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11. 发明授权

US5556823A Catalytic system and process for the copolymerization of olefins with carbon monoxide 失效
标题翻译：催化体系和烯烃与一氧化碳共聚的方法
公开(公告)号：US5556823A
公开(公告)日：1996-09-17
申请号：US348126
申请日：1994-11-28
申请人： Anna Sommazi , Gabriele Lugli , Fabio Garbassi
发明人： Anna Sommazi , Gabriele Lugli , Fabio Garbassi
IPC分类号： B01J31/14 , B01J31/18 , B01J31/24 , C07F1/00 , C07F5/02 , C08G67/02
CPC分类号： C08G67/02 , B01J31/146 , B01J31/1815 , B01J31/2409 , C07F1/005 , C07F5/027 , B01J2531/16 , B01J2531/17 , B01J2531/18
摘要： An active catalyst in the preparation of alternating copolymers of olefins with carbon monoxide (CO) and consisting of:a) a metal salt of the group IB of the periodic table;b) a bidentate binder containing two nitrogen or phosphorous atoms capable of binding themselves to the metal atom by means of co-ordination bonds;c) a Lewis acid;d) optionally an oxidizing agent.The preparation of the catalyst is described together with its use in the alternating copolymerization of ethylene (C2) and/or other olefins with carbon monoxide.
摘要翻译：烯烃与一氧化碳（CO）的交替共聚物的制备中的活性催化剂，其由以下组成：a）周期表第IB族金属盐; b）含有能够通过配位键结合自身与金属原子的两个氮原子或磷原子的二齿粘合剂; c）路易斯酸; d）任选的氧化剂。描述催化剂的制备及其在乙烯（C2）和/或其它烯烃与一氧化碳的交替共聚中的用途。

12. 发明授权

US5369073A Homogeneous catalytic system and process for copolymerizing olefins with carbon monoxide 失效
标题翻译：均相催化体系和烯烃与一氧化碳的共聚方法
公开(公告)号：US5369073A
公开(公告)日：1994-11-29
申请号：US29875
申请日：1993-03-11
申请人： Anna Sommazzi , Gabriele Lugli , Fabio Garbassi , Fausto Calderazzo
发明人： Anna Sommazzi , Gabriele Lugli , Fabio Garbassi , Fausto Calderazzo
IPC分类号： C08G67/00 , C08G67/02 , B01J31/18 , B01J31/28
CPC分类号： C08G67/02
摘要： A catalyst active in the preparation of alternating olefin/carbon monoxide (CO) copolymers is constituted by:(a) at least one salt of a metal of Group IB of the Periodic System,(b) an either mono- or bidentate ligand containing one or two nitrogen or phosphorus atoms capable of linking to the copper, silver or gold atom by means of dative bonds,(c) a mineral or organic acid.Disclosed are the preparation of the catalyst and the use of said catalyst in alternated copolymerization of ethylene (C2) and/or other olefins with carbon monoxide.
摘要翻译：在制备交替烯烃/一氧化碳（CO）共聚物中有活性的催化剂由以下组成：（a）至少一种周期系IB族金属的盐，（b）含有一个或多个或能够通过二价键连接到铜，银或金原子的两个氮或磷原子，（c）矿物或有机酸。公开了催化剂的制备和所述催化剂在乙烯（C2）和/或其它烯烃与一氧化碳的交替共聚中的用途。

