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11. 发明授权

US6013428A Color photographic recording material having a 2-equivalent magenta coupler and a white coupler 失效
标题翻译：具有2-当量品红色耦合器和白色耦合器的彩色照相记录材料
公开(公告)号：US6013428A
公开(公告)日：2000-01-11
申请号：US891391
申请日：1997-07-11
申请人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
发明人： Hans Langen , Heinrich Odenwalder , Uwe Dahlhaus
IPC分类号： C07C69/757 , G03C7/30 , G03C7/392 , G03C7/333
CPC分类号： C07C69/757 , G03C7/3012 , G03C7/39232 , G03C7/39236
摘要： A colour photographic recording material having at least one red-sensitive silver halide emulsion layer which is associated with a cyan coupler, at least one green-sensitive silver halide emulsion layer which is associated with a magenta coupler, at least one blue-sensitive silver halide emulsion layer which is associated with a yellow coupler contains in at least one green-sensitive silver halide emulsion layer a 2-equivalent pyrazolone coupler and in a photosensitive or non-photosensitive layer a white coupler of the formula (I) ##STR1## in which X.sup.1 means an acyl residue derived from an aliphatic, cycloaliphatic or aromatic carboxylic or sulphonic acid, a carbonic acid semi-ester or a carbamic acid,Z means the residue required to complete a saturated or partially unsaturated 5- or 6-membered carbocyclic ring which is optionally substituted and/or provided with a further fused ring or ring system.The colour images produced using the recording material exhibit elevated storage stability without a subsequent increase in fog or a subsequent increase in colour density or spotting occurring during storage.
摘要翻译：一种彩色照相记录材料，其具有与青色成色剂相关联的至少一种感红卤化银乳剂层，与品红色成色剂相关的至少一种感绿卤化银乳剂层，至少一种蓝敏感卤化银与黄色成色剂相关联的乳剂层在至少一种感绿卤化银乳剂层中含有2-当量吡唑啉酮偶联剂，在光敏或非感光层中含有式（I）的白色偶联剂，其中X1表示衍生自脂族，脂环族或芳族羧酸或磺酸，碳酸半酯或氨基甲酸的酰基残基Z表示完成饱和或部分不饱和的5-或6-元碳环所需的残基，其任选被取代和/或设置有另外的稠环或环系统。使用记录材料产生的彩色图像表现出提高的储存稳定性，而不会随后增加雾度，或随后的颜色密度增加或储存期间发生斑点。

12. 发明授权

US5407789A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US5407789A
公开(公告)日：1995-04-18
申请号：US190686
申请日：1994-02-01
申请人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
发明人： Heinrich Odenwalder , Hans hlschlager , Thomas Stetzer
IPC分类号： G03C7/305 , C07D249/12 , C07D271/10 , C07D271/113 , C07D405/04 , C07D413/04 , G03C7/392 , G03C1/46
CPC分类号： C07D271/113 , C07D249/12 , C07D405/04 , C07D413/04 , G03C7/39228 , G03C7/39256 , G03C7/39272
摘要： A photographic recording material on a transparent support having at least one light-sensitive silver halide emulsion layer and optionally conventional interlayers and protective layers, characterized in that the photographic recording material contains, in at least one of the above-mentioned layers, a compound corresponding to formula I, II or III ##STR1## wherein R.sub.1 denotes an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted heterocyclic group,R2 denotes hydrogen, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryl group or an unsubstituted or substituted alkylthio group,R.sub.3 denotes hydrogen or an unsubstituted or substituted alkyl group,R4 denotes an unsubstituted or substituted alkyl group, an unsubstituted or a substituted aryl group or an unsubstituted or substituted heterocyclic group,X denotes an alkylene group having 1 to 8 carbon atoms in which the carbon chain may be interrupted by oxygen or sulphur atoms, or it denotes an arylene group, andZ denotes hydrogen, a cation or a precursor compound thereof which is capable of releasing the mercapto compound non-imagewise in the course of development,is distinguished by excellent interimage and edge effects and by improved sharpness and graininess compared with conventional materials.
摘要翻译：在透明支撑体上的具有至少一个感光卤化银乳剂层和任选的常规中间层和保护层的照相记录材料，其特征在于，照相记录材料在至少一个上述层中含有相应的化合物其中R 1表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，R 2表示氢，未取代或取代的烷基，未取代或取代的芳基或未取代或取代的烷硫基，R 3表示氢或未取代或取代的烷基，R 4表示未取代或取代的烷基，未取代或取代的芳基或未取代或取代的杂环基，X表示具有1至8个碳链可被中断的碳原子或者表示亚芳基，Z表示氢，可以在显影过程中非成像地释放巯基化合物的阳离子或其前体化合物，其特征在于优异的图像和边缘效果，通过与常规材料相比提高清晰度和颗粒度。

