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11. 发明授权

US4151336A Process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene 失效
标题翻译：用于生产马来酸酐和二异丁烯基本上等摩尔分子共聚物的方法
公开(公告)号：US4151336A
公开(公告)日：1979-04-24
申请号：US869043
申请日：1978-01-13
申请人： Gunter Sackmann , Gunter Kolb , Heinz Fischer , Friedhelm Muller
发明人： Gunter Sackmann , Gunter Kolb , Heinz Fischer , Friedhelm Muller
IPC分类号： C08F2/00 , C08F8/14 , C08F10/00 , C08F10/14 , C08F20/00 , C08F20/02 , C08F210/14 , C08F220/04 , C08F222/06 , D21H17/37 , D21H17/43 , C08F6/06 , C08F6/24
CPC分类号： C08F222/06 , C08F210/14 , D21H17/43
摘要： An improved process for the production of a substantially equimolecular copolymer of maleic acid anhydride and diisobutylene in which from 10 to 100 mole % of the anhydride groups are esterified with linear or branched aliphatic monoalcohols containing from 1 to 20 carbon atoms or with cycloaliphatic monoalcohols containing from 5 to 6 carbon atoms to form the corresponding semiesters, wherein shortly before or after the end of the solution or suspension copolymerization of maleic acid anhydride and diisobutylene a monomer corresponding to the general formula ##STR1## in which R=H, CH.sub.3, C.sub.2 H.sub.5, --OR.sub.2, --O--CO--CH.sub.3, ##STR2## --CH.sub.2 OH, --CH.sub.2 O--C--CH.sub.3, R.sub.1 =H , CH.sub.3 andR.sub.2 =a linear or branched alkyl group containing from 1 to 4 carbon atoms,Or mixtures of these monomers with one another are added to the polymerization mixture in quantities of from 1 to 12 mole %, based on the maleic acid anhydride used. The aqueous or aqueous-alcoholic alkali, amine or ammonium salt solutions of the semiesters of the copolymer are highly effective as anionic sizing agents for paper.
摘要翻译：用于生产马来酸酐和二异丁烯的基本上等分子的共聚物的改进方法，其中10至100摩尔％的酸酐基团被含有1至20个碳原子的直链或支链脂族一元醇或含有1至20个碳原子的脂环族一元醇酯化 5至6个碳原子以形成相应的半分子，其中在马来酸酐和二异丁烯的溶液或悬浮液共聚之前或之后不久，对应于通式为“IMAGE”的单体，其中R = H，CH 3，C 2 H 5， -OR 2，-O-CO-CH 3， -CH 2 OH，-CH 2 O-C-CH 3，R 1 = H，CH 3和R 2 =含有1至4个碳原子的直链或支链烷基，或这些单体的混合物另有一种添加到1至12％MOES％的聚合物混合物中，基于所用的非水性非离子表面活性剂。共聚物的半酯的水性或水性醇碱性，胺或铵盐溶液作为纸张的阴离子施胶剂是非常有效的。

12. 发明授权

US4113506A Emulsions of resinic acid isocyanates as sizing agents for paper 失效
标题翻译：作为纸张尺寸代理的树脂异氰酸酯的乳液
公开(公告)号：US4113506A
公开(公告)日：1978-09-12
申请号：US749455
申请日：1976-12-10
申请人： Gunter Sackmann , Udo-Winfried Hendricks , Hans-Ludwig Honig , Gunter Kolb , Friedhelm Muller
发明人： Gunter Sackmann , Udo-Winfried Hendricks , Hans-Ludwig Honig , Gunter Kolb , Friedhelm Muller
IPC分类号： D21H17/21 , C08G18/71 , C08J3/05 , D21H17/08 , D21H17/62 , C08J3/02
CPC分类号： C08J3/05 , C08G18/71 , D21H17/08 , D21H17/62 , C08J2393/00
摘要： Stable aqueous emulsions comprising a resinic acid isocyanate, a non-ionic and/or anionic emulsifier and an optionally chlorinated hydrocarbon are used as sizing agents for paper or paper-like materials.

