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11. 发明申请

US20110108307A1 NON-ORIENTED ELECTRICAL STEEL SHEET AND METHOD OF MANUFACTURING THE SAME 审中-公开
标题翻译：非指定电工钢板及其制造方法
公开(公告)号：US20110108307A1
公开(公告)日：2011-05-12
申请号：US13001240
申请日：2009-07-15
申请人： Yoshihiro Arita , Yoshiyuki Ushigami , Shigeru Hirano , Hiroyasu Fujii , Toshinao Yamaguchi , Isoa Koike
发明人： Yoshihiro Arita , Yoshiyuki Ushigami , Shigeru Hirano , Hiroyasu Fujii , Toshinao Yamaguchi , Isoa Koike
IPC分类号： H01B7/02 , B32B15/01 , B05D5/12
CPC分类号： C23C30/00 , B32B15/015 , C21D8/12 , C22C19/03 , C22C38/02 , C22C38/06 , C22C38/40 , C22F1/10 , C23C28/021 , H01F1/18 , Y10T428/12931
摘要： A non-oriented electrical steel sheet is provided with a base material and an Fe—Ni alloy film formed on at least one surface of the base material. The Fe—Ni alloy film contains, by mass %, Fe: 10% to 40% and Ni: 60% to 90%, and has a thickness of 0.1 μm or more are provided.
摘要翻译：无取向电工钢板设置有形成在基材的至少一个表面上的基材和Fe-Ni合金膜。 Fe-Ni合金膜以质量％计含有Fe：10〜40％，Ni：60〜90％，厚度为0.1μm以上。

12. 发明申请

US20090233114A1 Grain-Oriented Electrical Steel Sheet Having High Tensile Strength Insulating Film and Method of Treatment of Such Insulating Film 有权
标题翻译：具有高抗拉强度绝缘膜的晶粒取向电工钢板和这种绝缘膜的处理方法
公开(公告)号：US20090233114A1
公开(公告)日：2009-09-17
申请号：US12227205
申请日：2007-05-18
申请人： Kazutoshi Takeda , Fumiaki Takahashi , Shuichi Yamazaki , Hiroyasu Fujii , Fumikazu Andou
发明人： Kazutoshi Takeda , Fumiaki Takahashi , Shuichi Yamazaki , Hiroyasu Fujii , Fumikazu Andou
IPC分类号： B32B15/04 , B05D3/10 , B05D3/02
CPC分类号： C23C22/22 , C21D8/1283 , C21D8/1288 , C23C22/188 , C23C22/20 , C23C22/74 , H01F1/147 , H01F1/18
摘要： Grain-oriented electrical steel sheet having a chrome-free high tensile strength insulating film characterized by comprising steel sheet on the surface of which is formed an insulating film containing a phosphate and colloidal silica as main ingredients and containing crystalline magnesium phosphate uniformly dispersed over the entire surface.
摘要翻译：具有无铬高强度绝缘膜的晶粒取向电工钢板，其特征在于，其表面上形成有作为主要成分的含有磷酸盐和胶体二氧化硅的绝缘膜，并且含有均匀分散在整体上的结晶磷酸镁表面。