13. 发明授权

US5266449A Bleaching bath 失效
标题翻译：漂白浴
公开(公告)号：US5266449A
公开(公告)日：1993-11-30
申请号：US969490
申请日：1992-10-30
申请人： Christa Dacke , Heinrich Odenwalder , Hans Langen
发明人： Christa Dacke , Heinrich Odenwalder , Hans Langen
IPC分类号： C07D249/04 , C07D249/08 , G03C5/39 , G03C5/44 , G03C7/42 , G03C7/28
CPC分类号： G03C7/42
摘要： A bleaching bath for processing of a color photographic silver halide material which contains the ferric complex of alaninediacetic acid as the bleaching agent and in a dye-stabilizing amount a formaldehyde precursor of the formula ##STR1## wherein X and Y denote the residual atoms of a hetero aromatic 5- or 6-membered ring,yields color photographic images with excellent dye-stabilizing. In the atmosphere above the stabilizing bath no formaldehyde is detectable.
摘要翻译：一种用于加工彩色照相卤化银材料的漂白浴，其含有丙氨酸二乙酸的三元配合物作为漂白剂，并且在染料稳定量下具有式（I）的甲醛前体，其中X和Y表示残基杂芳族5-或6-元环的原子产生具有优异染料稳定性的彩色摄影图像。在稳定浴上方的气氛中，无法检测到甲醛。

14. 发明授权

US5021332A Color photographic recording material containing a DIR coupler 失效
标题翻译：含有DIR耦合器的彩色照相记录材料
公开(公告)号：US5021332A
公开(公告)日：1991-06-04
申请号：US528045
申请日：1990-05-23
申请人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
发明人： Peter Bergthaller , Thomas Kruger , Hans Vetter , Heinrich Odenwalder
IPC分类号： G03C7/26 , C07D403/06 , G03C7/305 , G03C7/32 , G03C7/392
CPC分类号： C07D403/06 , G03C7/30535 , Y10S430/158
摘要： Good edge effects and inter-image effects are obtained where DIR couplers corresponding to formula I are used in color photogrpahic silver halide materials. ##STR1## in which R.sup.1 is H, Cl, --CF.sub.3, alkoxy, sulfamoyl;R.sup.2 is H, Cl, alkyl, cycloalkyl, alkoxy, alkoxycarbonyl, carbamoyl;n is 0, 1 or 2;X is O or S;Y is a group with a silver halide development inhibiting function releasable during color development;Z is benzoyl, pivaloyl, carbamoyl or a quinazolin-4-on-2-yl group.
摘要翻译：获得良好的边缘效果和图像间效果，其中对应于式I的DIR成色剂用于彩色光致卤化银材料。（I）其中R1是H，Cl，-CF3，烷氧基，氨磺酰基; R2是H，Cl，烷基，环烷基，烷氧基，烷氧基羰基，氨基甲酰基; n为0,1或2; X是O或S; Y是具有在显色期间可释放的卤化银显影抑制功能的组; Z是苯甲酰基，新戊酰基，氨基甲酰基或喹唑啉-4-基-2-基。