13. 发明授权

US5728774A Process for the continuous production of superabsorbent polymers from pan emulsions 失效
标题翻译：从泛乳液连续生产超吸收性聚合物的方法
公开(公告)号：US5728774A
公开(公告)日：1998-03-17
申请号：US771575
申请日：1996-12-20
申请人： Gunter Sackmann , Sergej Schapowalow , Martin Ullrich , Helmut Brod
发明人： Gunter Sackmann , Sergej Schapowalow , Martin Ullrich , Helmut Brod
IPC分类号： C08F8/12 , C08F20/00 , C08F20/44 , H01B3/44 , C08F220/44 , C08F220/56
CPC分类号： H01B3/448 , C08F8/44 , C08F2800/20 , C08F2810/20
摘要： A process for the continuous production of superabsorbent polymers, characterised in that aqueous emulsions of uncross-linked and cross-linked polyacrylonitrile homopolymers and/or copolymers, the polyacrylonitrile concentrations in the reaction mixture being from 10 to 45 w.t. %, are hydrolysed with aqueous alkali hydroxide solutions at 50.degree. to 100.degree. C. in a continuously operating reactor suitable for carrying out highly viscous reactions, and that from the highly viscous gels formed the products in the form of superabsorbent powders are continuously precipitated by means of continuous precipitation using low-boiling monoalcohols, and the use thereof in sanitary articles, as water-storing materials in agriculture or for sheathing electrical cables.
摘要翻译：用于连续生产超吸收性聚合物的方法，其特征在于，未交联和交联的聚丙烯腈均聚物和/或共聚物的水乳液，反应混合物中的聚丙烯腈浓度为10至45w.t. ％，在适用于进行高粘度反应的连续操作的反应器中，在50至100℃下用碱金属氢氧化物水溶液水解，并且由高粘度凝胶形成的超吸收性粉末形式的产物通过使用低沸点一元醇连续沉淀的方法，以及在卫生制品中的用途，作为农业中的储水材料或护套电缆。

14. 发明授权

US5288787A Emulsion polymers 失效
标题翻译：乳液聚合物
公开(公告)号：US5288787A
公开(公告)日：1994-02-22
申请号：US714317
申请日：1991-06-10
申请人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
IPC分类号： C08F2/26 , C08F220/12 , D21H17/34 , C08K3/20
CPC分类号： D21H17/34 , C08F2/26 , C08F220/12
摘要： Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.
摘要翻译：通过乳化由A）5-95重量％的至少一种由丙烯腈，甲基丙烯腈，任选取代的苯乙烯，乙烯基羧酸酯组成的系列中的至少一种单体的混合物得到的乳液聚合物和B）5-95重量％的丙烯酸和/ 或甲基丙烯酸酯，组分A）+ B的总和）为100重量％，在阴离子改性聚氨酯的水溶液或分散体存在下，优选含有-SO 3 Me +和/或-COO-Me +基团（Me + =阳离子，优选H +，Na +，K +，Li +，NH 4 +或取代的铵离子），并将所得乳液进行由自由基引发的聚合。所生产的乳液聚合物优选用作纸的表面施胶剂。

15. 发明授权

US4771097A Tub sizes for paper 失效
标题翻译：纸的尺寸
公开(公告)号：US4771097A
公开(公告)日：1988-09-13
申请号：US26340
申请日：1987-03-16
申请人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
发明人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
IPC分类号： C08F8/44 , C08F8/14 , C08L35/00 , D21H17/43 , D21H19/20 , D21H21/16 , C08L35/02
CPC分类号： C08F8/14 , D21H17/43 , D21H21/16
摘要： Tub sizes for paper, containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## --CH.sub.2 OH or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl,the anhydride groups of the copolymers being bis-esterified to the extent of about 3 to about 20 mol %, relative to the anhydride groups, with aliphatic monoalcohols having 1 to 12 C atoms.
摘要翻译：用于含有水性或含水醇碱金属的纸的桶尺寸，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， C 2 H 5，-OR 2，-OCOCH 3，-CH 2 OH或-CH 2 -O-COCH 3，R 1表示H或-CH 3，R 2表示烷基，所述共聚物的酸酐基团被双酯化至约3至约相对于酸酐基团为20摩尔％，具有1至12个碳原子的脂肪族一元醇。

16. 发明授权

US4287299A Process for the production of matting layers 失效
标题翻译：生产消光层的方法
公开(公告)号：US4287299A
公开(公告)日：1981-09-01
申请号：US149496
申请日：1980-05-13
申请人： Wolfgang Himmelmann , Rolf Bruck , Wolfgang Sauerteig , Peter Kruck , Gunter Kolb , Gunter Sackmann
发明人： Wolfgang Himmelmann , Rolf Bruck , Wolfgang Sauerteig , Peter Kruck , Gunter Kolb , Gunter Sackmann
IPC分类号： G03C1/32 , G03C1/04 , G03C1/95 , G03C1/76
CPC分类号： G03C1/95 , Y10S430/151
摘要： For the production of matted outer layers of photographic silver halide recording materials particles of a copolymer of maleic acid anhydride and a C.sub.2 -C.sub.8 monoolefin are dispersed in an aqueous solution of a hydrophilic colloid and the dispersion thus formed is applied to one or both surfaces of the photographic recording material and the layer is dried.
摘要翻译：对于摄影卤化银记录材料的无光泽外层的生产，将马来酸酐和C 2 -C 8单烯烃的共聚物颗粒分散在亲水胶体的水溶液中，并将如此形成的分散体施加到将照相记录材料和该层干燥。

