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11. 发明申请

US20110260100A1 Novel Metal-Organic Frameworks as Electrode Material for Lithium Ion Accumulators 审中-公开
标题翻译：新型金属有机骨架作为锂离子蓄电池的电极材料
公开(公告)号：US20110260100A1
公开(公告)日：2011-10-27
申请号：US13088865
申请日：2011-04-18
申请人： Natalia Trukhan , Ulrich Müller , Alexander Panchenko , Itamar Michael Malkowsky , Andreas Fischer
发明人： Natalia Trukhan , Ulrich Müller , Alexander Panchenko , Itamar Michael Malkowsky , Andreas Fischer
IPC分类号： H01M4/60 , C07C63/14 , H01M4/24
CPC分类号： H01M4/60 , H01M4/13 , H01M10/052
摘要： Described is an electrode material which is suitable for a lithium ion accumulator and comprises a porous metal-organic framework, wherein the framework comprises lithium ions and optionally at least one further metal ion and at least one bidentate organic compound and the at least one bidentate organic compound is based on a dihydroxydicarboxylic acid which can be reversibly oxidized to a quinoid structure. Also described is a porous metalorganic framework, the use thereof and also lithium ion accumulators comprising such electrode materials.
摘要翻译：描述了适用于锂离子蓄电池并且包括多孔金属 - 有机骨架的电极材料，其中框架包括锂离子和任选的至少一种其它金属离子和至少一种二齿有机化合物和至少一种二齿有机化合物化合物是基于可以被可逆地氧化成醌型结构的二羟基二羧酸。还描述了多孔金属有机骨架，其用途以及包含这种电极材料的锂离子蓄电池。

12. 发明申请

US20110065939A1 METHOD FOR THE SEPARATION OF ACETONITRILE FROM WATER 有权
标题翻译：从水中分离乙酰胆碱的方法
公开(公告)号：US20110065939A1
公开(公告)日：2011-03-17
申请号：US12837962
申请日：2010-07-16
申请人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baßler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
发明人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baßler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
IPC分类号： C07D301/12 , C07C255/03
CPC分类号： C07D301/12 , B01D17/0208 , B01D17/047 , Y02P20/582
摘要： A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile:water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene:propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile:water in L2 is less than 1; (iv) separating L1 from L2.
摘要翻译：一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

13. 发明申请

US20100029476A1 MAGNESIUM BUTYLISOPHTHALATE AS A POROUS METAL ORGANIC FRAMEWORK 审中-公开
标题翻译：作为多孔金属有机骨架的芒硝
公开(公告)号：US20100029476A1
公开(公告)日：2010-02-04
申请号：US12445322
申请日：2007-11-05
申请人： Natalia Trukhan , Ulrich Mueller , Markus Schubert
发明人： Natalia Trukhan , Ulrich Mueller , Markus Schubert
IPC分类号： C07C55/02 , B01J20/22
CPC分类号： B01J31/1691 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J2531/22 , C01B3/0015 , C01B6/003 , C01B7/00 , C01B13/0281 , C01B21/0455 , C01B23/0057 , C07C63/24 , C07F3/003 , F17C11/005 , Y02C10/08 , Y02E60/328
摘要： The present invention relates to a porous metal organic framework formed by Mg2+ ions to which 5-tert-butylisophthalate ions are coordinated to form a framework structure. The invention further provides a process for preparing it and its use, for example for the storage, separation or controlled release of a substance such as a gas or gas mixture.
摘要翻译：本发明涉及由Mg 2+离子形成的多孔金属有机骨架，其中5-叔丁基间苯二甲酸酯离子被配位以形成骨架结构。本发明进一步提供其制备方法及其用途，例如用于诸如气体或气体混合物的物质的储存，分离或控制释放。

14. 发明授权

US09096616B2 Process for preparing a porous metal-organic framework composed of zinc methylimidazolate 有权
标题翻译：制备由甲基咪唑啉锌组成的多孔金属 - 有机骨架的方法
公开(公告)号：US09096616B2
公开(公告)日：2015-08-04
申请号：US13542971
申请日：2012-07-06
申请人： Natalia Trukhan , Ulrich Müller
发明人： Natalia Trukhan , Ulrich Müller
IPC分类号： C07F3/06
CPC分类号： C07F3/06
摘要： Described is a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is a zinc ion and the at least one at least bidentate organic compound is based on 2-methylimidazole, which comprises the steps (a) addition of a first water-based solution comprising zinc ions to a second water-based solution comprising 2-methylimidazole, with a suspension being formed after addition of the second solution; (b) addition of a third solution comprising a strong base to the suspension formed in step (a).
摘要翻译：描述了一种制备多孔金属 - 有机骨架的方法，所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物，其中所述至少一种金属离子是锌离子，并且所述至少一种至少二齿有机化合物是基于2-甲基咪唑，其包括以下步骤：（a）在包含2-甲基咪唑的第二水性溶液中加入包含锌离子的第一水性溶液，在加入第二溶液后形成悬浮液; （b）向步骤（a）中形成的悬浮液中加入包含强碱的第三溶液。