15. 发明授权

US4897341A Color photographic recording material containing a dir-coupler 失效
标题翻译：含有双向耦合器的彩色照相记录材料
公开(公告)号：US4897341A
公开(公告)日：1990-01-30
申请号：US109762
申请日：1987-10-19
申请人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
发明人： Heinrich Odenwalder , Hans Ohlschlager , Friedrich-Wilhelm Kunitz , Dirk Hubner
IPC分类号： G03C7/36 , G03C7/305
CPC分类号： G03C7/30535
摘要： Remarkably high inter-image and edge effects are obtained when DIR-Couplers corresponding to Formula I are added to multilayered color photographic recording materials, in particular to green sensitive or red sensitive layers. The sharpness and color reproduction may thereby be improved. ##STR1## R.sup.1 and R.sup.2 denote alkyl or an aromatic group, R.sup.3 denotes H, alkyl or acylamino,R.sup.4 denotes H or alkylR.sup.5 denotes alkyl, alkinyl, aryl, acyloxy, carbamoyl or a cyclic imido group andn has the value 0 or 1and the total number of carbon atoms in R.sup.3, R.sup.4 and R.sup.5 is greater than 3 but not greater than 11.
摘要翻译：当将对应于式I的DIR耦合器添加到多层彩色照相记录材料，特别是绿色敏感层或红色敏感层时，可获得非常高的图像间和边缘效应。从而可以提高清晰度和色彩再现。 R1和R2表示烷基或芳基，R3表示H，烷基或酰氨基，R4表示H或烷基R5表示烷基，炔基，芳基，酰氧基，氨基甲酰基或环状酰亚胺基，n的数值为0或 1，R3，R4和R5中的碳原子总数大于3但不大于11。

16. 发明授权

US4420557A Color photographic recording material containing a non-diffusible electron donor precursor compound 失效
标题翻译：含有不扩散电子给体前体化合物的彩色照相记录材料
公开(公告)号：US4420557A
公开(公告)日：1983-12-13
申请号：US436581
申请日：1982-10-25
申请人： Heinrich Odenwalder , Paul Marx
发明人： Heinrich Odenwalder , Paul Marx
IPC分类号： G03C7/26 , G03C8/08 , G03C8/36 , G03C1/40 , G03C1/06 , G03C1/48 , G03C5/30
CPC分类号： G03C8/08 , Y10S430/16
摘要： Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.
摘要翻译：对应于下式的化合物：其中R 1表示芳族基团，R 2表示H，烷基，烯基，芳基或酰基，是用于彩色照相记录材料的合适的ED前体化合物。它们优选与可还原的染料释放剂组合使用。它们也适合作为所谓的清道夫。

17. 发明授权

US5922524A Colour photographic recording material 失效
标题翻译：彩色摄影材料
公开(公告)号：US5922524A
公开(公告)日：1999-07-13
申请号：US794098
申请日：1997-02-03
申请人： Ralf Buscher , Peter Bell , Hans-Ulrich Borst , Jorg Siegel , Johannes Willsau , Heinrich Odenwalder
发明人： Ralf Buscher , Peter Bell , Hans-Ulrich Borst , Jorg Siegel , Johannes Willsau , Heinrich Odenwalder
IPC分类号： G03C7/00 , G03C7/30 , G03C7/305 , G03C7/32 , G03C1/08 , G03C7/26
CPC分类号： G03C7/3029 , Y10S430/156
摘要： A colour photographic recording material having camera sensitivity, possessing on a transparent support at least one silver halide emulsion layer unit which is sensitive to part of the visible spectrum and consists of at least the following constituent layers:a) a spectrally sensitised silver halide emulsion layer containing an effective quantity of a FAR coupler (coupler, which during coupling releases groups producing fogging nuclei) and optionally a colour coupler, the latter during the colour development process coupling with a dye of which the colour is complementary to the spectral sensitisation of layer a), andb) a fine-grained silver halide emulsion layer having low light-sensitivity, of which the silver halide grains are not spectrally sensitised, being a layer adjacent to layer a),with layer b) containing a colour coupler which during the colour development process couples with a dye of which the colour is complementary to the spectral sensitisation of layer a) and the molar quantity of colour couplers in layer b) being greater than in layer a), is distinguished by improved graininess at higher sensitivity.
摘要翻译：具有相机灵敏度的彩色照相记录材料，在透明支撑体上具有对可见光谱的一部分敏感并由至少以下构成层组成的至少一个卤化银乳剂层单元：a）光谱增感的卤化银乳剂层包含有效量的FAR耦合器（耦合器，其在耦合释放期间产生起雾核）和任选的颜色耦合器，后者在显色过程中与其颜色与层a的光谱增感互补的染料）和b）具有低光敏感性的细粒度卤化银乳剂层，其中卤化银颗粒不受光谱敏化，是与层a）相邻的层，其中层b）包含颜色耦合器，其在色彩发展过程与色素互补的染料与a）和mol的光谱增感相互补充在b）中大于a）层中的成色剂的数量的特征在于在更高的灵敏度下改善的颗粒度。

