565C08F220/20
    • A copolymer suitable for use in forming a solid polymer electrolyte film comprising a first monomer represented by Formula (1): wherein n is 2 to 1,000; m is 2 to 1,000; x and y are individually 1 to 100; p is 0 to 10; and q is 1 to 10, R1 is an alkyl group having 1 to 10 carbon atoms, and A is an alkyl acryloyl group an acryloyl group, alkyl acryloyl group, methacryloyl group, alkyl methacryloyl group, a vinyl group, an allyl group, a styryl group, or a combination of two or more thereof; and a second monomer chosen from a hydroxyl-substituted alkyl acrylate, a hydroxyl-substituted alkyl methacrylate, or a combination of two or more thereof. The copolymer may be used to form a solid polymer electrolyte composition comprising (i) the copolymer, (ii) a plasticizer, and (iii) a salt. The solid polymer electrolyte may be used to form a solid polymer electrolyte film, which may be suitable for use in electrochemical devices.
    • 一种适合用于形成固体聚合物电解质膜的共聚物,其包含由式(1)表示的第一单体:其中n为2至1,000; m为2〜1,000; x和y分别为1〜100; p为0〜10; q为1〜10,R1为碳原子数1〜10的烷基,A为烷基丙烯酰基,丙烯酰基,烷基丙烯酰基,甲基丙烯酰基,烷基甲基丙烯酰基,乙烯基,烯丙基, 苯乙烯基或其两种或更多种的组合; 和选自羟基取代的丙烯酸烷基酯,羟基取代的甲基丙烯酸烷基酯或其两种或更多种的组合的第二单体。 共聚物可用于形成固体聚合物电解质组合物,其包含(i)共聚物,(ii)增塑剂和(iii)盐。 固体聚合物电解质可用于形成固体聚合物电解质膜,其可适用于电化学装置。
    • 20. 发明授权
    • Silylated polyurethane/polyorganosiloxane blend and sealant composition and fumed silica composition containing same
    • 甲硅烷基化聚氨酯/聚有机硅氧烷共混物和含有它们的密封剂组合物和煅制二氧化硅组合物
    • US09200160B2
    • 2015-12-01
    • US12748810
    • 2010-03-29
    • Indumathi RamakrishnanShayne Joseph LandonDavid A. WilliamsAnantharaman Dhanabalan
    • Indumathi RamakrishnanShayne Joseph LandonDavid A. WilliamsAnantharaman Dhanabalan
    • C08L75/04C08L83/04C08L83/06C08G18/83C08G77/18C08G77/16
    • C08L83/04C08G18/837C08G77/16C08G77/18C08G2190/00C08L75/04C08L83/06
    • There is provided herein a composition comprising: (A) a silanol and/orhydrocarbon-terminated polyorganosiloxane in an amount of from about 30 weight percent to about 90 weight percent; and, (B) a moisture curable silylated polyurethane resin in an amount of from about 10 weight percent to about 70 weight percent. There is also provided herein in another embodiment a two part sealant composition wherein the first part comprises: (A) a silanol and/or hydrocarbon-terminated polyorganosiloxane in an amount of from about 15 weight percent to about 60 weight percent, (B) a moisture curable silylated polyurethane resin in an amount of from about 2 weight percent to about 32 weight percent, and (C) a filler, said weight percents being based on the weight of the first part. In addition, there is provided herein a fumed silica composition comprising: (A) a silanol and/or hydrocarbon-terminated polyorganosiloxane in an amount of from about 20 weight percent to about 62 weight percent; (B) a moisture curable silylated polyurethane resin in an amount of from about 8 weight percent to about 38 weight percent; and, (C) a treated fumed silica in an amount of from about 5 to about 10 weight percent.
    • 本文提供的组合物包含:(A)约30重量%至约90重量%的硅烷醇和/或烃封端的聚有机硅氧烷; 和(B)可湿固化的甲硅烷基化聚氨酯树脂,其量为约10重量%至约70重量%。 在另一个实施方案中还提供了两部分密封剂组合物,其中第一部分包括:(A)约15重量%至约60重量%的量的硅烷醇和/或烃封端的聚有机基硅氧烷,(B) 湿度可固化的甲硅烷基化聚氨酯树脂,其量为约2重量%至约32重量%,和(C)填料,所述重量百分比基于第一部分的重量。 此外,本文提供了一种热解法二氧化硅组合物,其包含:(A)约20重量%至约62重量%的硅烷醇和/或烃封端的聚有机硅氧烷; (B)水分可固化的甲硅烷基化聚氨酯树脂,其量为约8重量%至约38重量%; 和(C)处理的热解法二氧化硅的量为约5至约10重量%。