15. 发明授权

US08609879B2 Method for the separation of acetonitrile from water 有权
标题翻译：从水中分离乙腈的方法
公开(公告)号：US08609879B2
公开(公告)日：2013-12-17
申请号：US12837962
申请日：2010-07-16
申请人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baβler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
发明人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baβler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
IPC分类号： C07C255/00
CPC分类号： C07D301/12 , B01D17/0208 , B01D17/047 , Y02P20/582
摘要： A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.
摘要翻译：一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

16. 发明授权

US08524932B2 Process for preparing porous metal-organic frameworks based on aluminum fumarate 有权
标题翻译：基于富马酸铝制备多孔金属 - 有机骨架的方法
公开(公告)号：US08524932B2
公开(公告)日：2013-09-03
申请号：US13249943
申请日：2011-09-30
申请人： Emi Leung , Ulrich Müller , Natalia Trukhan , Hendrick Mattenheimer , Gerhard Cox , Stefan Blei
发明人： Emi Leung , Ulrich Müller , Natalia Trukhan , Hendrick Mattenheimer , Gerhard Cox , Stefan Blei
IPC分类号： C07F5/06
CPC分类号： C07F5/069
摘要： The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.
摘要翻译：本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。至100℃，绝对压力不超过2巴0.2至4小时。

17. 发明申请

US20120082864A1 Process For Preparing Porous Metal-Organic Frameworks Based On Aluminum Fumarate 有权
标题翻译：基于富铝酸铝制备多孔金属有机骨架的方法
公开(公告)号：US20120082864A1
公开(公告)日：2012-04-05
申请号：US13249943
申请日：2011-09-30
申请人： Emi Leung , Ulrich Müller , Natalia Trukhan , Hendrick Mattenheimer , Gerhard Cox , Stefan Blei
发明人： Emi Leung , Ulrich Müller , Natalia Trukhan , Hendrick Mattenheimer , Gerhard Cox , Stefan Blei
IPC分类号： C07F5/06 , B32B9/00
CPC分类号： C07F5/069
摘要： The present invention relates to a process for preparing a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, where the at least one metal ion is based on an aluminum ion and the at least one at least bidentate organic compound is based on fumaric acid, by reacting at least one aluminum compound with at least fumaric acid in an alkaline aqueous medium, optionally in the presence of at least one base, at a temperature in the range from 20° C. to 100° C. at an absolute pressure of not more than 2 bar for from 0.2 to 4 hours.
摘要翻译：本发明涉及一种制备多孔金属 - 有机骨架的方法，其包含与至少一种金属离子配位的至少一种至少二齿的有机化合物，其中所述至少一种金属离子基于铝离子，并且所述至少一种至少二齿有机化合物是基于富马酸，在至少一种碱的存在下，在至少一种碱的存在下，在20℃的温度下使至少一种铝化合物与至少富马酸在碱性水性介质中反应。至100℃，绝对压力不超过2巴0.2至4小时。

18. 发明申请

US20100119442A1 PROCESS FOR PREPARING A HETEROATOM-COMPRISING SILICATE 有权
标题翻译：制备含硅杂环的方法
公开(公告)号：US20100119442A1
公开(公告)日：2010-05-13
申请号：US12594727
申请日：2008-04-03
申请人： Ulrich Mueller , Natalia Trukhan , Hermann Gies , Bart Tijsebaert , Csaba Varszegi , Dirk De Vos
发明人： Ulrich Mueller , Natalia Trukhan , Hermann Gies , Bart Tijsebaert , Csaba Varszegi , Dirk De Vos
IPC分类号： C01B39/04
CPC分类号： B01J29/87 , B01J29/04 , B01J29/048 , C01B39/06 , C01B39/48 , C04B35/16 , C04B35/624 , C04B35/62655 , C04B35/62675 , C04B2235/3284 , C04B2235/3286 , C04B2235/6021 , C04B2235/612 , Y02P20/582
摘要： The present invention relates to a process for preparing at least one sheet silicate comprising Ga and/or Zn, and based thereon, a framework silicate, preferably of the RRO structure type, to the sheet silicate and framework silicate themselves and to the uses of the silicates, especially of the framework silicate, preferably as catalysts.
摘要翻译：本发明涉及一种制备至少一种包含Ga和/或Zn的片状硅酸盐的方法，并且基于此，优选具有RRO结构类型的骨架硅酸盐与片状硅酸盐和骨架硅酸盐本身以及其用途硅酸盐，特别是骨架硅酸盐，优选作为催化剂。