18. 发明授权

US5702877A Color photographic silver halide material 失效
标题翻译：彩色照相卤化银材料
公开(公告)号：US5702877A
公开(公告)日：1997-12-30
申请号：US605475
申请日：1996-02-26
申请人： Heinrich Odenwalder , Hans Langen , Uwe Dahlhaus , Heinz-Dieter Schutz
发明人： Heinrich Odenwalder , Hans Langen , Uwe Dahlhaus , Heinz-Dieter Schutz
IPC分类号： G03C7/00 , C07D231/22 , G03C7/30 , G03C7/38 , G03C7/392 , G03C7/32
CPC分类号： C07D231/22 , G03C7/39252 , G03C7/3008
摘要： A colour photographic silver halide material with a support, at least one silver halide emulsion layer and at least one non-light sensitive layer applied thereto, wherein the silver halide emulsion layer contains at least one colour coupler, and wherein the silver halide emulsion layer or the non-light sensitive layer contains a compound of the formula (I) ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 mean hydrogen or an organic residue and n means 0 or an integer from 1 to 4 or R.sub.1 and R.sub.2 together, R.sub.1 and an adjacent residue R.sub.3 together or two adjacent residues R.sub.3 together form a carbocyclic or heterocyclic ring with 5 to 7 ring atoms or R.sub.1, R.sub.2 or R.sub.3 mean a bridging member by means of which two compounds of the formula (I) are attached together or R.sub.1, R.sub.2 or R.sub.3 are attached to a polymer via a bridging member, wherein at least one of the substituents R.sub.1, R.sub.2 and R.sub.3 is an organic residue, is distinguished by improved grain.
摘要翻译：一种具有载体的彩色照相卤化银材料，至少一种卤化银乳剂层和施加于其上的至少一种非光敏层，其中所述卤化银乳剂层含有至少一种颜色成色剂，并且其中所述卤化银乳剂层或非感光层含有式（I）的化合物，其中R 1，R 2和R 3表示氢或有机残基，n表示0或1至4的整数或R 1和R 2一起，R 1和相邻的残基R3一起或两个相邻的残基R3一起形成具有5至7个环原子的碳环或杂环，或者R 1，R 2或R 3表示通过其连接两个式（I）化合物的桥连构件一起或R 1，R 2或R 3通过桥连构件连接到聚合物上，其中取代基R 1，R 2和R 3中的至少一个是有机残基，其特征在于改进的颗粒。

