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    • 13. 发明申请
    • Process for producing cycloalkanol and/or cycloalkanone
    • 制备环烷醇和/或环烷酮的方法
    • US20060020149A1
    • 2006-01-26
    • US11183920
    • 2005-07-19
    • Hajime Ishida
    • Hajime Ishida
    • C07D487/22C07C45/28
    • C07C45/33C07C29/50C07C2601/14C07C49/403C07C35/08
    • The object of the present invention is to produce cycloalkanol and/or cycloalkanone with good selectivity by oxidizing cycloalkane with molecular oxygen. The method of the present invention comprises the step of oxidizing cycloalkane with molecular oxygen in the presence of cobalt salt of carboxylic acid and cobalt complex with porphyrin as a ligand; such cobalt complex typically represented by the formula (1): (wherein, each of X1 to X8 independently represents a hydrogen atom, a halogen atom, a nitro group, a cyano group, a hydrocarbon group, a halogenated hydrocarbon group or a sulfonyl group, each of R1 to R4 independently represents a hydrogen atom, a nitro group, a cyano group, a hydrocarbon group or a halogenated hydrocarbon group.)
    • 本发明的目的是通过用分子氧氧化环烷烃来制备具有良好选择性的环烷醇和/或环烷酮。 本发明的方法包括在羧酸和钴配合物的钴盐与卟啉作为配体的存在下,用分子氧氧化环烷烃的步骤; 通常由式(1)表示的这种钴络合物:(其中X 1至X 8各自独立地表示氢原子,卤素原子,硝基, 氰基,烃基,卤代烃基或磺酰基,R 1至R 4各自独立地表示氢原子,硝基,氰基 基团,烃基或卤代烃基)
    • 16. 发明授权
    • Process for producing cycloalkanol and/or cycloalkanone
    • 制备环烷醇和/或环烷酮的方法
    • US07632942B2
    • 2009-12-15
    • US11183920
    • 2005-07-19
    • Hajime Ishida
    • Hajime Ishida
    • C07C29/48C07B47/00
    • C07C45/33C07C29/50C07C2601/14C07C49/403C07C35/08
    • The object of the present invention is to produce cycloalkanol and/or cycloalkanone with good selectivity by oxidizing cycloalkane with molecular oxygen. The method of the present invention contains the step of oxidizing cycloalkane with molecular oxygen in the presence of cobalt salt of carboxylic acid and cobalt complex with porphyrin as a ligand, the cobalt complex with porphyrin as a ligand being a compound represented by the formula (1): wherein each of X1 to X8 independently represents a hydrogen atom, a halogen atom, a nitro group, a cyano group, a hydrocarbon group, a halogenated hydrocarbon group or a sulfonyl group, and each of R1 to R4 independently represents a hydrogen atom, a nitro group, a cyano group, a hydrocarbon group or a halogenated hydrocarbon group.
    • 本发明的目的是通过用分子氧氧化环烷烃来制备具有良好选择性的环烷醇和/或环烷酮。 本发明的方法包括在羧酸和钴配合物的钴盐与卟啉作为配体的存在下,用分子氧氧化环烷烃的步骤,与卟啉作为配体的钴络合物是由式(1)表示的化合物 ):其中X1〜X8各自独立地表示氢原子,卤素原子,硝基,氰基,烃基,卤代烃基或磺酰基,R 1〜R 4各自独立地表示氢原子 硝基,氰基,烃基或卤代烃基。
    • 19. 发明授权
    • Baby chair and bed
    • 婴儿椅和床
    • US4084849A
    • 1978-04-18
    • US726231
    • 1976-09-24
    • Hajime IshidaMitsuyo Tsumita
    • Hajime IshidaMitsuyo Tsumita
    • A47D1/00A47D11/00A47C1/034
    • A47D11/005A47D1/002
    • The present invention relates to a combination chair and bed for small children featuring a back and seat rotatably mounted to each other, a footrest rotatably mounted to the seat, a support rod having legs spaced apart from each other and an intermediate connecting portion, the ends of the leg portions being connected to the footrest permitting rotation therebetween, the legs also being connected to the back permitting rotation therebetween, a locking rod having ends and an intermediate portion, the ends of the locking rod being connected to the legs of the support rod permitting rotation therebetween, and a positioning and locking mechanism connecting the intermediate portion of the locking rod to the back at a plurality of predetermined positions therealong such that the back, seat and footrest may assume a flat position defining a bed, a collapsed position for carrying and storage, and a plurality of intermediate positions when functioning as a chair.
    • 本发明涉及一种用于小孩子的组合式椅子和床,其特征在于可相互安装的后座和座椅,可旋转地安装在座椅上的脚凳,具有彼此间隔开的腿部的支撑杆和中间连接部分, 所述腿部连接到所述脚踏板以允许其间旋转,所述腿还连接到所述后部允许的旋转,锁定杆具有端部和中间部分,所述锁定杆的端部连接到所述支撑杆的腿部 允许在其间旋转;以及定位和锁定机构,其将锁定杆的中间部分连接到后面的多个预定位置,使得后部,座椅和脚踏板可以呈现限定床的平坦位置,用于承载的折叠位置 和存储,以及当用作椅子时的多个中间位置。