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11. 发明授权

US06185963B1 Fiber strand package having a size with low solvent content 失效
标题翻译：具有低溶剂含量的纤维束包装
公开(公告)号：US06185963B1
公开(公告)日：2001-02-13
申请号：US08933038
申请日：1997-09-18
申请人： Patrick Moireau , Timothy Johnson
发明人： Patrick Moireau , Timothy Johnson
IPC分类号： C03B4002
CPC分类号： C03C25/26 , Y10T428/2936 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： The invention relates to a process for manufacturing continuous a glass fiber strand. The process consists in depositing on the glass filaments which are in the process of being drawn a sizing composition consisting of a solution of which the solvent content is less than 5 wt %, the solution comprising a mixture of constituents which can be polymerized and/or crosslinked by heat treatment, at least 60 wt % of the constituents being constituents of which the molecular weight (Mw) is less than 750, less than 10 weight % being film-forming agents and 0 to 25 weight % being coupling agents, lubricants, stabilizers and initiators and/or catalysts, it being possible if necessary for the agent to be polymerized and/or crosslinked by heat treatment, in winding the strand or strands, formed by collection of the filaments, on a rotating support so as to form a wound package consisting of turns of strand coated with a non-polymerized sizing composition. The strands are intended to reinforce thermoplastic or thermosetting organic substrates or substances of mineral origin.
摘要翻译：本发明涉及连续玻璃纤维束的制造方法。该方法包括沉积在正在拉伸的溶液含量小于5重量％的溶液组成的施胶组合物的过程中的玻璃纤维，该溶液包含可以聚合的成分的混合物和/或通过热处理交联，至少60重量％的组分是其分子量（Mw）小于750，小于10重量％的成膜剂和0至25重量％的偶联剂，润滑剂，稳定剂和引发剂和/或催化剂，如果需要，通过热处理可将聚合和/或交联的试剂在通过收集长丝形成的丝束或绞线卷绕在旋转的载体上以形成缠绕包装，其由涂覆有非聚合施胶组合物的线股匝组成。股线旨在加强热塑性或热固性有机基底或矿物来源的物质。

12. 发明申请

US20090092832A1 GLASS FIBRES COATED WITH SIZE CONTAINING NANOPARTICLES 审中-公开
标题翻译：玻璃纤维与包含纳米颗粒的尺寸
公开(公告)号：US20090092832A1
公开(公告)日：2009-04-09
申请号：US12158470
申请日：2006-12-18
申请人： Patrick Moireau
发明人： Patrick Moireau
IPC分类号： B32B17/02 , C08K7/16
CPC分类号： C08J5/08 , C03C25/1025 , C03C25/26 , C03C25/47 , Y10T428/2933 , Y10T428/2938
摘要： The invention relates to glass strands coated with a sizing composition which comprises (in % by weight): 25 to 90% of at least one film-forming agent; 3 to 25% of at least one coupling agent; and 2 to 18% of nanoparticles. The invention also relates to a sizing composition that can coat said strands, to the method of obtaining it and to the composites incorporating such strands.The glass strands of the invention have a high wet aging resistance.
摘要翻译：本发明涉及涂覆有施胶组合物的玻璃纤维束，其包含（重量％）：25至90％的至少一种成膜剂; 3至25％的至少一种偶联剂; 和2至18％的纳米颗粒。本发明还涉及一种能够涂覆所述丝线的上胶组合物，其获得方法和包含这种丝束的复合材料。本发明的玻璃丝具有高的耐湿老化性。

13. 发明申请

US20090017301A1 GLASS FIBRES AND GLASS FIBRE STRUCTURES PROVIDED WITH A COATING CONTAINING NANOPARTICLES 审中-公开
标题翻译：玻璃纤维和玻璃纤维结构提供包含纳米粒子的涂料
公开(公告)号：US20090017301A1
公开(公告)日：2009-01-15
申请号：US12158707
申请日：2006-12-22
申请人： Patrick Moireau
发明人： Patrick Moireau
IPC分类号： B32B17/06 , C08K3/34 , C08K3/10 , C08J3/205
CPC分类号： C03C25/1025 , C03C25/26 , C03C25/47 , C08J7/08 , Y10T428/2927
摘要： The invention relates to reinforcing glass strands and the structures of such glass strands having an improved wet aging resistance and equipped with a coating composition, obtained from a solution and/or a suspension and/or an emulsion, that comprises (in % by weight of solids): 60 to 95% of at least one polymer 2 to 18% of nanoparticles. It also relates to a coating composition suitable for coating said strands and strand structures, its production method and the composites incorporating the strands and strand structures.
摘要翻译：本发明涉及增强玻璃纤维束和这种玻璃纤维束的结构，其具有改善的耐湿老化性并且配备有由溶液和/或悬浮液和/或乳液获得的涂料组合物，其包含（以重量％固体）：60至95％的至少一种聚合物2至18％的纳米颗粒。它还涉及适用于涂覆所述股线和股线结构的涂料组合物，其制备方法和掺入链和链结构的复合材料。

