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    • 16. 发明授权
      US06696402B2 Laundry detergent compositions comprising zwitterionic polyamines 失效
    • Laundry detergent compositions comprising zwitterionic polyamines
    • 包含两性离子多胺的洗衣洗涤剂组合物
    • US06696402B2
    • 2004-02-24
    • US10232357
    • 2002-08-30
    • Eugene Paul Gosselink , Kenneth Nathan Price
    • Eugene Paul Gosselink , Kenneth Nathan Price
    • C11D168
    • C11D3/3796 , C11D3/3723
    • The present invention relates to laundry detergent compositions comprising: A) from about 0.01%, preferably from about 0.1%, more preferably from about 1%, most preferably from about 3% to about 50%, preferably to about 20%, more preferably to about 10%, most preferably to about 7% by weight, of a hydrophobically modified polyamine having the formula: wherein R is C5-C20 linear or branched alkylene, and mixtures thereof; R1 is an alkyleneoxy unit having the formula: —(R2O)x—R3 wherein R2 is C2-C4 linear or branched alkylene, and mixtures thereof; at least one R3 is an anionic unit, and the remaining R3 moieties are selected from the group consisting of hydrogen, C1-C22 alkyl, C7-C22 alkylenearyl, an anionic unit, and mixtures thereof; x is from about 15 to about 30; Q is a hydrophobic quaternizing unit selected from the group consisting of C8-C30 linear or branched alkyl, C6-C30 cycloalkyl, C7-C30 substituted or unsubstituted alkylenearyl, and mixtures thereof; X is an anion present in sufficient amount to provide-electronic neutrality; n is from 0 to 4; B) from about 0.01% by weight, of a surfactant system comprising one or more surfactants selected from: i) from 0% to 100% by weight, of one or more anionic surfactants; ii) from 0% to 100% by weight, of one or more nonionic surfactants; iii) optionally from 0.1% to about 80% by weight, of one or more cationic surfactants; iv) optionally from 0.1% to about 80% by weight, of one or more zwitterionic surfactants; v) optionally from 0.1% to about 80% by weight, of one or more ampholytic surfactants; or vi) mixtures thereof; C) the balance carriers and adjunct ingredients.
    • 本发明涉及洗衣洗涤剂组合物，其包含：A）约0.01％，优选约0.1％，更优选约1％，最优选约3％至约50％，优选至约20％，更优选至 约10重量％，最优选至约7重量％的具有下式的疏水改性多胺：其中R是C 5 -C 20直链或支链亚烷基，及其混合物; R 1是具有下式的亚烷氧基单元：其中R 2是C 2 -C 4直链或支链亚烷基，及其混合物; 至少一个R 3是阴离子单元，其余的R 3部分选自氢，C 1 -C 22烷基，C 7 -C 22亚烷基硬脂基，阴离子单元及其混合物; x为约15至约30; Q是选自C8-C30直链或支链烷基，C6-C30环烷基，C7-C30取代或未取代的亚烷基硬脂基的疏水季铵化单元及其混合物; X是足以提供电子中性的阴离子; n为0至4; B）约0.01重量％的包含一种或多种表面活性剂的表面活性剂体系，所述表面活性剂体系选自：i）0重量％至100重量％的一种或多种阴离子表面活性剂; ii）0 ％至100重量％的一种或多种非离子表面活性剂; iii）任选0.1％至约80％重量的一种或多种阳离子表面活性剂; iv）任选地0.1％至约80％重量的一种或多种 更多的两性离子表面活性剂; v）任选地0.1％至约80％重量的一种或多种两性表面活性剂; orvi）混合物; C）平衡载体和辅助成分。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Espacenet 法律信息 同族专利 专利引用
    • 18. 发明授权
      US6127331A Laundry compositions comprising alkoxylated polyalkyleneimine dispersants 失效
    • Laundry compositions comprising alkoxylated polyalkyleneimine dispersants
    • 包含烷氧基化聚亚烷基亚胺分散剂的洗衣组合物
    • US6127331A
    • 2000-10-03
    • US103240
    • 1998-06-23
    • James Albert Cleary , Shulin Zhang , Eugene Paul Gosselink