17. 发明授权

US6156848A Pre-formed super absorbers with high swelling capacity 失效
标题翻译：具有高溶胀能力的预成型超吸收体
公开(公告)号：US6156848A
公开(公告)日：2000-12-05
申请号：US964069
申请日：1997-11-04
申请人： Gunter Sackmann , Sergej Schapowalow , Siegfried Korte , Rolf-Volker Meyer
发明人： Gunter Sackmann , Sergej Schapowalow , Siegfried Korte , Rolf-Volker Meyer
IPC分类号： A61L15/00 , A61L15/60 , B01J20/26 , C08F6/14 , C08F8/12 , C08F20/04 , C08F20/44 , C08F20/56 , C09K17/16 , F16F1/36 , C08F120/44
CPC分类号： F16F1/3605 , A61L15/60 , C08F8/44 , C09K17/16 , C08F2800/20 , C08F2810/20
摘要： Super-absorbent polymer in the form of pre-formed spherical particles obtainable by alkaline hydrolysis of aqueous emulsions of crosslinked and/or un-crosslinked homopolymers and/or copolymers of acrylonitrile in water/alcohol mixtures and the use of the polymer in hygiene products, as a water-storing material in agriculture and for the sheathing of electrical cables.
摘要翻译：可通过碱水解丙烯腈在水/醇混合物中的交联和/或未交联的均聚物和/或共聚物的水性乳液获得的预形成的球形颗粒形式的超吸收性聚合物和聚合物在卫生产品中的用途，作为农业中的储水材料和电缆护套。

18. 发明授权

US5258466A Paper size 失效
标题翻译：纸张尺寸
公开(公告)号：US5258466A
公开(公告)日：1993-11-02
申请号：US713923
申请日：1991-06-12
申请人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
IPC分类号： C08F2/24 , C08F2/26 , C08F267/10 , D21H17/42 , C08F20/10 , C08F22/06
CPC分类号： D21H17/42 , C08F267/10
摘要： Emulsion polymers which are prepared by free-radical polymerisation of monomers in the presence ofa) polymers of the formulae ##STR1## wherein the radicals have the meanings given in the description, and b) low-molecular anionic emulsifiers,are outstandingly suitable as surface sizes for paper. They are distinguished by a low tendency to foaming and by a wide application spectrum.
摘要翻译：通过在a）式（I）的聚合物（II）的存在下，通过单体的自由基聚合制备的乳液聚合物，其中基团具有在说明书中给出的含义，和b）分子阴离子乳化剂，非常适合作为纸张的表面尺寸。它们的特征在于低发泡趋势和广泛的应用范围。

19. 发明授权

US5013794A Polymers of diisobutylene-sulfonate alkane maleic acid derivatives 失效
标题翻译：二异丁烯磺酸烷烃马来酸衍生物的聚合物
公开(公告)号：US5013794A
公开(公告)日：1991-05-07
申请号：US475623
申请日：1990-02-06
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F267/10 , D21H17/34 , D21H21/16
CPC分类号： C08F267/10 , D21H17/34 , D21H21/16
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

20. 发明授权

US4613337A Process for dyeing cellulose-containing fibre materials by the cold pad-batch or pad-steam method: maleic anhydride-styrene copolymer 失效
标题翻译：通过冷垫批次或蒸汽 - 蒸汽法染色含纤维素纤维材料的方法：马来酸酐 - 苯乙烯共聚物
公开(公告)号：US4613337A
公开(公告)日：1986-09-23
申请号：US730227
申请日：1985-05-03
申请人： Udo W. Hendricks , Klaus Lesche , Gunter Sackmann , Wolf-Dieter Schroer
发明人： Udo W. Hendricks , Klaus Lesche , Gunter Sackmann , Wolf-Dieter Schroer
IPC分类号： D06P1/52 , D06P3/60 , D06P3/66
CPC分类号： D06P1/525 , D06P3/66 , Y10S8/918
摘要： The dyeing of cellulose fibres or fibre blends containing cellulose fibres with reactive dyes by a cold pad-batch or pad-steam process is effected with aqueous padding liquors which contain water-soluble reaction products of copolymers of maleic anhydride and ethylene, propylene, isobutylene, diisobutylene or styrene with ammonia or amines of the formula ##STR1## in which R.sup.1 and R.sup.2 stand for hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -hydroxyalkyl.
摘要翻译：含有纤维素纤维的纤维素纤维或含有活性染料的纤维混合物通过冷垫批次或蒸汽 - 蒸汽法进行染色是用含有马来酸酐与乙烯，丙烯，异丁烯等的共聚物的水溶性反应产物的含水填料液进行的，二异丁烯或苯乙烯与氨或式Ⅰ'的胺，其中R1和R2代表氢，C1-C4-烷基或C1-C4-羟基烷基。

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