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    • 12. 发明授权
    • Anthraquinone-azomethine compounds, processes for their preparation and
processes for dyeing synthetic fibre materials and for pigmenting
organic macromolecular substances
    • 蒽醌 - 偶氮甲碱化合物,其制备方法和合成纤维材料染色工艺和有机高分子物质着色
    • US4389215A
    • 1983-06-21
    • US305568
    • 1981-09-24
    • Rutger NeeffMeinhard RolfWalter Muller
    • Rutger NeeffMeinhard RolfWalter Muller
    • C09B56/00C09B1/20C09B55/00
    • C09B1/205C09B55/00Y10S8/922Y10S8/924Y10S8/927
    • Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## or of the tautomeric formula ##STR3## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, optionally substituted phenyl, carboxyl, carboxylic acid, C.sub.1 -C.sub.4 -alkyl ester or hydroxyl,R.sub.2 denotes hydrogen, halogen, nitro, cyano, optionally substituted carbamoyl or optionally substituted sulphamoyl, sulphonic acid C.sub.1 -C.sub.4 -alkyl ester, sulphonic acid aryl ester, C.sub.1 -C.sub.4 -alkylcarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, optionally substituted benzoyl, alkyl or optionally substituted phenyl sulphone, or a hetero-aromatic radical, for example a radical of the formula ##STR4## or of the formula ##STR5## or of the formula ##STR6## R.sub.3 denotes optionally substituted aryl or hetero-aryl, cycloalkyl or C.sub.1 -C.sub.12 -alkyl, it being possible for the alkyl chain to be interrupted by oxygen or sulphur and/or substituted by hydroxyl, N(R.sub.5).sub.2 --or--N(R.sub.5).sub.3.sup..sym. X.sup..crclbar. groups,R.sub.4 denotes a substituent,R.sub.5 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, cycloalkyl or optionally substituted aryl,X denotes an anion,m denotes 1, 2, 3 or 4 andn denotes 0, 1, 2, 3 or 4,processes for their preparation and processes for dyeing synthetic fibre materials and for pigmenting organic macromolecular substances using the new anthraquinone-azomethine compounds.
    • 式(I)的蒽醌 - 偶氮甲碱化合物或互变异构体式(Ia)或互变异构式(IMA)(Ib)的蒽醌 - 偶氮甲碱化合物,其中A表示不含磺酸基团的蒽醌基团, 任选进一步取代并且优选由至多5个稠环组成,R 1表示氢,C 1 -C 4 - 烷基,羟基-C 1 -C 4 - 烷基,任选取代的苯基,羧基,羧酸,C 1 -C 4 - 烷基酯或羟基, R 2表示氢,卤素,硝基,氰基,任选取代的氨基甲酰基或任选取代的氨磺酰基,磺酸C 1 -C 4 - 烷基酯,磺酸芳基酯,C 1 -C 4烷基羰基,C 1 -C 4烷氧基羰基,任选取代的苯甲酰基,烷基或 任选取代的苯基砜或杂芳族基团,例如式(II)或式(IMAGE)(III)或式(IV)的基团R 3表示任选取代的芳基 或杂芳基,环烷基或C 1 -C 12 - 烷基 可能的烷基链被氧或硫中断,和/或被羟基,N(R 5)2 - 或-N(R 5)3(+)X( - )基团取代,R 4表示取代基,R 5表示氢, C 1 -C 4 - 烷基,环烷基或任选取代的芳基,X表示阴离子,m表示1,2,3或4,n表示0,1,2,3或4,其制备方法和合成纤维材料染色方法 并使用新的蒽醌 - 偶氮甲碱化合物着色有机高分子物质。
    • 18. 发明授权
    • Conditioning process for phthalocyanine pigments
    • 酞菁颜料的调理方法
    • US5284511A
    • 1994-02-08
    • US50686
    • 1993-04-12
    • Meinhard RolfAbdul Sattar
    • Meinhard RolfAbdul Sattar
    • C09B67/20C09B67/12C09B67/50C09B47/04
    • C09B67/0016
    • The present invention relates to a process for preparing a beta-phase metal phthalocyanine pigments in which(a) a crude metal phthalocyanine having an average particle size of about 10 to about 200 .mu.M is dry milled until the average particle size is reduced to about 0.01 to about 0.5 .mu.m;(b) the milled metal phthalocyanine is finished by thoroughly mixing said metal phthalocyanine with at least about 4 parts by weight, relative to the metal phthalocyanine, of a finishing solvent containing a mixture of(i) about 5 to 100 percent by weight, based on the total amount of finishing solvent, of a monocarboxylic acid monoester, dicarboxylic acid diester, diol diester, lactone, or cyclic carbonate, or a mixture thereof, and(ii) 0 to about 95 percent by weight, based on the total amount of finishing solvent, of water;(c) the ester used in step (b) is hydrolyzed; and(d) the beta-phase metal phthalocyanine pigment is collected.
