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    • 13. 发明授权
    • Washing liquid for semiconductor substrate and method of producing semiconductor device
    • 用于半导体衬底的洗涤液及其制造方法
    • US07176173B2
    • 2007-02-13
    • US10659190
    • 2003-09-10
    • Masayuki Takashima
    • Masayuki Takashima
    • C11D1/62
    • H01L21/02074C11D3/221C11D7/06C11D11/0047C23G1/24
    • An object of the present invention is to provide washing liquid for semiconductor substrate capable of removing grinding grains of silica, alumina or the like in a polishing agent and polishing trashes of copper, and capable of leaving little organic substance due to an additive used for preventing corrosion of copper on the surface of a copper wiring after washing, while corrosion of copper is suppressed, and a method of producing a semiconductor device using this washing liquid. The object is achieved by washing liquid for a semiconductor substrate having a copper wiring, comprising a basic compound and at least one selected from the group consisting of sugar alcohols and saccharides. Also the present invention provides a method of producing a semiconductor device comprising a step of forming a copper wiring by chemical mechanical polishing and washing it with washing liquid for a semiconductor substrate containing a basic compound and at least one selected from the group consisting of sugar alcohols and saccharides.
    • 本发明的目的是提供一种用于半导体衬底的洗涤液,其能够除去研磨剂中的二氧化硅,氧化铝等的研磨颗粒,并抛光铜的抛光物质,并且由于用于预防的添加剂而能够留下少量有机物质 洗涤后铜线表面的铜的腐蚀,同时铜的腐蚀被抑制,以及使用该洗涤液的半导体装置的制造方法。 该目的是通过洗涤具有铜布线的半导体衬底的液体来实现的,其包括碱性化合物和选自糖醇和糖类的至少一种。 本发明还提供一种半导体器件的制造方法,其包括通过化学机械抛光形成铜布线并用含有碱性化合物的半导体基板的洗涤液和从糖醇中选择的至少一种 和糖。
    • 14. 发明申请
    • Photoresist stripper composition
    • 光刻胶剥离剂组合物
    • US20050287480A1
    • 2005-12-29
    • US11096681
    • 2005-03-31
    • Masayuki Takashima
    • Masayuki Takashima
    • G03F7/42G03C5/00H01L21/027H01L21/304
    • G03F7/423
    • (Problem) It is to provide a stripper having excellent ability to suppress corrosion or damage to the copper wiring or the low-k film, and having excellent photoresist residue removability after ashing. (Solution) The invention provides a photoresist stripper composition characterized in containing salts of at least two different inorganic acids, surfactants and a corrosion inhibitor for metal, and having a pH in the range of 3-10; and a process for preparation of semiconductor devices characterized in that the photoresist residues generated during the preparation of semiconductor devices which employs copper or a copper-dominant alloy as the material for wiring is stripped using said photoresist stripper.
    • (问题)提供具有优异的抑制铜布线或低k膜的腐蚀或损坏的能力的剥离器,并且在灰化后具有优异的光致抗蚀剂残留物去除性。 (溶液)本发明提供一种光致抗蚀剂剥离剂组合物,其特征在于含有至少两种不同的无机酸,表面活性剂和金属腐蚀抑制剂的盐,并且pH在3-10的范围内; 以及半导体器件的制备方法,其特征在于,使用所述光致抗蚀剂剥离剂剥离在制备半导体器件期间产生的光致抗蚀剂残留物,其使用铜或铜主导合金作为布线材料。
    • 15. 发明授权
    • Toner supply device for a developing apparatus
    • 用于显影装置的调色剂供应装置
    • US4949123A
    • 1990-08-14
    • US317564
    • 1989-03-01
    • Masayuki Takashima
    • Masayuki Takashima
    • G03G15/08
    • G03G15/0872G03G2215/0665G03G2215/0675Y10S222/01
    • A toner supply device for supplying a toner to a developing apparatus of an electrophotographic copier or similar image recorder is implemented by a cylindrical toner tank mounted on the apparatus and a toner cartridge filled with a toner and removably loaded in the toner tank. A hook-like yieldable stop is fitted on the toner tank, while lugs having contiguous inclined surface are provided on the toner cartridge for urging the stop when the cartridge is inserted into the tank. The stop and lugs allow only a toner cartridge of exclusive kind associated with the image recorder to be inserted into the toner tank.
