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11. 发明专利

JPS5962551A Preparation of dinitrophenyl ethers 失效
标题翻译： DININROPHENYL ETHERS的制备
公开(公告)号：JPS5962551A
公开(公告)日：1984-04-10
申请号：JP17226582
申请日：1982-09-30
申请人： Chisso Corp , Kaken Pharmaceut Co Ltd
发明人： OGAWA TETSUYA , SAITOU SHINICHI , INOI TAKESHI , KATOU MASAJI , OBARA HEITAROU
IPC分类号： C07C67/00 , C07C201/00 , C07C201/12 , C07C205/33 , C07C205/36 , C07C205/37 , C07C205/38
CPC分类号： C07C201/12 , C07C205/36 , C07C205/37 , C07C205/38
摘要： PURPOSE: To obtain a dinitrophenyl ether easily in high yield without using a halide compound as an intermediate, by reacting dinitrophenyl methyl ether with a specific alcohol in the presence of an alkaline compound.
CONSTITUTION: A compound shown by the formula I (one of R
1 and R
2 is nitro, and the other is H, 1W10C straight-chain, branched chain, or cyclic hydrocarbon) is reacted with a compound shown by the formula R
3 OH (R
3 is 2W10C straight- chanin, branched, cyclic hydrocarbon, 1W5C straight-chain hydrocarbon having one phenyl group as a substituent group, etc.) in the presence of an alkali compound (e.g., NaOH, KOH, pyridine, etc.) in a solvent such as benzene, hexane, etc. or in the absence of it at 60W180°C to give the desired compound shown by the formula II. The amount of the alkaline compound used as the catalyst is 1/2W1/10 based on the compound shown by the formula I , and equimolar amounts of the compound shown by the formula I and the compound shown by the formula R
3 OH are used.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：在碱性化合物的存在下，通过使二硝基苯基甲基醚与特定的醇反应，以高产率获得二硝基苯醚，而不使用卤化物作为中间体。构成：将式I化合物（R 1和R 2中的一个为硝基，另一个为H，1-10C直链，支链或环状烃）与式R 3 OH（R 3 是2-10C直链，支链，环烃，具有一个苯基作为取代基的1-5C直链烃等）在碱性化合物（例如NaOH，KOH，吡啶等）存在下）在溶剂如苯，己烷等中，或在不存在下在60-180℃下反应，得到式II所示的所需化合物。用作催化剂的碱性化合物的量基于式I所示的化合物为1 / 2-1 / 10，并且使用等摩尔量的式I所示的化合物和由式R3OH表示的化合物。

12. 发明专利

JPS60166646A LIQUID CRYSTAL SUBSTITUTED BIPHENYL ESTER 失效
公开(公告)号：JPS60166646A
公开(公告)日：1985-08-29
申请号：JP2143984
申请日：1984-02-08
申请人： CHISSO CORP
发明人： SAITOU SHINICHI , INOUE HIROMICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07C67/00 , C07C69/75 , C07C69/757 , C07C69/773 , C07C69/78 , C07C69/82 , C07C69/90 , C07C69/92 , C07C69/96 , C07C253/00 , C07C255/46 , C07C255/55 , C09K19/12 , C09K19/20 , C09K19/30 , C09K19/46
摘要： NEW MATERIAL:A substituted biphenyl ester expressed by formula I [R1* is 4-18C alkyl having optical activity; formula II is formula III or IV; Z is R2 (R2 is alkyl or alkoxyl), R2CO or R2COO; X and Y are H, Br, Cl, F or CN (either one of X and Y is H)]. EXAMPLE:3'-Bromo-4'-(2-methylbutyloxy)-4-biphenylyl 4-octyloxybenzoate. USE:A chiral smectic liquid crystal composition utilized as an optical switcing element. PREPARATION:An optically active 4'-alkoxy-3'(or 3)-substituted-4-hydroxy biphenyl is esterified with a 4-substituted benzoyl halide to afford the aimed compound expressed by formula I .

13. 发明专利

JPS6054341A CARBONIC ACID ESTER OF LIQUID CRYSTAL 失效
公开(公告)号：JPS6054341A
公开(公告)日：1985-03-28
申请号：JP16276683
申请日：1983-09-05
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07C69/96 , C09K19/20 , C09K19/46 , G02F1/13
摘要： NEW MATERIAL:A carbonic acid ester shown by the formula I (R is C1-18 alkyl; l is 0 or 1; m is 1 when l=0, and m is 1 or 2 when l=1; X is COO or -O- when m=1, and X is single bond when m=2; * is optically active carbon. EXAMPLE:4-Nonyloxycarbonyloxybenzoic acid-4'-(S-2-methylbutyloxy-carbonyl) phenyl ester. USE:One component for chiral smectic liquid crystal composition. A chiral smectic liquid crystal substance containing an optically active group, useful as an optical switching element using a liquid crystal composition showing chiral smectic C phase, also usable as an inhibitor against formation of reverse domain. PREPARATION:A compound shown by the formula II is reacted with a compound shown by the formula III to give a compound shown by the formula IV, which is reacted with SOCl2, and finally with a phenol shown by the formula Vhaving optical activity to give a compound shown by the formula I .

