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    • 14. 发明申请
    • Method for the Manufacture of Microparticles Comprising an Effect Substance
    • 包含影响物质的微粒的制造方法
    • US20110230343A1
    • 2011-09-22
    • US13125388
    • 2009-10-14
    • Michael SchroersRainer Dyllick-BrenzingerMichael MerkHeiko Barg
    • Michael SchroersRainer Dyllick-BrenzingerMichael MerkHeiko Barg
    • A01C1/06C12P7/62C12P13/00C12P17/02A01N25/28A01P3/00A01P7/02A01P7/04A01P13/00A23K1/16A23L1/30
    • B01J13/14
    • A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.
    • 本发明的主题是制备包含效应化合物的微粒M的方法,其包括:A)通过酶促聚酯合成在包含酶,效应化合物和聚酯单体的反相微乳液中形成微粒A的粗悬浮液 ; 和B)在微粒A的粗悬浮液中聚合来自由烯属不饱和单体,多异氰酸酯和聚环氧化物组成的组的壁单体。此外,本发明涉及可通过本发明的方法获得的微粒M 还涉及包含微粒M的农用化学制剂。此外,本发明涉及根据本发明制备的微粒M作为着色剂,化妆品,药​​物,杀生物剂,植物保护剂,肥料,食品或动物添加剂的组分的用途 饲料或聚合物,纸,纺织品,皮革,洗涤剂或清洁剂的助剂。 最后,本发明还涉及一种防止不期望的植物生长的方法,一种防治植物上不希望的昆虫或螨虫侵袭和/或防治植物病原性真菌的方法,以及用农药制剂处理的种子。
    • 20. 发明授权
    • Anilines as markers for mineral oils
    • 苯胺作为矿物油的标记物
    • US5627077A
    • 1997-05-06
    • US424497
    • 1995-06-22
    • Rainer Dyllick-BrenzingerFriedrich-Wilhelm RaulfsUlrike Schlosser
    • Rainer Dyllick-BrenzingerFriedrich-Wilhelm RaulfsUlrike Schlosser
    • C07D209/08C07D295/096C10L1/00C10L1/14C10L1/16C10L1/22C10L1/223C10L1/24C10M169/04C10M171/00C10N30/20G01N33/28G01N33/00G01N37/00
    • C10L1/003C07D209/08C07D295/096C10L1/14C10L1/22C10L1/223C10L1/2235C10M171/007G01N33/2882C10L1/143C10L1/1608C10L1/1616C10L1/2227C10L1/224C10L1/2286C10L1/231C10L1/232C10L1/2335C10L1/2412C10L1/2418C10L1/2431C10L1/2437Y10T436/13Y10T436/17Y10T436/255
    • Anilines of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, unsubstituted or substituted alkyl, alkenyl or unsubstituted or substituted phenyl orR.sup.1 and R.sup.2, together with the nitrogen atom linking them are a heterocyclic radical or R.sup.1 may furthermore be unsubstituted or substituted hydroxyl or unsubstituted or substituted amino,R.sup.3 and R.sup.7 are each hydrogen, unsubstituted or substituted alkyl, alkenyl, cyano, nitro, acyl, acylamino, unsubstituted or substituted hydroxyl, unsubstituted or substituted carboxymethyl, unsubstituted or substituted amino, unsubstituted or substituted mercapto or unsubstituted or substituted sulfamoyl or, together with R.sup.2, are alkylene, alkenylene or phenylalkenylene,R.sup.4 is hydrogen, unsubstituted or substituted alkyl, alkenyl, unsubstituted or substituted hydroxyl, unsubstituted or substituted amino, unsubstituted or substituted carboxyl or unsubstituted or substituted sulfamoyl andR.sup.5 and R.sup.6 are each hydrogen, unsubstituted or substituted alkyl, alkenyl, unsubstituted or substituted phenyl, nitro, acylamino, unsubstituted or substituted hydroxyl, unsubstituted or substituted amino, unsubstituted or substituted sulfamoyl, alkyl-, alkenyl- or arylsulfonyl, acyl or unsubstituted or substituted carboxyl,with the proviso that at least one of the radicals R.sup.3, R.sup.5 or R.sup.7 is hydrogen,are used for marking mineral oils, and the above-mentioned anilines are detected in mineral oils.
    • PCT No.PCT / EP93 / 03133 Sec。 371日期:1995年6月22日 102(e)日期1995年6月22日PCT 1993年11月9日PCT公布。 公开号WO94 / 11466 日期:1994年5月26日公式其中R 1和R 2各自为氢,未取代或取代的烷基,烯基或未取代或取代的苯基或R 1和R 2与其连接的氮原子的式(I)的氨基是杂环基或 R 1还可以是未取代的或取代的羟基或未取代或取代的氨基,R 3和R 7各自为氢,未取代或取代的烷基,烯基,氰基,硝基,酰基,酰氨基,未取代或取代的羟基,未取代或取代的羧甲基,未取代或取代的氨基 未取代或取代的巯基或未取代或取代的氨磺酰基,或与R2一起为亚烷基,亚烯基或苯基亚烯基,R4为氢,未取代或取代的烷基,烯基,未取代或取代的羟基,未取代或取代的氨基,未取代或取代的羧基或未取代的 或取代的氨磺酰基,且R 5和R 6各自为未经取代或未取代的氢 取代的烷基,烯基,未取代或取代的苯基,硝基,酰基氨基,未取代或取代的羟基,未取代或取代的氨基,未取代或取代的氨磺酰基,烷基 - ,烯基 - 或芳基磺酰基,酰基或未取代或取代的羧基,条件是至少 基团R3,R5或R7之一是氢,用于标记矿物油,并且在矿物油中检测到上述苯胺。