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11. 发明授权

US06239225B1 Process for the manufacture of impact resistant modified polymers 有权
标题翻译：用于制造抗冲击改性聚合物的方法
公开(公告)号：US06239225B1
公开(公告)日：2001-05-29
申请号：US09350228
申请日：1999-07-08
申请人： Gisbert Michels , Bernd Klinksiek , Otto Schmid , Ralph Ostarek , Richard Weider , Raymond D. Burk , Joong-In Kim
发明人： Gisbert Michels , Bernd Klinksiek , Otto Schmid , Ralph Ostarek , Richard Weider , Raymond D. Burk , Joong-In Kim
IPC分类号： C08F2502
CPC分类号： C08F279/02 , C08F279/04 , C08F212/00 , C08F2/02
摘要： A continuous process for the manufacture of impact resistant polymers is disclosed. The process comprise polymerization of a reaction mixture containing vinylaromatic monomers in the presence of soluble rubber and entails shearing at least some of said mixture at a rate of more than 30000 1/s using a device having no rotating parts. The resulting product is characterized in its low gloss and improved impact properties.
摘要翻译：公开了制造抗冲击聚合物的连续方法。该方法包括在可溶性橡胶存在下聚合含有乙烯基芳族单体的反应混合物，并且使用不具有旋转部分的装置，以至少一些所述混合物以大于30000l / s的速率剪切。所得产品的特征在于其低光泽和改善的冲击性能。

12. 发明授权

US5872180A Substrates which have been provided with an oil-, water- and soil-repellant treatment and fluorine-containing compositions for this purpose 失效
标题翻译：已经提供了防水，防水和疏水处理的基材和用于此目的的含氟组合物
公开(公告)号：US5872180A
公开(公告)日：1999-02-16
申请号：US850023
申请日：1997-05-01
申请人： Gisbert Michels , Hans-Albert Ehlert , Uwe Zweering
发明人： Gisbert Michels , Hans-Albert Ehlert , Uwe Zweering
IPC分类号： B05D5/00 , B05D7/24 , C08F18/02 , C08F212/00 , C08F212/08 , C08F218/02 , C08F218/08 , C08F218/10 , C08F220/24 , C08J7/04 , C08L33/04 , C08L33/06 , C08L33/16 , C08L33/18 , C08L33/20 , C09D125/00 , C09D125/08 , C09D131/02 , C09D131/04 , C09K3/00 , C09K3/18 , C14C9/00 , D06M13/02 , D06M13/224 , D06M15/233 , D06M15/263 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/31 , D06M15/333 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34 , D21H19/20 , C08L27/12
CPC分类号： D06M15/333 , C08L33/16 , D06M15/233 , D06M15/263 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/31 , C08L33/06 , D06M2200/11 , D06M2200/12 , Y10T442/2238 , Y10T442/227 , Y10T442/2287
摘要： Fluorine-containing compositions for treating substrates to render them oil-, water- and soll-repellant, comprising a fluorine-containing acrylic copolymer and a fluorine-free poly(meth)acrylate.
摘要翻译：含氟的组合物，用于处理基材以使其具有油，水和溶胶排斥性，包含含氟丙烯酸共聚物和无氟聚（甲基）丙烯酸酯。

13. 发明授权

US06573358B2 Process for the preparation of superabsorbent polymers from polyacrylonitrile precipitation polymers 有权
标题翻译：从聚丙烯腈沉淀聚合物制备超吸收聚合物的方法
公开(公告)号：US06573358B2
公开(公告)日：2003-06-03
申请号：US09835665
申请日：2001-04-16
申请人： Gisbert Michels , Günter Sackmann , Klaus Struss
发明人： Gisbert Michels , Günter Sackmann , Klaus Struss
IPC分类号： C08F602
CPC分类号： C08F8/12 , C08F2810/20 , C08F220/44 , C08F216/125 , C08F8/44
摘要： A process for the preparation of superabsorbers is disclosed. The process entails subjecting a polyacrylonitrile precipitation polymer alkaline hydrolysis to obtain a hydrolysis product. The hydrolysate that may optionally be neutralized is dried and ground and optionally modified by crosslinking of its surface. The inventive superabsorber is suitable for the preparation of nappies, incontinence articles, water-storage materials and electric cable coverings.
摘要翻译：公开了制备超吸收剂的方法。该方法需要使聚丙烯腈沉淀聚合物碱性水解以获得水解产物。可任选中和的水解产物被干燥并研磨，并通过其表面交联任选地改性。本发明的超吸收剂适用于制备尿布，失禁制品，储水材料和电缆覆盖物。