13. 发明授权

US5369187A Polymers containing repeating cycloketonic units, and method for obtaining them 失效
标题翻译：含有重复环丙基单元的聚合物及其获得方法
公开(公告)号：US5369187A
公开(公告)日：1994-11-29
申请号：US71517
申请日：1993-06-03
申请人： Anna Sommazzi , Nicoletta Cardi , Fabio Garbassi , Chrissostomos Chatgilialoglu
发明人： Anna Sommazzi , Nicoletta Cardi , Fabio Garbassi , Chrissostomos Chatgilialoglu
IPC分类号： C08F8/48 , C08C19/00 , C08C19/10 , C08F8/00 , C08G67/02
CPC分类号： C08C19/00 , C08C19/10
摘要： Polymers having a very good combination of chemical, mechanical and process properties, and particularly useable either alone or as mixtures, as high-tenacity thermoplastic polymer and as elastomers or elastomeric modifiers, contain, randomly distributed along their chain, repeating cycloketonic structural units having the following general formula (I): ##STR1## wherein: A represents a tetravalent aliphatic or cycloaliphatic, substituted or non-substituted moiety containing a total number of from 4 to 50, preferably from 4 to 20, carbon atoms.Such polymers can be prepared by means of a process which comprises reacting, in a liquid media, a polydiene containing adjacent structural units derived from the 1,4-cis polymerization of conjugated dienes, with carbon monoxide, in the presence of free radical generating compounds and, optionally, a compound capable of acting as a hydrogen donor.
摘要翻译：作为高韧性热塑性聚合物和弹性体或弹性体改性剂，具有非常好的化学，机械和加工性能的组合，特别是可单独使用或作为混合物使用的聚合物包含沿着它们的链无规分布的重复的环酮结构单元，通式（I）：其中：A表示含有总数为4至50，优选4至20个碳原子的四价脂族或脂环族，取代或未取代的部分。这样的聚合物可以通过一种方法制备，该方法包括使液体介质中含有衍生自共轭二烯的1,4-顺式聚合的相邻结构单元的聚二烯与一氧化碳在存在自由基产生化合物和任选的能够充当氢供体的化合物。

14. 发明授权

US5334343A Polyester compositions with a high crystallization rate 失效
标题翻译：具有高结晶速率的聚酯组合物
公开(公告)号：US5334343A
公开(公告)日：1994-08-02
申请号：US850041
申请日：1992-03-12
申请人： Riccardo Po' , Ernesto Occhiello , Giorgio Giannotta , Fabio Garbassi
发明人： Riccardo Po' , Ernesto Occhiello , Giorgio Giannotta , Fabio Garbassi
IPC分类号： C08K5/10 , C08K5/12 , C08L67/00 , C08L67/02 , B29C45/00
CPC分类号： C08K5/12
摘要： Polyester compositions with a high crystallization rate obtained by mixing, at a high temperature, a polyester resin with at least one organic compound having the general formula:ROOC--Ar--OOC--Ar'--COO--Ar--COOR (I)where R represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl radical whereare Ar and Ar', either the same or different, represent a simple or condensed aromatic radical containing from 6 to 12 carbon atoms, and cooling the mixture thus obtained to room temperature.
摘要翻译：通过在高温下将聚酯树脂与至少一种具有以下通式的有机化合物：ROOC-Ar-OOC-Ar'-COO-Ar-COOR（I）混合而获得的具有高结晶速率的聚酯组合物，其中R表示氢原子或C1-C4烷基，其中Ar和Ar'相同或不同，表示含有6至12个碳原子的简单或缩合的芳族基团，并将由此获得的混合物冷却至室温。

15. 发明授权

US5279853A Process for coating, with inorganic films, the surface of bodies fabricated from polymeric materials 失效
标题翻译：用无机膜涂覆由聚合材料制成的主体表面的方法
公开(公告)号：US5279853A
公开(公告)日：1994-01-18
申请号：US811968
申请日：1991-12-23
申请人： Ernesto Occhiello , Marco Morra , Fabio Garbassi
发明人： Ernesto Occhiello , Marco Morra , Fabio Garbassi
IPC分类号： C23C14/10 , B05D5/06
CPC分类号： C23C14/10
摘要： A process for coating the surface of bodies fabricated from polymeric materials with inorganic films by depositing on the polymeric bodies a thin layer obtained by thermal evaporation, under vacuum, of glass/silicon mixtures. The process provides for improved control of surface-depending properties, such as wettability, haze resistance, gas and weight barrier properties and selective absorption of ultraviolet light.
摘要翻译：通过在聚合物体上沉积由玻璃/硅混合物在真空下热蒸发获得的薄层来涂覆由聚合材料制成的主体表面的方法。该方法提供了改善表面依赖性质的控制，例如润湿性，防雾性，气体和重量阻隔性能以及紫外光的选择性吸收。