    • 用于向电子照相复印机或类似图像记录器的显影装置供应调色剂的调色剂供应装置通过安装在设备上的圆柱形调色剂罐和填充有调色剂并可移除地装载在调色剂罐中的调色剂盒来实现。 在调色剂盒上安装有钩形可屈服的止动件,而当墨盒插入墨盒时,具有相邻倾斜表面的凸耳设置在调色剂盒上用于推动止动件。 止动件和接片仅允许将与图像记录器相关的专有墨粉盒插入墨粉盒。
    • 18. 发明授权
    • Electronic parts cleaning solution
    • 电子零件清洗液
    • US07485612B2
    • 2009-02-03
    • US11174061
    • 2005-06-30
    • Masayuki Takashima
    • Masayuki Takashima
    • H01L21/00
    • C11D11/0047H01L21/02052H01L21/02068
    • (Object) To provide a new electronic parts cleaning solution that inhibits the corrosion of silicon or metals other than the silicon, and that efficiently cleans off fine dust or organic matters adhered on the surface of electronic parts, and that does not have white turbidity easily.(Solution) An electronic parts clearing solution which is characterized in containing an anionic surfactant, hydroxide, metal corrosion inhibitor, water, and a nonionic surfactant represented by formula (I) and/or a nonionic surfactant represented by formula (II): HO-((EO)x—(PO)y)z—H  (I) R-[((EO)a—(PO)b)c—H]m  (II) (EO is an oxyethylene group, and PO is an oxypropylene group. x and y, and a and b are positive number, which x(x+y) and a(a+b) are 0.05 to 0.5 respectively, and z and c are positive integers. R is a residue group wherein hydrogen atoms are removed from hydroxyl group of alcohol or amine represented by a group having valency of 1˜4).
    • (目的)提供抑制硅或金属以外的硅腐蚀的新的电子部件清洗液,能够有效地清除附着在电子部件表面的细小尘埃或有机物,并且不容易发生白浊 。 (溶液)一种电子部件清除液,其特征在于含有式(I)所示的阴离子表面活性剂,氢氧化物,金属缓蚀剂,水和非离子表面活性剂和/或式(II)表示的非离子性表面活性剂: 在线公式描述=“在线公式”end =“lead”?HO - ((EO)x-(PO)y)zH(I)<?in-line-formula description =“In-line 公式“end =”tail“?> <?in-line-formula description =”In-line Formulas“end =”lead“?> R - [((EO)a-(PO)b)cH] m (EO是氧化乙烯基,PO是氧化亚丙基)x和y,a和b是正数,其中 x(x + y)和a(a + b)分别为0.05〜0.5,z和c为正整数,R为残基,其中氢原子由醇或胺的羟基除去, 1〜4)。
    • 19. 发明授权
    • Photoresist stripper
    • 光阻剥离器
    • US07199091B2
    • 2007-04-03
    • US11110533
    • 2005-04-19
    • Masayuki Takashima
    • Masayuki Takashima
    • C11D1/02C11D3/26C11D3/30
    • C11D3/046C11D3/042C11D3/044C11D3/30C11D11/0047
    • Recently, use is made of copper wiring as the wiring material for semiconductor devices, and of low dielectric constant films as the insulating film between the lines of wiring. In this connection, a photoresist stripper is in need which can inhibit corrosion or damage on the copper wiring or the Low-k film, and which has excellent property of removing ashed photoresist residues. The invention provides a photoresist stripper (hereinafter, referred to as the stripper of the invention) characterized in containing a tertiary amine compound, an alkaline compound, a fluoro compound, and an anionic surfactant; and a process for preparation of semiconductor devices using the stripper of the invention.
    • 近来,使用铜布线作为半导体器件的布线材料,并且使用作为布线之间的绝缘膜的低介电常数膜。 在这方面,需要能够抑制对铜布线或Low-k膜的腐蚀或损伤的光致抗蚀剂剥离剂,其具有除去灰化的光致抗蚀剂残留物的优异性能。 本发明提供一种特征在于含有叔胺化合物,碱性化合物,氟化合物和阴离子表面活性剂的光致抗蚀剂剥离剂(以下称为本发明的剥离剂) 以及使用本发明的脱模剂制备半导体器件的方法。