14. 发明专利

JPS6051147A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS6051147A
公开(公告)日：1985-03-22
申请号：JP13814883
申请日：1983-07-28
申请人： CHISSO CORP
发明人： SAITOU SHINICHI , INOUE HIROMICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07C69/017 , C07C69/24 , C07C69/708 , C09K19/12 , C09K19/20
摘要： NEW MATERIAL:The chiral liquid crystal substance of formula (X is 1-18C alkyl or alkyloxy; l, m and n are 0 or 1; when n is 0, at least one of l and m is 0; * is optically active carbon atom) having optically active group. EXAMPLE:4-n-Octyloxy-4'-S-alpha-methylbutanoyloxybiphenyl. USE:Useful as a component of a liquid crystal composition. It has high clear point to raise the upper limit of the liquid crystal temperature range of the composition. It has cholesteric phase, and exhibits chiral smectic phase which is a ferroelectric liquid phase at about room temperature. It is also useful as an agent to prevent the formation of reverse domain. PREPARATION:The compound of formula can be produced by reacting 4-hydroxy-4'-substituted-biphenyl with an optically active carboxylic acid chloride or alkyl chloroformate in a basic solvent such as pyridine.

15. 发明专利

JPS59231043A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS59231043A
公开(公告)日：1984-12-25
申请号：JP10610083
申请日：1983-06-14
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07C69/017 , C07C69/773 , C07C69/92 , C09K19/12 , C09K19/20 , C09K19/46
摘要： NEW MATERIAL:The compound of formula I (l and m are 0 or 1; n is 1, 2 or 3; R is 1-18C straight or branched chain alkyl; the C atom labeled with * is optically active). EXAMPLE:[4-p-Octyloxbenzoyloxy-4'-(3-methyl-pentyl)biphenyl]. USE:A liquid crystal substance useful for the preparation of a chiral nematic liquid crystal composition useful as an agent for preventing the formation of reverse domain (stripe pattern) and a liquid crystal composition exhibiting chiral smectic phase and constituting an optical switching element. PREPARATION:The compound of formula I can be prepared by reacting the compound of formula I - formula IV with the compound of formula V in the presence of pyridine. The titled compound can raise the upper limit of the chiral smectic C temperature range of a liquid crystal composition when mixed with other compound, and can give a liquid crystal composition exhibiting chiral smectic C phase near room temperature.

16. 发明专利

JPS6122051A Liquid crystal ester and liquid crystal composition 失效
标题翻译：液晶和液晶组合物
公开(公告)号：JPS6122051A
公开(公告)日：1986-01-30
申请号：JP14269984
申请日：1984-07-10
申请人： Chisso Corp
发明人： INUKAI TAKASHI , FURUKAWA KENJI , TERAJIMA KENJI , SAITOU SHINICHI
IPC分类号： C09K19/20 , C07C69/773 , C07C69/90 , C07C69/94 , C07C69/96 , C09K19/46 , G02F1/13 , G09F9/35
摘要： NEW MATERIAL:The compound of formula I (R
1 is 1W18C alkyl; R
2 is 2W15C alkyl; X is single bond, O, CO or group of formula IV W formula VI; * represents optically active carbon atom).
EXAMPLE: 4'-Octyloxy-biphenylcarboxylic acid 4-(1-methylheptyl)phenyl ester.
USE: A liquid crystal substance. It exhibits smectic A phase at a lower temperature range than isotropic liquid, and exhibits chiral smectic phase (SC* phase) at further low temperature range. It has high spontaneous polarization in SC* phase, and is useful for manufacturing a display element having low working voltage and high response. It has excellent compatibility with other liquid crystal compounds.
PREPARATION: The compound of formula I can be prepared by reacting the 4'- substituted-4-biphenylcarboxylic acid halide of formula II with the optically active p-(1-methylalkyloxy)phenol of formula III in a basic solvent such as pyridine.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：新物质：式Ⅰ化合物（R1为1-18C烷基; R2为2-15C烷基; X为单键，O，CO或式Ⅳ基团，式Ⅵ; *为光学活性碳原子）。实施例：4'-辛氧基 - 联苯基羧酸4-（1-甲基庚基）苯基酯。用途：液晶物质。它在比各向同性液体更低的温度范围内显示出近晶A相，并在更低的温度范围内显示手性近晶相（SC *相）。它在SC *相中具有高自发极化，并且可用于制造具有低工作电压和高响应的显示元件。它与其他液晶化合物具有优异的相容性。制备：式Ⅰ化合物可以通过使式Ⅱ的4'-取代-4-联苯羧酸卤化物与式III的光学活性对 - （1-甲基烷氧基）苯酚在碱性溶剂如吡啶中反应来制备。