16. 发明授权

US5278281A Polyesters showing a high crystallization rate and procedure for their preparation 失效
标题翻译：显示出高结晶速率的聚酯及其制备方法
公开(公告)号：US5278281A
公开(公告)日：1994-01-11
申请号：US850039
申请日：1992-03-12
申请人： Riccardo Po , Ernesto Occhiello , Fabio Garbassi , Luigi Pelosini
发明人： Riccardo Po , Ernesto Occhiello , Fabio Garbassi , Luigi Pelosini
IPC分类号： C08G63/183 , C08G63/181 , C08G63/185 , C08G63/60 , C08G63/78 , C08G63/16
CPC分类号： C08G63/60 , C08G63/185
摘要： Polyesters with a high crystallization rate synthesized by the polycondensation of terephthalic acid with at least one C.sub.2 -C.sub.4 alkylenic glycol in the presence of 0.1-1.5 mol % of a copolymerizable reagent having the general formula:ROOC--Ar--OOC--Ar'--COO--Ar--COORwhere Ar and Ar'represent aromatic radicals and R represent a halogen, a hydrogen atom or a C.sub.1- C.sub.4 alkyl radical.
摘要翻译：通过对苯二甲酸与至少一种C 2 -C 4亚烷基二醇在0.1-1.5摩尔％的具有以下通式的可共聚试剂的存在下缩聚而合成的聚酯：ROOC-Ar-OOC-Ar'-COO Ar-COOR，其中Ar和Ar表示芳族基团，R代表卤素，氢原子或C1-C4烷基。

17. 发明授权

US5266676A Low-crystallization-speed polyesters, and process for their preparation 失效
标题翻译：低结晶速度聚酯，及其制备方法
公开(公告)号：US5266676A
公开(公告)日：1993-11-30
申请号：US914850
申请日：1992-07-15
申请人： Riccardo Po' , Ernesto Occhiello , Fabio Garbassi , Luigi Pelosini
发明人： Riccardo Po' , Ernesto Occhiello , Fabio Garbassi , Luigi Pelosini
IPC分类号： C08G63/181 , C08G63/189 , C08G63/199 , C08G63/60 , D01F6/84 , C08G63/20
CPC分类号： D01F6/84 , C08G63/181 , C08G63/189 , C08G63/60
摘要： Low-crystallization-speed polyesters obtained by means of the polycondensation of 2,6-naphthalene-dicarboxy acid with at least one (C.sub.2 -C.sub.10)-(cyclo)alkylene glycol in the presence of 0.5-50 mol % of a copolymerizable reactant of general formula:ROOC--Ar--OOC--Ar'--COO--Ar--COOR (I)wherein Ar and Ar' stand for aromatic radicals, and R stands for a hydrogen atom or a (C.sub.1 -C.sub.4)-alkyl radical, or the OR group is replaced by a halogen.

18. 发明授权

US06576730B2 Organic initiators and their use in the polymerization of unsaturated monomers 有权
公开(公告)号：US06576730B2
公开(公告)日：2003-06-10
申请号：US09852697
申请日：2001-05-11
申请人： Nicoletta Cardi , Riccardo Po' , Giuliana Schimperna , Maria Caldararo , Maria Anna Cardaci , Fabio Garbassi
发明人： Nicoletta Cardi , Riccardo Po' , Giuliana Schimperna , Maria Caldararo , Maria Anna Cardaci , Fabio Garbassi
IPC分类号： C08F400
CPC分类号： C07D265/02 , C07D261/20 , C07D273/00 , C08F4/00
摘要： Process for the polymerization of unsaturated vinyl and/or vinylidene monomers which comprises reacting one or more monomers in the presence of heterocyclic initiators having a nitrogen atom bound to an oxygen atom at a temperature ranging from 100 to 130° C.