13. 发明授权

US5565272A Grain oriented silicon steel sheet having excellent primary film properties 失效
标题翻译：具有优异的初始膜性能的晶粒取向硅钢板
公开(公告)号：US5565272A
公开(公告)日：1996-10-15
申请号：US911637
申请日：1992-07-10
申请人： Hiroaki Masui , Morio Shiozaki , Nobuyuki Takahashi , Hisashi Kabayashi , Takeo Nagashima , Shuichi Yamazaki , Hiroyasu Fujii
发明人： Hiroaki Masui , Morio Shiozaki , Nobuyuki Takahashi , Hisashi Kabayashi , Takeo Nagashima , Shuichi Yamazaki , Hiroyasu Fujii
IPC分类号： C21D1/76 , C21D8/12 , C21D9/46 , C22C38/00 , C22C38/02 , C23C22/00 , H01F1/147 , H01F1/16 , B32B15/04
CPC分类号： H01F1/14783 , C21D8/1283 , H01F1/14766 , Y10T428/31
摘要： A grain oriented silicon steel sheet having excellent primary glass film property and magnetic property, comprising 2.0 to 5.0% by weight of Si, wherein a primary glass film formed during secondary recrystallization annealing is composed mainly of forsterite (Mg.sub.2 SiO.sub.4) and an oxide containing Al, mainly of spinel (MgAl.sub.2 O.sub.4), or Al and Si, mainly of cordierite (MgO.sub.2 Al.sub.4 Si.sub.5 O.sub.18) and/or sapphirine (Mg.sub.4 Al.sub.10 Si.sub.2 O.sub.23), and in an analysis of the surface of the steel sheet by glow discharge optical emission spectrometry analysis (GDS analysis), a peak derived from Al is separated from a peak derived from Mg, and, preferably, the peak derived from Al is separated from the peak derived from Mg and the distance (time) from the surface of the steel sheet at which the peak derived from Al is 1.2 times or more the distance from the surface of the steel sheet at which the peak derived from Mg appears.
摘要翻译：一种具有优异的初级玻璃膜性能和磁特性的晶粒取向硅钢板，其包含2.0-5.0重量％的Si，其中在二次再结晶退火过程中形成的初级玻璃膜主要由镁橄榄石（Mg 2 SiO 4）和含有Al的氧化物组成，主要是尖晶石（MgAl2O4），主要是堇青石（MgO2Al4Si5O18）和/或蓝宝石（Mg4Al10Si2O23）的Al和Si，并且通过辉光放电发射光谱分析（GDS分析）对钢板表面进行分析，来自Al的峰与从Mg衍生的峰分离，优选从Al衍生的峰与来自Mg的峰以及与来自Al的峰的钢板的表面的距离（时间）分离是从Mg出现的峰出现的钢板表面的距离的1.2倍以上。

14. 发明授权

US07998284B2 Grain-oriented electrical steel sheet having high tensile strength insulating film and method of treatment of such insulating film 有权
标题翻译：具有高抗拉强度绝缘膜的晶粒取向电工钢板和这种绝缘膜的处理方法
公开(公告)号：US07998284B2
公开(公告)日：2011-08-16
申请号：US12227205
申请日：2007-05-18
申请人： Kazutoshi Takeda , Fumiaki Takahashi , Shuichi Yamazaki , Hiroyasu Fujii , Fumikazu Andou
发明人： Kazutoshi Takeda , Fumiaki Takahashi , Shuichi Yamazaki , Hiroyasu Fujii , Fumikazu Andou
IPC分类号： H01F1/14 , H01F1/18
CPC分类号： C23C22/22 , C21D8/1283 , C21D8/1288 , C23C22/188 , C23C22/20 , C23C22/74 , H01F1/147 , H01F1/18
摘要： Grain-oriented electrical steel sheet having a chrome-free high tensile strength insulating film characterized by comprising steel sheet on the surface of which is formed an insulating film containing a phosphate and colloidal silica as main ingredients and containing crystalline magnesium phosphate uniformly dispersed over the entire surface.
摘要翻译：具有无铬高强度绝缘膜的晶粒取向电工钢板，其特征在于，其表面上形成有作为主要成分的含有磷酸盐和胶体二氧化硅的绝缘膜，并且含有均匀分散在整体上的结晶磷酸镁表面。

15. 发明授权

US08268097B2 Grain-oriented electrical steel sheet and producing method therefor 有权
标题翻译：晶粒取向电工钢板及其制造方法
公开(公告)号：US08268097B2
公开(公告)日：2012-09-18
申请号：US12736257
申请日：2009-03-30
申请人： Fumiaki Takahashi , Kazutoshi Takeda , Hiroyasu Fujii , Shuichi Yamazaki , Yoshiaki Natori
发明人： Fumiaki Takahashi , Kazutoshi Takeda , Hiroyasu Fujii , Shuichi Yamazaki , Yoshiaki Natori
IPC分类号： H01F1/18
CPC分类号： C23C22/74 , C21D8/1288 , C21D2201/05 , C23C22/20 , C23C22/22 , H01F1/14725 , H01F1/18
摘要： A grain-oriented electrical steel sheet has a tension film that does not include chromium. In the present invention, the tension film, including a phosphate and silica as constituents, includes a manganese compound and a potassium compound. The mole ratio K/Mn of potassium to manganese in the film is set to a certain range. The film can be produced by preparing a coating solution by adding a compound, which includes the phosphate and the silica and also includes the potassium and the manganese, and applying the coating solution on a grain-oriented electrical steel sheet after final annealing is completed, followed by drying and baking.
摘要翻译：晶粒取向电工钢板具有不含铬的张力膜。在本发明中，包含磷酸盐和二氧化硅作为成分的张力膜包括锰化合物和钾化合物。膜中钾与锰的摩尔比K / Mn设定在一定范围内。可以通过添加包括磷酸盐和二氧化硅的化合物并且还包括钾和锰来制备涂布溶液并在最终退火完成之后将涂布溶液施加到方向性电磁钢板上来制备膜，然后干燥和烘烤。

