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11. 发明授权

US5902916A Process for reacting an organic compound in the presence of a ruthenium catalyst formed in situ 失效
标题翻译：在原位形成的钌催化剂存在下使有机化合物反应的方法
公开(公告)号：US5902916A
公开(公告)日：1999-05-11
申请号：US845435
申请日：1997-04-25
申请人： Thomas Ruhl , Boris Breitscheidel , Franz Josef Brocker , Wolfgang Reif , Jochem Henkelmann , Karl Heinz Brauch , Andreas Henne
发明人： Thomas Ruhl , Boris Breitscheidel , Franz Josef Brocker , Wolfgang Reif , Jochem Henkelmann , Karl Heinz Brauch , Andreas Henne
IPC分类号： B01J23/46 , C07B35/02 , C07B61/00 , C07C29/132 , C07C29/141 , C07C29/149 , C07C29/20 , C07C35/08 , C07C209/72 , C07C211/40 , C08F8/04 , C07C5/10
CPC分类号： C07C29/20 , B01J23/462 , C07B35/02 , C07C209/72 , C07C29/141 , C07C29/149 , C07C29/19 , C08F8/04 , C07C2101/14 , Y02P20/584
摘要： A process for reacting an organic compound in the presence of a catalyst, wherein the catalyst comprises a homogeneous ruthenium compound or a mixture of two or more thereof deposited in situ on a support.
摘要翻译：一种在催化剂存在下使有机化合物反应的方法，其中催化剂包含在载体上原位沉积的均匀钌化合物或两种或更多种的混合物。

12. 发明授权

US5728900A Process for the selective hydrogenation of butyne-1,4-diol to butene-2-diol-1,4 失效
标题翻译：丁炔-1,4-二醇选择性氢化成丁烯-2-二醇-1,4-的方法
公开(公告)号：US5728900A
公开(公告)日：1998-03-17
申请号：US608647
申请日：1996-02-29
申请人： Franz Josef Brocker , Rainer Becker , Volkmar Menger , Peter Stops
发明人： Franz Josef Brocker , Rainer Becker , Volkmar Menger , Peter Stops
IPC分类号： B01J23/44 , B01J23/60 , B01J23/62 , B01J37/02 , C07B61/00 , C07C29/17 , C07C33/035 , C07C29/56
CPC分类号： C07C29/17 , B01J23/60 , B01J23/628 , B01J37/0238 , C07C33/035 , B01J37/0225
摘要： Catalyst and process for the preparation of butene-2-diol-1,4 by the hydrogenation of butyne-2-diol-1,4 in aqueous solution over a palladium-containing fixed-bed catalyst, which is doped with lead or cadmium, in which a catalyst is used which has been made by applying Pd and Pb or Pd and Cd successively, by vapor deposition or sputtering, to a metal gauze or a metal foil acting as support material followed by forming the catalyst at an elevated temperature in air.
摘要翻译：通过在掺杂铅或镉的含钯固定床催化剂的水溶液中氢化丁炔-2-二醇-1,4-来制备丁烯-2-二醇-1,4的催化剂和方法，其中使用通过气相沉积或溅射将Pd和Pb或Pd和Cd连续地施加到作为载体材料的金属丝网或金属箔，然后在空气中升高的温度下形成催化剂而制备的催化剂。

13. 发明授权

US6162758A Process for dehydrogenating secondary cyclic alcohols 有权
标题翻译：脱氢次环醇的方法
公开(公告)号：US6162758A
公开(公告)日：2000-12-19
申请号：US142218
申请日：1998-09-03
申请人： Franz Josef Brocker , Michael Hesse , Robert Markl
发明人： Franz Josef Brocker , Michael Hesse , Robert Markl
IPC分类号： B01J23/02 , B01J23/06 , B01J27/232 , B01J35/10 , B01J37/03 , C07B61/00 , C07C45/00 , C07C45/29 , C07C49/403 , C07C45/65
CPC分类号： C07C45/002 , B01J23/06 , B01J27/232
摘要： In the dehydrogenation of secondary alcohols in the presence of a catalyst comprising zinc oxide and calcium carbonate at elevated temperature in the gas phase, secondary cyclic alcohols are used and the dehydrogenation is carried out in the presence of hydrogen and a catalyst whose active components comprise from 30 to 60% by weight of zinc oxide and from 40 to 70% by weight of calcium carbonate in the calcite modification.
摘要翻译： PCT No.PCT / EP97 / 01124 Sec。 371日期：1998年9月3日 102（e）日期1998年9月3日PCT 1997年3月6日PCT公布。公开号WO97 / 33853 日期：1997年9月18日在气相中升高的温度下，在包含氧化锌和碳酸钙的催化剂存在下，仲醇脱氢，使用二级环状醇，脱氢在氢气和催化剂存在下进行其活性组分占方解石改性中的30-60重量％的氧化锌和40-70重量％的碳酸钙。