19. 发明授权

US5306605A Photographic recording material 失效
标题翻译：摄影记录材料
公开(公告)号：US5306605A
公开(公告)日：1994-04-26
申请号：US42585
申请日：1993-04-05
申请人： Heinrich Odenwalder , Lothar Rosenhahn , Thomas Stetzer
发明人： Heinrich Odenwalder , Lothar Rosenhahn , Thomas Stetzer
IPC分类号： G03C1/035 , C07D249/12 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/12 , C07D417/12 , G03C1/43 , G03C5/50 , G03C7/305 , G03C7/32 , G03C1/34 , G03C1/42
CPC分类号： C07D401/12 , C07D249/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D413/10 , C07D417/12 , G03C7/305 , Y10S430/158 , Y10S430/16
摘要： A photographic recording material comprising a carrier and at least one photosensitive silver halide emulsion layer, a non-photosensitive layer and optional conventional intermediate and protective layers, characterised in that the photographic recording material (1) contains at least one silver halide emulsion layer having a silver iodide content .gtoreq.3 mol % and an average grain diameter .ltoreq.0.4 .mu.m, and (2), at least in one layer, contains a compound having the formula I ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 denote hydrogen, an optionally substituted hydrocarbon radical, an optionally substituted alkylthio, alkyloxy or arylthio radical, an optionally substituted amino group, OH or halogen or R.sup.1 and R.sup.2 together denote the radical for completing a carbocyclic or heterocyclic ring,R.sub.4, R.sub.5 denote hydrogen, an optionally substituted alkyl or aryl radical, or an optionally substituted heterocyclic radical,R.sub.6, R.sub.7 denote hydrogen or a radical which can be split off in alkaline solution, andR.sub.8 denotes hydrogen, an optionally substituted alkyl or aryl radical, or an optionally substituted alkylthio radical.The material gives excellent inter-image and edge-effects and has improved sharpness and grain as compared with conventional materials.
摘要翻译：一种照相记录材料，其包含载体和至少一种光敏卤化银乳剂层，非感光层和任选的常规中间和保护层，其特征在于，照相记录材料（1）含有至少一个卤化银乳剂层，其具有碘化银含量> 3mol％，平均粒径<= 0.4（my）m，（2）至少在一层中含有具有式I（*化学结构*）（I）的化合物，其中 R 1，R 2和R 3表示氢，任选取代的烃基，任选取代的烷硫基，烷氧基或芳硫基，任选取代的氨基，OH或卤素或R 1和R 2一起表示用于完成碳环或杂环的基团，R 4 R5代表氢，任选取代的烷基或芳基或任选取代的杂环基，R 6，R 7表示氢或可在碱性下分解的基团并且R8表示氢，任选取代的烷基或芳基或任选取代的烷硫基。与常规材料相比，该材料具有优异的图像间和边缘效应，并且提高了锐度和纹理。

20. 发明授权

US5215875A Color photographic recording material 失效
标题翻译：彩色摄影记录材料
公开(公告)号：US5215875A
公开(公告)日：1993-06-01
申请号：US712258
申请日：1991-06-07
申请人： Reinhart Matejec , Hans Vetter , Heinrich Odenwalder
发明人： Reinhart Matejec , Hans Vetter , Heinrich Odenwalder
IPC分类号： G03C5/42 , G03C1/74 , G03C7/00 , G03C7/30 , G03C7/392 , G03C7/407
CPC分类号： G03C7/39224 , G03C7/302 , G03C7/3022 , Y10S430/144
摘要： A color photographic recording material comprising at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler and typical intermediate and protective layers, in which the silver halide coating of all the photosensitive layers, expressed as AgNO.sub.3, amounts to no more than 0.3 g/m.sup.2 and the color-coupler-containing layers contain at least one p-phenylenediamine compound containing at least one primary amino group and at least one ballast group dissolved in hydrophobic oil droplets, can be developed in an environment-friendly manner using an intensifying bath.
摘要翻译：一种彩色照相记录材料，其包含至少一种含有至少一种黄色成色剂的感蓝卤化银乳剂层，至少一种含有至少一种品红成色剂的至少一种感绿卤化银乳剂层和至少一种感红卤化银乳剂层含有至少一个青色成色剂和典型的中间和保护层，其中以AgNO 3表示的所有感光层的卤化银涂层不超过0.3g / m 2，并且含色调剂的层含有至少一种可以使用强化浴以环保的方式显影含有至少一个伯氨基和至少一个溶解在疏水性油滴中的压载物的对苯二胺化合物。

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