16. 发明授权

US06461741B1 Grain-oriented electromagnetic steel sheet with excellent coating properties and process for its manufacture 有权
标题翻译：晶粒取向的电磁钢板具有优良的涂层性能及其制造工艺
公开(公告)号：US06461741B1
公开(公告)日：2002-10-08
申请号：US09661003
申请日：2000-09-13
申请人： Kazutoshi Takeda , Shuichi Yamazaki , Hideyuki Kobayashi , Hiroyasu Fujii
发明人： Kazutoshi Takeda , Shuichi Yamazaki , Hideyuki Kobayashi , Hiroyasu Fujii
IPC分类号： B32B1504
CPC分类号： C23C28/044 , C04B28/346 , C04B2111/00525 , C21D8/1283 , C21D8/1288 , C23C22/08 , C23C22/33 , C23C22/74 , H01F1/14783 , H01F1/18 , Y10S428/90 , Y10S428/928 , Y10T428/12993 , Y10T428/32 , C04B14/06 , C04B14/307 , C04B40/0263 , C04B41/5006 , C04B41/0072
摘要： A high permeability grain-oriented electromagnetic steel sheet with a higher tension-imparting effect and more excellent cohesion and magnetic properties compared to the prior art, which also maintains sufficient corrosion resistance to withstand practical use; the grain-oriented electromagnetic steel sheet has on its surface an insulation coating comprising a first layer composed mainly of a divalent or trivalent metal hydrogen phosphate salt and silica, and a second layer composed mainly of aluminum borate and leaving a surface roughness of 0.1 &mgr;m-0.35 &mgr;m in terms of Ra (center like average roughness).
摘要翻译：与现有技术相比，具有更高的张力赋予效果和更优异的内聚力和磁特性的高磁导率晶粒取向电磁钢板，其也保持足够的耐腐蚀性以抵抗实际应用; 晶粒取向电磁钢板表面具有包含主要由二价或三价金属磷酸氢盐和二氧化硅组成的第一层的绝缘层，以及主要由硼酸铝组成的第二层，表面粗糙度为0.1μm- 以Ra计为0.35μm（中心像平均粗糙度）。

17. 发明申请

US20110039114A1 GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND PRODUCING METHOD THEREFOR 有权
标题翻译：面向电磁钢板及其制造方法
公开(公告)号：US20110039114A1
公开(公告)日：2011-02-17
申请号：US12736257
申请日：2009-03-30
申请人： Fumiaki Takahashi , Kazutoshi Takeda , Hiroyasu Fujii , Shuichi Yamazaki , Yoshiaki Natori
发明人： Fumiaki Takahashi , Kazutoshi Takeda , Hiroyasu Fujii , Shuichi Yamazaki , Yoshiaki Natori
IPC分类号： B32B15/04 , B05D3/02 , B32B15/18
CPC分类号： C23C22/74 , C21D8/1288 , C21D2201/05 , C23C22/20 , C23C22/22 , H01F1/14725 , H01F1/18
摘要： A grain-oriented electrical steel sheet has a tension film that does not include chromium. In the present invention, the tension film, including a phosphate and silica as constituents, includes a manganese compound and a potassium compound. The mole ratio K/Mn of potassium to manganese in the film is set to a certain range. However, the manganese described herein does not refer to manganese derived from a manganese phosphate included in raw materials of the film. The film can be produced by preparing a coating solution by adding a compound, which includes the phosphate and the silica and also includes the potassium and the manganese, and applying the coating solution on a grain-oriented electrical steel sheet after final annealing is completed, followed by drying and baking.
摘要翻译：晶粒取向电工钢板具有不含铬的张力膜。在本发明中，包含磷酸盐和二氧化硅作为成分的张力膜包括锰化合物和钾化合物。膜中钾与锰的摩尔比K / Mn设定在一定范围内。然而，本文所述的锰不是指源自包含在膜的原料中的磷酸锰的锰。可以通过添加包含磷酸盐和二氧化硅的化合物并且还包括钾和锰来制备涂布溶液并在最终退火完成之后将涂布溶液涂覆在方向性电磁钢板上来制备膜，然后干燥和烘烤。