14. 发明授权

US5935898A Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production 失效
标题翻译：单峰和多模式催化剂载体和具有窄孔径分布及其生产的催化剂
公开(公告)号：US5935898A
公开(公告)日：1999-08-10
申请号：US711989
申请日：1996-09-10
申请人： Peter Trubenbach , Alfred Hagemeyer , Gunter Lauth , Uwe Dingerdissen , Franz Josef Brocker , Klemens Flick
发明人： Peter Trubenbach , Alfred Hagemeyer , Gunter Lauth , Uwe Dingerdissen , Franz Josef Brocker , Klemens Flick
IPC分类号： C12M1/40 , B01J21/00 , B01J27/00 , B01J29/00 , B01J35/10 , B01J37/00 , B01J23/00
CPC分类号： B01J37/0018 , B01J35/10 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J35/108 , B01J35/1085
摘要： Monomodal or polymodal catalyst supports or catalysts having a BET specific surface area of from 0.01 to 250 m.sup.2 /g and a monomodal or polymodal pore size distribution having a mean pore diameter of from 50 to 300,000 nm measured by the mercury pressure porosimetry method, whereina) from 10 to 95% of the pore volume is at from 0.1 to 3 times the mean pore diameter and/orb) from 10 to 80% of the pore volume is at from 0.4 to 3 times the mean pore diameter and/orc) from 50 to 95% of the pore volume is at from 0.1 to 1 times the mean pore diameter and/ord) from 50 to 80% of the pore volume is at from 0.4 to 1 times the mean pore diameter ande) the width at half height of the pore size distribution is less than 0.5 times the mean pore diameter,which are useful for preparing chlorine from hydrogen chloride in a non-steady-state Deacon process, for the reaction of ethylbenzene to give styrene in a non-steady-state oxydehydrogenation, for preparing aziridine from ethanolamine, in reductions, hydrogenations, oxidations, dehydrogenations, acid- or base-catalyzed reactions or reactions in a fluidized bed, for removing combustion residues from diesel exhaust gases and for removing NO.sub.x from waste gases, in bioreactors together with bacteria and as biocatalyst supports with immobilized enzymes or microbes, and a process for producing said monomodal or polymodal catalyst supports or catalysts.
摘要翻译：单峰或多模式催化剂载体或BET比表面积为0.01至250m 2 / g的催化剂载体和通过汞压孔隙度法测量的平均孔径为50至300,000nm的单峰或多模孔径分布，其中a ）孔体积的10至95％为平均孔径的0.1至3倍和/或b）孔体积的10至80％为平均孔径的0.4至3倍和/或c ）孔体积的50至95％为平均孔径的0.1至1倍，和/或d）孔体积的50至80％为平均孔径的0.4至1倍，e）孔尺寸分布的半高宽度小于平均孔径的0.5倍，这可用于在非稳态Deacon方法中从氯化氢制备氯，用于乙苯的反应，稳态氧化脱氢，用于从乙醇胺制备氮丙啶，还原 ns，氢化，氧化，脱氢，酸或碱催化的反应或在流化床中的反应，用于从生物反应器中连同细菌和作为生物催化剂载体与固定化酶一起从柴油机排气中除去燃烧残余物并从废气中除去NOx 或微生物，以及用于生产所述单峰或多模式催化剂载体或催化剂的方法。

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