14. 发明授权

US06514612B1 Glass fibre coating composition, method using said composition and resulting product 失效
标题翻译：玻璃纤维涂料组合物，使用所述组合物和所得产物的方法
公开(公告)号：US06514612B1
公开(公告)日：2003-02-04
申请号：US09581910
申请日：2000-09-12
申请人： Patrick Moireau , Marc Roubin
发明人： Patrick Moireau , Marc Roubin
IPC分类号： D02G300
CPC分类号： C03C25/26 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： The present invention relates to a sizing composition for a glass yarn, consisting of a solution whose solvent content is less than 5% by weight, this solution comprising at least 60% by weight of polymerizable components, at least 60% by weight of these polymerizable components being components with a molecular mass of less than 750 and these polymerizable components comprising at least one mixture capable of polymerizing: of component(s) containing at least one reactive acrylic function and/or at least one reactive methacrylic function, and of component(s) containing at least one reactive primary amine function and/or at least one reactive secondary amine function, at least 20% of the polymerizable components containing at least two reactive functions chosen from acrylic, methacrylic, primary amine and secondary amine functions.
摘要翻译：本发明涉及一种用于玻璃纱线的上胶组合物，其由溶剂含量小于5重量％的溶液组成，该溶液包含至少60重量％的可聚合组分，至少60重量％的这些可聚合的组分是分子量小于750的组分，并且这些可聚合组分包含至少一种能够聚合的混合物：包含至少一种反应性丙烯酸官能团和/或至少一种反应性甲基丙烯酸官能团的组分，和组分）包含至少一种反应性伯胺官能团和/或至少一种反应性仲胺官能团，至少20％的可聚合组分含有至少两种选自丙烯酸，甲基丙烯酸，伯胺和仲胺官能团的反应性官能团。

15. 发明授权

US5961684A Sizing composition for glass strands, process using this composition and resulting products 失效
标题翻译：用于玻璃丝的上胶组合物，使用该组合物和所得产品的方法
公开(公告)号：US5961684A
公开(公告)日：1999-10-05
申请号：US894809
申请日：1997-09-04
申请人： Patrick Moireau , Christelle Pousse
发明人： Patrick Moireau , Christelle Pousse
IPC分类号： C03C25/10 , C03C25/26 , C03C25/36 , C04B14/42 , C08J5/08 , C03C25/02
CPC分类号： C03C25/36 , C03C25/26 , C08J5/08 , Y10T428/2938 , Y10T428/2962
摘要： A glass yarn sizing composition consisting of a solution having a viscosity of at most 400 cP and including less than 5 wt. % of solvent and at least one basic heat-polymerisable system which includes at least 60 wt. % of components having a molecular weight of less than 750, and at least 60 wt. % of a mixture of one or more components having at least one epoxy reactive function, and one or more components having at least one (preferably primary or secondary) amine reactive function, wherein the amount of components having at least one amine reactive function represents at least 6 wt. % of the composition. A method using said composition, and the resulting yarns coated with said composition, are also disclosed.
摘要翻译： PCT No.PCT / FR96 / 02084第 371日期：1997年9月4日 102（e）1997年9月4日PCT PCT 1996年12月26日PCT公布。公开号WO97 / 25288 PCT 日期1997年7月17日一种玻璃纱线上浆组合物，其由粘度至多为400cP且小于5wt。％的溶剂和至少一种碱性可热聚合体系，其包括至少60wt。％的分子量小于750的组分和至少60重量％％的具有至少一个环氧反应性官能团的一种或多种组分的混合物，以及一种或多种具有至少一种（优选伯或仲）胺反应性官能团的组分，其中具有至少一个胺反应性官能团的组分的量代表至少6wt。％的组成。还公开了使用所述组合物的方法，以及涂覆有所述组合物的所得纱线。