17. 发明专利

JPS6143A FERROELECTRIC LIQUID CRYSTAL AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS6143A
公开(公告)日：1986-01-06
申请号：JP11959084
申请日：1984-06-11
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , MIYAZAWA KAZUTOSHI , INUKAI TAKASHI , TERAJIMA KENJI
IPC分类号： C07C51/60 , C07C69/773 , C07C69/92 , C07C69/94 , C07C69/96 , C09K19/12 , C09K19/20 , C09K19/46 , G02F1/13
摘要： NEW MATERIAL:A compound of formula I [l, m are 1, 2; X is R , OR , COR , OCOR , OCOOR , COOR (R is 1-15C alkyl); R is 2-15C alkyl; * denotes optically active atoms]. EXAMPLE:p-Octyloxyphenyl 4'-(1-methyl-heptyloxy)-4-biphenylcarboxylate. USE:Chiral liquid crystal: it has high compatibility to other compounds to expand temperature range of the chiral smectic C phase, further lowers the driving voltage of a display element utilizing ferroelectric properties. PREPARATION:The reaction of optically active 1-methyl-1-alkanol of formula IIwith p-toluenesulfonyl chloride gives a compound of formula III. The product is allowed to react with a compound of formula IV, followed by hydrolysis to give a compound of formula VI. Then, the product is allowed to react with thionyl chloride and a phenol successively to give the compound of formula I.

18. 发明专利

JPS60226861A SUBSTITUTED PYRIDAZINE 失效
公开(公告)号：JPS60226861A
公开(公告)日：1985-11-12
申请号：JP6628884
申请日：1984-04-03
申请人： CHISSO CORP
发明人： SAITOU SHINICHI , INOUE HIROMICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07D237/14 , C09K19/34 , C09K19/44 , C09K19/46 , G02F1/13
摘要： NEW MATERIAL:An optically actie pyridazine compound of formula I (X is 1-18C alkyl or alkyloxy; R* is optically active group). EXAMPLE:S-3-(2-methylbutoxy)-6-(4'-nonylphenyl)-pyridazine. USE:A chiral smectic liquid crystal substance useful for the production of an optical switching element responding extremely rapidly compared with a TN- type display element, having memory effect, and capable of displaying the halftone easily, and an agent for preventing the formation of a reverse domain in a TN-type display element. PREPARATION:The compound of formula I can be prepared from the compounds of formula II and formula III via the compounds of formula IV - formula VII through 5 steps. The third step reaction is carried out by heating the compound of formula V together with bromine in acetic acid when X=alkyl, or heating together with selenium dioxide in dioxane when X=alkyloxy, to obtain the compound of formula VI.

19. 发明专利

JPS6013729A LIQUID CRYSTAL SUBSTANCE AND LIQUID CRYSTAL COMPOSITION 失效
公开(公告)号：JPS6013729A
公开(公告)日：1985-01-24
申请号：JP12176983
申请日：1983-07-05
申请人： CHISSO CORP
发明人： INOUE HIROMICHI , SAITOU SHINICHI , TERAJIMA KENJI , INUKAI TAKASHI , FURUKAWA KENJI
IPC分类号： C07C43/205 , C07C41/00 , C07C45/00 , C07C49/84 , C07C67/00 , C09K19/12
摘要： NEW MATERIAL:The compound of formula I (R is 1-18C alkyl; X is O, CO or CH2; n is 0-2; the C atom labeled with * is optically active). EXAMPLE:4-Octyloxy-4'-[(S)-3-methyl-pentanoyl]biphenyl. USE:A component of chiral nematic liquid crystal composition. It is a chiral liquid crystal substance having optical activity and applicable as an optical switching element. It is capable of responding extremely quickly, being driven easily by time-sharing driving, and exhibiting a half-tone easily by controlling the reversing time of the polarity, and is suitable for the graphic display. It can be used also as an agent for preventing the formation of reverse domain. PREPARATION:The compound of formula I wherein X is CO and n is 1 can be prepared by reacting the Grignard reagent of formula II derived from (+)-2- methylbutyl bromide and metallic Mg with 4-alkyloxy-4'-cyanobiphenyl of formula III.

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