18. 发明授权

US07736449B2 High-strength hot-dip galvanized steel sheet and method for producing the same 有权
标题翻译：高强度热浸镀锌钢板及其制造方法
公开(公告)号：US07736449B2
公开(公告)日：2010-06-15
申请号：US11977537
申请日：2007-10-24
申请人： Yoshihisa Takada , Masayoshi Suehiro , Masao Kurosaki , Hidekuni Murakami , Hiroyasu Fujii , Haruhiko Eguchi , Hisaaki Sato
发明人： Yoshihisa Takada , Masayoshi Suehiro , Masao Kurosaki , Hidekuni Murakami , Hiroyasu Fujii , Haruhiko Eguchi , Hisaaki Sato
IPC分类号： C23C2/28
CPC分类号： C22C38/02 , C21D1/185 , C21D1/74 , C21D8/0273 , C21D8/0278 , C21D9/46 , C22C38/008 , C22C38/04 , C22C38/06 , C22C38/08 , C22C38/12 , C22C38/16 , C23C2/02 , C23C2/40 , Y10T29/301 , Y10T428/12799 , Y10T428/12951
摘要： The present invention stably provides a high-strength hot-dip galvanized steel sheet having a high tensile strength and no non-plated portions and being excellent in workability and surface properties even when the employed equipment has only a reduction annealing furnace and a steel sheet containing relatively large amounts of Si, Mn and Al that are regarded as likely to cause non-plated portions is used as the substrate. The present invention: secures good plating performance even when the steel sheet contains Si, Mn and Al by adding Ni to a steel sheet, thus forming oxides at some portions in the steel sheet surface layer, and resultantly suppressing the surface incrassation of Si, Mn and Al at the portions where oxides are not formed; enhances the effect of Ni and accelerates the formation of oxides by further adding Mo, Cu and Sn; and moreover, in the case of a TRIP steel sheet, secures austenite by determining the ranges of Si and Al strictly, avoiding the deterioration of plating performance caused by the addition of Ni, and further adding Mo in a balanced manner.In addition, the present invention, in a TRIP steel sheet, improves press formability by regulating a retained austenite ratio and accelerates the formation of oxides by regulating a hydrogen concentration and a dew point in annealing before plating.
摘要翻译：本发明稳定地提供了具有高拉伸强度和无镀层部分的高强度热浸镀锌钢板，并且即使所用设备仅具有还原退火炉和含有被认为可能引起非电镀部分的相对大量的Si，Mn和Al被用作衬底。本发明：即使在钢板中含有Si，Mn和Al的钢板中也添加了Ni，从而在钢板表面层的某些部分形成氧化物，也可以确保良好的镀层性，从而抑制Si，Mn 和Al在不形成氧化物的部分; 通过进一步添加Mo，Cu和Sn，增强Ni的作用并加速氧化物的形成; 此外，在TRIP钢板的情况下，通过严格地确定Si和Al的范围来确保奥氏体，避免由于添加Ni而引起的电镀性能的劣化，并且进一步以平衡的方式添加Mo。此外，本发明在TRIP钢板中，通过调节残留奥氏体比例，通过调节镀层前退火时的氢浓度和露点来促进氧化物的形成，提高冲压成形性。