19. 发明申请

US20110076229A1 PROCESS FOR THE DIRECT SYNTHESIS OF Cu CONTAINING ZEOLITES HAVING CHA STRUCTURE 有权
标题翻译：具有CHA结构的含Cu沸石的直接合成方法
公开(公告)号：US20110076229A1
公开(公告)日：2011-03-31
申请号：US12994058
申请日：2009-05-19
申请人： Natalia Trukhan , Ulrich Mueller , Ivor Bull
发明人： Natalia Trukhan , Ulrich Mueller , Ivor Bull
IPC分类号： C01B39/04 , C01B39/00 , C01B21/02
CPC分类号： B01J29/763 , B01D53/9418 , B01D2251/2062 , B01D2255/2063 , B01D2255/20761 , B01D2255/50 , B01D2255/9202 , B01D2255/9207 , B01D2257/402 , B01D2257/404 , B01D2257/406 , B01D2258/012 , B01J29/072 , B01J29/7065 , B01J35/04 , B01J37/0215 , B01J37/036 , B01J37/038 , B01J37/30 , C01B37/00 , C01B39/06 , C01B39/48 , Y02C20/10 , Y02P20/153
摘要： A process for the preparation of a copper containing zeolitic material having CHA framework structure and a composition comprising the molar ratio (n YO2):X2O3 wherein X is a trivalent element, preferably Al, Y is a tetravalent element, preferably Si, and wherein n is preferably at least 20, the process comprising the preparation of an phosphor-free aqueous solution containing at least one source for X2O3 and at least one source for YO2, at least one structure directing agent suitable for the preparation of a zeolitic material having CHA framework structure, and at least one Cu source, and the process further comprising the hydrothermal crystallization of said aqueous solution obtaining a suspension containing the copper containing zeolitic material having CHA framework structure.
摘要翻译：一种制备具有CHA骨架结构的含铜沸石材料和包含摩尔比（n YO 2）：X 2 O 3的组合物的方法，其中X是三价元素，优选Al，Y是四价元素，优选Si，其中n 优选至少为20，该方法包括制备含有至少一种X 2 O 3源和至少一种YO源的无磷水溶液，至少一种适于制备具有CHA骨架的沸石材料的结构导向剂结构和至少一个Cu源，并且所述方法还包括所述水溶液的水热结晶，得到含有具有CHA骨架结构的含铜沸石材料的悬浮液。

20. 发明授权

US09221692B2 Process for preparing a heteroatom-comprising silicate 有权
标题翻译：制备含杂原子的硅酸盐的方法
公开(公告)号：US09221692B2
公开(公告)日：2015-12-29
申请号：US12594727
申请日：2008-04-03
申请人： Ulrich Mueller , Natalia Trukhan , Hermann Gies , Bart Tijsebaert , Csaba Varszegi , Dirk De Vos
发明人： Ulrich Mueller , Natalia Trukhan , Hermann Gies , Bart Tijsebaert , Csaba Varszegi , Dirk De Vos
IPC分类号： C01B39/04 , C01B39/06 , B01J29/04 , B01J29/87 , C04B35/16 , C04B35/624 , C04B35/626
CPC分类号： B01J29/87 , B01J29/04 , B01J29/048 , C01B39/06 , C01B39/48 , C04B35/16 , C04B35/624 , C04B35/62655 , C04B35/62675 , C04B2235/3284 , C04B2235/3286 , C04B2235/6021 , C04B2235/612 , Y02P20/582
摘要： The present invention relates to a process for preparing at least one sheet silicate comprising Ga and/or Zn, and based thereon, a framework silicate, preferably of the RRO structure type, to the sheet silicate and framework silicate themselves and to the uses of the silicates, especially of the framework silicate, preferably as catalysts.
摘要翻译：本发明涉及一种制备至少一种包含Ga和/或Zn的片状硅酸盐的方法，并且基于此，优选具有RRO结构类型的骨架硅酸盐与片状硅酸盐和骨架硅酸盐本身以及其用途硅酸盐，特别是骨架硅酸盐，优选作为催化剂。

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