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    • 12. 发明申请
    • Mercaptan Removal Method
    • 硫醇去除方法
    • US20080245703A1
    • 2008-10-09
    • US12057407
    • 2008-03-28
    • Renaud CadoursEric LemaireJulia Magne-Drisch
    • Renaud CadoursEric LemaireJulia Magne-Drisch
    • C10G51/00
    • C10L3/10B01D53/86B01D53/8606B01D2257/306C10L3/102
    • The method allows to remove mercaptans contained in a gaseous feed comprising hydrocarbons by carrying out the following stages: a) contacting, in a reactor R1, gaseous feed 1 with a liquid stream 13 comprising olefins, in the presence of a first acid catalyst so that the mercaptans react with the olefins so as to form sulfides, b) discharging an effluent 3 from reactor R1 and separating the effluent into a gas phase and a liquid phase so as to obtain a mercaptan-depleted treated gas 4 and a sulfide-laden liquid, c) separating the sulfide-laden liquid into a first fraction 6 and a second fraction 5, the volume flow rate of first fraction 6 being at least three times higher than the volume flow rate of second fraction 5, d) recycling first fraction 6 to stage a) as a first portion of said liquid stream to be fed into said reactor R1, e) regenerating second fraction 5 by cracking so as to obtain a sulfide-depleted second fraction 2 that is recycled to stage a) as a second portion of said liquid stream.
    • 该方法允许通过进行以下步骤来除去包含在包含烃的气体进料中的硫醇:a)在反应器R 1中,气态进料1与包含烯烃的液体流13在第一种酸催化剂存在下接触, 硫醇与烯烃反应以形成硫化物,b)从反应器R 1排出流出物3,并将流出物分离成气相和液相,以获得硫醇贫化处理气体4和硫化物 - 负载液体,c)将含硫化物的液体分离成第一馏分6和第二馏分5,第一馏分6的体积流量比第二馏分5的体积流速高至少三倍,d)先循环 馏分6至步骤a)作为待进料到所述反应器R 1中的所述液体物流的第一部分,e)通过裂化再生第二级分5,以获得被再循环到a)的硫化物贫化的第二馏分2作为 第二部分 所说的液体流。
    • 15. 发明授权
    • Mercaptan removal method
    • 硫醇去除方法
    • US07811538B2
    • 2010-10-12
    • US12057407
    • 2008-03-28
    • Renaud CadoursEric LemaireJulia Magne-Drisch
    • Renaud CadoursEric LemaireJulia Magne-Drisch
    • B01D53/48
    • C10L3/10B01D53/86B01D53/8606B01D2257/306C10L3/102
    • The method allows to remove mercaptans contained in a gaseous feed comprising hydrocarbons by carrying out the following stages: a) contacting, in a reactor R1, gaseous feed 1 with a liquid stream 13 comprising olefins, in the presence of a first acid catalyst so that the mercaptans react with the olefins so as to form sulfides, b) discharging an effluent 3 from reactor R1 and separating the effluent into a gas phase and a liquid phase so as to obtain a mercaptan-depleted treated gas 4 and a sulfide-laden liquid, c) separating the sulfide-laden liquid into a first fraction 6 and a second fraction 5, the volume flow rate of first fraction 6 being at least three times higher than the volume flow rate of second fraction 5, d) recycling first fraction 6 to stage a) as a first portion of said liquid stream to be fed into said reactor R1, e) regenerating second fraction 5 by cracking so as to obtain a sulfide-depleted second fraction 2 that is recycled to stage a) as a second portion of said liquid stream.
    • 该方法允许通过进行以下步骤来除去包含在包含烃的气态进料中的硫醇:a)在反应器R1中将气态进料1与包含烯烃的液体流13在第一酸催化剂存在下接触使得 硫醇与烯烃反应以形成硫化物,b)从反应器R1排出流出物3,并将流出物分离成气相和液相,以获得硫醇贫化处理气体4和含硫化物的液体 ,c)将含硫化物的液体分离成第一馏分6和第二馏分5,第一馏分6的体积流量比第二馏分5的体积流速高至少三倍,d)回收第一馏分6 将a)作为待进料到所述反应器R1中的所述液体物流的第一部分,e)通过裂化再生第二馏分5,以获得被再循环至a)段的硫化物贫乏的第二馏分2作为第二部分 的说 液体流。