19. 发明授权

US5780004A Process for the preparation of mixed silica-zirconia sols and mixed oxides obtained in spherical form 失效
标题翻译：用于制备球形混合氧化硅 - 氧化锆溶胶和混合氧化物的方法
公开(公告)号：US5780004A
公开(公告)日：1998-07-14
申请号：US672038
申请日：1996-06-26
申请人： Luigi Balducci , Raffaele Ungarelli , Fabio Garbassi
发明人： Luigi Balducci , Raffaele Ungarelli , Fabio Garbassi
IPC分类号： B01J21/08 , B01J35/10 , B01J37/03 , C01B33/141 , C01B33/148 , C01G25/02
CPC分类号： B01J37/033 , B01J21/08 , B01J37/036 , B01J35/10
摘要： A process for the preparation of mixed silica-zirconia sols and mixed oxides in spherical form, comprising mixing a silicon alkoxide with a solution of an inorganic zirconium salt in a low molecular weight polyol and subjecting the intermediate thus formed to acid hydrolysis in a water medium.
摘要翻译：一种用于制备球形混合二氧化硅 - 氧化锆溶胶和混合氧化物的方法，包括将硅醇盐与无机锆盐溶液在低分子量多元醇中混合，并使由此形成的中间体在水介质中酸解。

20. 发明授权

US5717060A Process for the preparation of copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation 失效
标题翻译：用于制备基于一氧化碳和至少一种含有烯基不饱和化合物的共聚物的方法
公开(公告)号：US5717060A
公开(公告)日：1998-02-10
申请号：US741901
申请日：1996-10-31
申请人： Anna Sommazzi , Fabio Garbassi , Giovanni Mestroni , Barbara Milani , Lidia Vicentini
发明人： Anna Sommazzi , Fabio Garbassi , Giovanni Mestroni , Barbara Milani , Lidia Vicentini
IPC分类号： C08G67/00 , C08G67/02 , B01J31/18
CPC分类号： C08G67/02
摘要： An improved process is described for the preparation of alternating linear copolymers based on carbon monoxide and at least one compound containing an alkenyl unsaturation which comprises reacting in a liquid solvent under the operating conditions, a mixture of carbon monoxide and one or more compounds containing an alkenyl unsaturation in the presence of: (i) a catalyst having general formula (I) �Pd(chel) (chel') !.sup.++ �A.sup.- !.sub.2 (I) wherein chel and chel' the same or different, represent a nitrogenated or phosphorated bidentate chelating agent, and A.sup.- represents an essentially non-coordinating, non esterifiable and non labile anion of an acid with pKa less than 2; and (ii) a cocatalyst having general formula (II) �chel"H.sup.+ !�A'.sup.- ! (II) wherein A'.sup.-, the same as or different from A.sup.-, has the same meaning defined above and chel" represents a nitrogenated bidentate chelating agent the same as or different from chel and chel'.
摘要翻译：描述了一种用于制备基于一氧化碳和至少一种含有烯基不饱和键的化合物的交替线性共聚物的改进方法，该化合物包括在操作条件下在液体溶剂中反应，一氧化碳和一种或多种含有烯基的化合物的混合物存在下的不饱和度：（i）具有通式（I）[Pd（螯合物）（螯合物）] ++ [A-] 2（I）的催化剂，其中螯合物和螯合物相同或不同，代表氮化或磷酸二异构螯合剂，A-代表pKa小于2的酸的基本上非配位的，非酯化的和非不稳定的阴离子; 和（ii）具有通式（II）[chel'H +] [A' - ]（II）的助催化剂，其中与A相同或不同的A'具有与上述相同的含义，并且“ 表示与螯合物相同或不同的氮化二齿螯合剂。

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