19. 发明申请

US20060124907A1 High-strength hop-dip galvanized steel sheet and method for producing the same 有权
标题翻译：高强度浸镀锌钢板及其制造方法
公开(公告)号：US20060124907A1
公开(公告)日：2006-06-15
申请号：US10542393
申请日：2004-01-15
申请人： Yoshihisa Takada , Masayoshi Suehiro , Masao Kurosaki , Hidekuni Murakami , Hiroyasu Fujii , Haruhiko Eguchi , Hisaaki Sato
发明人： Yoshihisa Takada , Masayoshi Suehiro , Masao Kurosaki , Hidekuni Murakami , Hiroyasu Fujii , Haruhiko Eguchi , Hisaaki Sato
IPC分类号： H01B1/12
CPC分类号： C22C38/02 , C21D1/185 , C21D1/74 , C21D8/0273 , C21D8/0278 , C21D9/46 , C22C38/008 , C22C38/04 , C22C38/06 , C22C38/08 , C22C38/12 , C22C38/16 , C23C2/02 , C23C2/40 , Y10T29/301 , Y10T428/12799 , Y10T428/12951
摘要： The present invention stably provides a high-strength hot-dip galvanized steel sheet having a high tensile strength and no non-plated portions and being excellent in workability and surface properties even when the employed equipment has only a reduction annealing furnace and a steel sheet containing relatively large amounts of Si, Mn and Al that are regarded as likely to cause non-plated portions is used as the substrate. The present invention: secures good plating performance even when the steel sheet contains Si, Mn and Al by adding Ni to a steel sheet, thus forming oxides at some portions in the steel sheet surface layer, and resultantly suppressing the surface incrassation of Si, Mn and Al at the portions where oxides are not formed; enhances the effect of Ni and accelerates the formation of oxides by further adding Mo, Cu and Sn; and moreover, in the case of a TRIP steel sheet, secures austenite by determining the ranges of Si and Al strictly, avoiding the deterioration of plating performance caused by the addition of Ni, and further adding Mo in a balanced manner. In addition, the present invention, in a TRIP steel sheet, improves press formability by regulating a retained austenite ratio and accelerates the formation of oxides by regulating a hydrogen concentration and a dew point in annealing before plating.
摘要翻译：本发明稳定地提供了具有高拉伸强度和无镀层部分的高强度热浸镀锌钢板，并且即使所用设备仅具有还原退火炉和含有被认为可能引起非电镀部分的相对大量的Si，Mn和Al被用作衬底。本发明：即使在钢板中含有Si，Mn和Al的钢板中也添加了Ni，从而在钢板表面层的某些部分形成氧化物，也可以确保良好的镀层性，从而抑制Si，Mn 和Al在不形成氧化物的部分; 通过进一步添加Mo，Cu和Sn，增强Ni的作用并加速氧化物的形成; 此外，在TRIP钢板的情况下，通过严格地确定Si和Al的范围来确保奥氏体，避免由于添加Ni而引起的电镀性能的劣化，并且进一步以平衡的方式添加Mo。此外，本发明在TRIP钢板中，通过调节残留奥氏体比例，通过调节镀层前退火时的氢浓度和露点来促进氧化物的形成，提高冲压成形性。

20. 发明授权

US5190597A Process for producing grain-oriented electrical steel sheet having improved magnetic and surface film properties 失效
标题翻译：用于生产具有改进的磁性和表面膜性质的面向电工钢板的方法
公开(公告)号：US5190597A
公开(公告)日：1993-03-02
申请号：US788212
申请日：1991-11-05
申请人： Hisashi Kobayashi , Osamu Tanaka , Hiroyasu Fujii
发明人： Hisashi Kobayashi , Osamu Tanaka , Hiroyasu Fujii
IPC分类号： C21D1/76 , C21D8/12 , C22C38/00 , C22C38/06 , H01F1/16
CPC分类号： C21D8/1272 , C21D1/76 , C21D8/1255
摘要： A process for producing a grain-oriented electrical steel sheet having improved magnetic and surface film properties, comprising: using an electrical silicon steel slab containins S in an extremely small amount of 0.012 wt % or less and Mn in a limited range of 0.08 to 0.45 wt %; heating the slab to a relatively low temperature of not higher than 1200.degree. C.; hot-rolling the slab to form a hot-rolled strip; cold-rolling the strip to a thickness of a final product sheet; decarburization-annealing the cold-rolled strip; nitriding the strip while it is travelling; applying an annealing separator to the strip; and final texture-annealing the strip by heating the strip to a first temperature of from 800.degree. to 850.degree. C. in an atmosphere of (N.sub.2 +Ar).gtoreq.30 vol % with 25 vol % or more N.sub.2 and the remainder H.sub.2 and subsequently heating from the first temperature to above 1200.degree. C. in a conventional atmosphere.

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