14. 发明授权

US06482897B1 Process for producing ABS moulding compositions having a high rubber content 失效
标题翻译：具有高橡胶含量的ABS模塑组合物的制造方法
公开(公告)号：US06482897B1
公开(公告)日：2002-11-19
申请号：US08907202
申请日：1997-08-06
申请人： Richard Weider , Gisbert Michels , Frank Wingler
发明人： Richard Weider , Gisbert Michels , Frank Wingler
IPC分类号： C08F27904
CPC分类号： C08F279/04
摘要： A process for producing impact-resistant moulding compositions, which is characterised in that a monomer mixture comprising 90 to 20 parts by weight of an aromatic monoalkenyl compound, 10 to 50 parts by weight of an ethylenically unsaturated nitrile, 0 to 30 parts by weight of other copolymerisable compounds is polymerised by a radical mechanism in the presence of 15 to 50 parts by weight, per 100 parts by weight of monomers, of a soluble, gel-free butadiene polymer, and in the presence of 50 to 200 parts by weight, per 100 parts by weight of monomers, of a solvent, wherein the solvent is selected from the group comprising an aliphatic (C1-C8) or cycloaliphatic alcohol, ketone, ether, ester, nitrile (A) or mixtures thereof or a mixture of (A) with an aliphatic (C4-C10), cycloaliphatic or aromatic hydrocarbon (B) in an A:B weight ratio of 100:0 to 30:70, and the polymerisation is conducted as far as a polymer content of the total mixture of 30 to 70% by weight, with thorough mixing and optionally with the subsequent addition of a regulator and initiator, so that the isolated thermoplastic moulding composition contains 20 to 40% by weight of butadiene polymer.
摘要翻译：一种耐冲击成型组合物的制造方法，其特征在于，含有90〜20重量份芳香族单链烯基化合物，10〜50重量份烯属不饱和腈，0〜30重量份其它可共聚合的化合物通过自由基机理在每100重量份单体，每100重量份单体，可溶性，无凝胶的丁二烯聚合物存在下共聚合15至50重量份，并且在50至200重量份的存在下，每100份单体重量的溶剂，其中溶剂选自脂族（C1-C8）或脂环族醇，酮，醚，酯，腈（A）或其混合物或（A）与脂族（C 4 -C 10），脂环族或芳族烃（B），其A:B重量比为100:0至30:70，并进行聚合，只要总混合物的聚合物含量为30-70％重量，充分混合和选择随后加入调节剂和引发剂，使得分离的热塑性模塑组合物含有20至40重量％的丁二烯聚合物。