    • 本发明涉及一种制备β-相金属酞菁颜料的方法,其中(a)将平均粒径为约10至约200(M)的M的粗金属酞菁干磨,直到平均粒径减小 至约0.01至约0.5(my)m; (b)通过将所述金属酞菁与相对于金属酞菁相比至少约4重量份的整理溶剂完全混合,所述最终溶剂含有(i)约5至100重量%的基于 单体羧酸单酯,二羧酸二酯,二醇二酯,内酯或环状碳酸酯的总量,或其混合物,和(ii)0〜95重量% 整理溶剂,水; (c)步骤(b)中使用的酯水解; 和(d)收集β相金属酞菁颜料。
    • 19. 发明授权
    • Anthraquinone-azo pyridone-containing compounds
    • 含蒽醌 - 偶氮吡啶酮的化合物
    • US4709019A
    • 1987-11-24
    • US486878
    • 1983-04-21
    • Meinhard RolfRutger NeeffWalter Muller
    • Meinhard RolfRutger NeeffWalter Muller
    • C09B56/12C09B29/01C09B29/42C09B29/36C09D1/08C09D5/00
    • C09B29/363C09B29/0018
    • Anthraquinone-azo pyridone-containing compounds which in one of their tautomeric structures, correspond to the formula ##STR1## in which A denotes an .alpha.-anthraquinone radical which is free from sulphonic acid groups and is unsubstituted or substituted and preferably consists of at most 5 fused rings;R.sub.1 denotes hydrogen; alkyl, preferably C.sub.1 -C.sub.4 -alkyl; aryl, preferably phenyl or naphthyl; carboxyl; carboxylic acid ester, preferably carboxylic acid C.sub.1 -C.sub.4 -alkyl ester; or hydroxyl andR.sub.2 denotes hydrogen; halogen; nitro; cyano; unsubstituted or substituted carbamoyl or sulphamoyl; alkylcarbonyl, in particular (C.sub.1 -C.sub.4 -alkyl)-carbonyl; alkoxycarbonyl, in particular (C.sub.1 -C.sub.4 -alkoxy)-carbonyl; alkyl- or unsubstituted or substituted aryl-sulphone, preferably C.sub.1 -C.sub.4 -alkyl-sulphone or unsubstituted or substituted phenylsulphone; or a hetero-aromatic radical, for example, a radical of the formula ##STR2## or of the formula ##STR3## Such anthraquinone-azo compounds, because of their fastness to light and migration, are suitable for use in producing fast pigmented systems.
    • 在其互变异构结构之一中的蒽醌 - 偶氮吡啶酮化合物对应于下式:其中A表示不含磺酸基团且未被取代或取代的α-蒽醌基团,优选由至多5个 稠环; R1表示氢; 烷基,优选C 1 -C 4 - 烷基; 芳基,优选苯基或萘基; 羧基; 羧酸酯,优选羧酸C1-C4烷基酯; 或羟基,R 2表示氢; 卤素; 硝基 氰基; 未取代的或取代的氨基甲酰基或氨磺酰基; 烷基羰基,特别是(C 1 -C 4 - 烷基) - 羰基; 烷氧基羰基,特别是(C 1 -C 4 - 烷氧基) - 羰基; 烷基或未取代或取代的芳基砜,优选C 1 -C 4 - 烷基 - 砜或未取代或取代的苯基砜; 或杂芳族基团,例如下式的基团或下式的化合物由于它们的光和迁移的牢度,这样的蒽醌 - 偶氮化合物适合用于生产快速着色的体系。