16. 发明授权

US5882792A Sizing composition for glass threads, process using this composition and resulting products 失效
标题翻译：用于玻璃丝的上胶组合物，使用该组合物和所得产品的方法
公开(公告)号：US5882792A
公开(公告)日：1999-03-16
申请号：US687437
申请日：1996-10-10
申请人： Patrick Moireau
发明人： Patrick Moireau
IPC分类号： C03C25/10 , C03C25/28 , C03C25/36 , C08G59/00 , C08G59/18 , C08G59/68 , D01D5/096 , D06M10/10 , D06M15/55 , D02G3/00 , C08F2/46 , C08F6/00
CPC分类号： C03C25/36 , C03C25/285 , Y10T428/2933 , Y10T428/2938 , Y10T428/296 , Y10T428/2962 , Y10T428/31511 , Y10T428/31645
摘要： The present invention relates to a sizing composition for glass threads which comprises a solution of a viscosity of less than or equal to 400 cP containing less than 5% by weight of solvent and containing at least one base system which can be polymerized under the action of ultraviolet radiation or an electron beam, the said base system comprising at least one component that has a molecular mass of less than 750 and that has at least one reactive epoxy group and comprising at least 60% by weight of one or more components that have a molecular mass of less than 750 and that have at least one reactive group selected from the following groups: epoxy, hydroxy, vinyl ether, acrylic and methacrylic. The invention relates also to a process using this composition and to the threads coated with the said composition.
摘要翻译： PCT No.PCT / FR95 / 01640 Sec。 371日期：1996年10月10日 102（e）日期1996年10月10日PCT 1995年12月11日PCT PCT。公开号WO96 / 18683 日本1996年6月20日本发明涉及一种玻璃丝的上胶组合物，其包含粘度小于或等于400cP的溶液，其含有少于5重量％的溶剂并含有至少一个基体系，其可以是在紫外线辐射或电子束的作用下聚合，所述基体系包含至少一种分子量小于750的组分，并且具有至少一个反应性环氧基并且包含至少60重量％的一个或多个分子量小于750且具有至少一个选自以下基团的反应性基团的更多组分：环氧基，羟基，乙烯基醚，丙烯酸和甲基丙烯酸。本发明还涉及使用该组合物和涂覆有所述组合物的丝线的方法。

17. 发明授权

US5486416A Continuous thread manufactured by mechanical drawing 失效
标题翻译：连续线由机械制图制造
公开(公告)号：US5486416A
公开(公告)日：1996-01-23
申请号：US248147
申请日：1994-05-24
申请人： Timothy Johnson , Patrick Moireau
发明人： Timothy Johnson , Patrick Moireau
IPC分类号： D01D10/00 , B29C35/08 , B29C35/10 , B29C70/20 , C03B37/12 , C03C25/12 , D01D5/098 , D01F11/00 , D02G3/18 , D02J1/00 , D02J13/00 , D06M10/00 , D06M13/02 , D06M13/152 , D06M13/224 , D06M13/51 , D06M13/513 , D06M15/70 , D06M101/00 , D06M101/16 , D06M101/18 , D06M101/20 , D06M101/22 , D06M101/30 , D06M101/32 , D06M101/34 , D06M101/40 , D02G3/00
CPC分类号： C03C25/12 , B29C35/10 , B29C70/20 , B29C2035/0827 , B29K2309/08 , Y10T428/29 , Y10T428/2913 , Y10T428/2933
摘要： In the manufacture of a continuous thread coated with a mixture which reacts to ultraviolet radiation, a large number of continuous filaments are formed by mechanically drawing a large number of molten thermoplastic material streams flowing from openings in at least one device. A mixture in the liquid state which can react under the effect of ultraviolet radiation is deposited onto the surface of at least some of the filaments before they are combined to form at least one thread. The thread is wound into the form of a winding on a rotating support, and exposed to ultraviolet radiation during the winding operation.
摘要翻译：在制造涂覆有与紫外线辐射反应的混合物的连续螺纹时，通过机械拉伸从至少一个装置中的开口流出的大量熔融热塑性材料流而形成大量连续长丝。在紫外线辐射的作用下能够反应的液体状态的混合物在组合之前被沉积到至少一些长丝的表面上以形成至少一个线。线缠绕在旋转支架上的绕组形式，并且在卷绕操作期间暴露于紫外线辐射。