15. 发明授权

US5753569A Substrates which have been provided with an oil-, water- and soil-repellant treatment and fluorine-containing compositions for this purpose 失效
标题翻译：已经提供了防水，防水和疏水处理的基材和用于此目的的含氟组合物
公开(公告)号：US5753569A
公开(公告)日：1998-05-19
申请号：US560417
申请日：1995-11-17
申请人： Gisbert Michels , Hans-Albert Ehlert , Uwe Zweering
发明人： Gisbert Michels , Hans-Albert Ehlert , Uwe Zweering
IPC分类号： B05D5/00 , B05D7/24 , C08F18/02 , C08F212/00 , C08F212/08 , C08F218/02 , C08F218/08 , C08F218/10 , C08F220/24 , C08J7/04 , C08L33/04 , C08L33/06 , C08L33/16 , C08L33/18 , C08L33/20 , C09D125/00 , C09D125/08 , C09D131/02 , C09D131/04 , C09K3/00 , C09K3/18 , C14C9/00 , D06M13/02 , D06M13/224 , D06M15/233 , D06M15/263 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/31 , D06M15/333 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34 , D21H19/20 , B03D3/00
CPC分类号： D06M15/333 , C08L33/16 , D06M15/233 , D06M15/263 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/31 , C08L33/06 , D06M2200/11 , D06M2200/12 , Y10T442/2238 , Y10T442/227 , Y10T442/2287
摘要： Substrates which have been provided with an oil-, water- and soil-repellant treatment from the group consisting of naturally occurring and synthetic textiles and their mixtures, leather, mineral substances, thermoplastic and thermosetting polymers and paper, comprise fluorine-containing compositions which comprise two components A and B. Component A is a fluorine-containing acrylic copolymer with the following comonomers: a) (meth)acrylates containing perfluoroalkyl groups C.sub.n F.sub.2n+1 --X--O--CO--CR.sup.1 .dbd.CH.sub.2 (I), b) monomers from the group consisting of styrene, acrylonitrile, vinyl acetate, vinyl propionate and monomers, CH.sub.2 .dbd.CR.sup.4 --CO----OR.sup.5 (II), c) monomers ##STR1## and d) monomers CH.sub.2 .dbd.CR.sup.11 COO--CH.sub.2 CH.sub.2 N(R.sup.9, R.sup.10) (IVa) or in quaternized form �CH.sub.2 .dbd.CR.sup.11 --COO--CH.sub.2 CH.sub.2 N(R.sup.9 R.sup.10 R.sup.12)!.sup..sym. Y.sup..crclbar. (IVb) or in N-oxidized form ##STR2## or of the formula CH.sub.2 .dbd.CR.sup.13 --COO.sup..sym. Z.sup..crclbar. (V) Component B is a fluorine-free poly(meth)acrylate of comonomers CH.sub.2 .dbd.CHR.sup.14 --COO--R.sup.15 (VI) 0 to 20% by weight of comonomer (VI) can be replaced by comonomers from the group consisting of vinyl acetate, styrene, acrylonitrile, hydroxyethyl (meth)- acrylate, hydroxypropyl (meth)acrylate, glycidyl (meth)acrylate, (meth)acrylamide, N-methylol-(meth)acrylamide and N-methoxymethylol(meth)acrylamide. The weight ratio of A to B is 1:25 to 10:1. Substituents and indices are mentioned in the description.
摘要翻译：已经提供了由天然和合成纺织品及其混合物，皮革，矿物质，热塑性和热固性聚合物和纸组成的组中的防水，防水和疏水处理的基材包括含氟组合物，其包含组分A是含有以下共聚单体的含氟丙烯酸共聚物：a）含有全氟烷基CnF2n + 1-XO-CO-CR1 = CH2（I）的（甲基）丙烯酸酯，b）来自该组的单体由CH 2 = CR 4 -CO -OR 5（II），c）单体2 CH 2 N（R 9，R 10）（Ⅳa）或季铵化形式[CH 2 = CR 11 -COO-CH 2 CH 2 N（（+）Y（ - ）（IVb）或N-氧化形式（IVc）或式CH2 = CR13-COO（+）Z（ - ）（Ⅴ）组分B是氟 - 共聚单体CH2 = CHR14-COO-R15（Ⅵ）的游离聚（甲基）丙烯酸酯可以由0〜20重量％的共聚单体（Ⅵ）代替由v组成的组的共聚单体苯乙烯，丙烯腈，（甲基）丙烯酸羟乙酯，（甲基）丙烯酸羟丙酯，（甲基）丙烯酸缩水甘油酯，（甲基）丙烯酰胺，N-羟甲基 - （甲基）丙烯酰胺和N-甲氧基羟甲基（甲基）丙烯酰胺。 A与B的重量比为1:25至10:1。取代基和指数在说明书中提及。

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