18. 发明授权

US08999505B2 Sizing composition in the form of a physical gel for glass strands, glass strands obtained and composites comprising the said strands 有权
标题翻译：用于玻璃丝的物理凝胶形式的胶料组合物，所得的玻璃丝和包含所述丝束的复合材料
公开(公告)号：US08999505B2
公开(公告)日：2015-04-07
申请号：US12676612
申请日：2008-09-04
申请人： Dominique Serughetti , Jean-Baptiste Denis , Patrick Moireau
发明人： Dominique Serughetti , Jean-Baptiste Denis , Patrick Moireau
IPC分类号： D02G3/00 , B32B27/04 , C03C25/26
CPC分类号： C03C25/26 , Y10T428/249944 , Y10T428/249948 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： The present invention relates to a sizing composition in the form of a physical gel for glass strands which contains 0.1 to 5% by weight of at least one texturing agent chosen from xanthans, guars and succinoglycans, 2 to 8% by weight of at least one film-forming agent, 0.1 to 8% by weight of at least one compound chosen from plasticizing agents, surface-active agents and dispersing agents, 0.1 to 4% by weight of at least one coupling agent, and 0 to 6% by weight of at least one additive. Another subject-matter of the present invention is glass strands coated with the abovementioned sizing composition and the composite materials containing an organic or inorganic material reinforced with the said glass strands.
摘要翻译：本发明涉及一种玻璃纤维物理凝胶形式的上胶组合物，其含有0.1至5重量％的至少一种选自黄原胶，瓜尔胶和琥珀聚糖的组合剂，2至8重量％的至少一种至少一种选自增塑剂，表面活性剂和分散剂的化合物，0.1至4重量％的至少一种偶联剂和0至6重量％的成膜剂，至少一种添加剂。本发明的另一主题是涂覆有上述施胶组合物的玻璃丝和含有用所述玻璃丝增强的有机或无机材料的复合材料。

19. 发明申请

US20060099417A1 Polyurethane-based anhydrous sizing compositions for glass fibres, glass fibres obtained and composite materials comprising said fibres 审中-公开
标题翻译：用于玻璃纤维的聚氨酯基无水施胶组合物，所获得的玻璃纤维和包含所述纤维的复合材料
公开(公告)号：US20060099417A1
公开(公告)日：2006-05-11
申请号：US10512864
申请日：2003-05-21
申请人： Patrick Moireau , Christelle Pousse
发明人： Patrick Moireau , Christelle Pousse
IPC分类号： D02G3/00
CPC分类号： C03C25/326 , C03C25/25 , Y10T428/2933
摘要： The invention relates to a sizing composition consisting of a solution comprising less than 5% by weight of solvent and comprising a curable base system, said system comprising at least 50% by weight of a mixture of: one or more components containing at least one isocyanate reactive functional group; one or more components containing at least one hydroxyl reactive functional group; and optionally, one or more components containing at least one amine reactive functional group. A subject of the invention is also the glass strands coated with the aforementioned sizing composition. The glass strands obtained can be used to reinforce organic or inorganic materials.
摘要翻译：本发明涉及由包含小于5重量％的溶剂并包含可固化基体系的溶液组成的施胶组合物，所述系统包含至少50重量％的混合物：一种或多种含至少一种异氰酸酯的组分反应性官能团; 一种或多种含有至少一个羟基反应性官能团的组分; 和任选的一种或多种含有至少一个胺反应性官能团的组分。本发明的主题也是用上述施胶组合物涂覆的玻璃丝。获得的玻璃丝可用于增强有机或无机材料。

20. 发明授权

US06187435B1 Sizing composition for glass strands, process using this composition and resulting products 失效
标题翻译：用于玻璃丝的上胶组合物，使用该组合物和所得产品的方法
公开(公告)号：US06187435B1
公开(公告)日：2001-02-13
申请号：US08849741
申请日：1997-09-08
申请人： Patrick Moireau , Anne L'her
发明人： Patrick Moireau , Anne L'her
IPC分类号： D02G300
CPC分类号： C08J5/08 , C03C25/26 , C03C25/36 , Y10T428/2938 , Y10T428/2956 , Y10T428/31627
摘要： The present invention relates to a sizing composition for glass strands composed of a solution with a viscosity of less than or equal to 400 cP comprising less than 5% by weight of solvent and comprising at least one thermally polymerizable base system, the said base system comprising at least 60% by weight of components with a molecular mass of less than 750 and comprising at least 60 % by weight of a mixture: of component(s) exhibiting at least one epoxy reactive functional group, and of component(s) exhibiting at least one anhydride reactive functional group. The invention also relates to a process using this composition and to the strands obtained according to this process and coated with the said composition.
摘要翻译：本发明涉及由粘度小于或等于400cP的溶液组成的玻璃丝束用上胶组合物，该溶液含有少于5％（重量）的溶剂并且包括至少一种可热聚合的基体系，所述的基体系包括至少60重量％的分子量小于750的组分和包含至少60重量％的显示出至少一个环氧反应性官能团的组分的混合物和显示在至少一种酸酐反应性官能团。本发明还涉及使用该组合物和根据该方法获得并用所述组合物涂覆的线的方法。

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