    • James Albert Cleary , Shulin Zhang , Eugene Paul Gosselink
    • C11D3/37 , C11D3/39 , C11D3/30 , C11D3/386 , C11D3/395
    • C11D3/3723 , C11D3/3907 , C11D3/3915 , C11D3/3917 , C11D3/392
    • The present invention relates to laundry detergent compositions which comprise an alkoxylated polyalkyleneimine soil dispersant having the formula: ##STR1## wherein R is C.sub.2 -C.sub.6 linear alkylene, C.sub.3 -C.sub.6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:--(R.sup.1 O).sub.m (R.sup.2 O).sub.n R.sup.3wherein R.sup.1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R.sup.2 is ethylene; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x, and y are each independently from about 4 to about 200; provided at least one --(R.sup.1 O) unit is attached to the backbone prior to attachment of an --(R.sup.2 O) unit and further provided m+n is at least 12, said dispersants are compatible with bleach. The disclosed alkoxylated polyalkyleneimines are also suitable for use as soil dispersant in bleach-containing laundry pre-soaks and bleaching agents.
    • 本发明涉及衣物洗涤剂组合物，其包含具有下式的烷氧基化聚亚烷基亚胺土壤分散剂：其中R是C 2 -C 6直链亚烷基，C 3 -C 6支链亚烷基及其混合物; B是分支的延续; E是具有下式的亚烷氧基单元： - （R 1 O）m（R 20）n R 3，其中R 1是1,2-亚丙基，1,2-亚丁基及其混合物; R2是乙烯; R3是氢，C1-C4烷基及其混合物; m为约1至约10; n为约10至约40; w，x和y各自独立地为约4至约200; 提供至少一个 - （R 1 O）单元在连接 - （R 2 O）单元之前连接到骨架上，并进一步提供m + n至少为12，所述分散剂与漂白剂相容。 所公开的烷氧基化聚亚烷基亚胺也适用于含漂白剂的洗衣前预浸和漂白剂中的土壤分散剂。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 19. 发明授权
      US6111056A Cyclic amine based polymers and process for their production 有权
    • Cyclic amine based polymers and process for their production
    • 循环胺基聚合物及其生产方法
    • US6111056A
    • 2000-08-29
    • US153307
    • 1998-09-15
    • Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh , Rajan Panandiker , Sherri Randall , Eugene Paul Gosselink , William Conrad Wertz
    • Soren Hildebrandt , Elisabeth Kappes , Dieter Boeckh , Rajan Panandiker , Sherri Randall , Eugene Paul Gosselink , William Conrad Wertz
    • C08G73/02 , C08G73/06 , C11D3/00 , C11D3/22 , C11D3/37 , C11D3/382 , C08G69/00 , C08F8/02 , C08G12/00 , C08L79/02
    • C08G73/0273 , C08G73/02 , C08G73/022 , C08G73/0616 , C11D3/0015 , C11D3/225 , C11D3/227 , C11D3/3723 , C11D3/3776
    • A cyclic amine containing polymer substantially free of primary and secondary amino groups which is prepared by reacting:a) an amine selected from the group consisting of:i) cyclic amines having at least one nitrogen atom in the ring and at least one primary amino alkyl group bonded to the nitrogen atom of the ring, andii) mixtures of cyclic amines containing at least two nitrogen atoms which react with a cross-linking agent with at least one other amine containing 1-6 nitrogen atoms which react with a cross-linking agent, withb) at least one cross-linker selected from the group consisting of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms and mixtures of at least one compound containing two groups which react with the primary amino group and said nitrogen atoms with at least one compound containing at least three groups which react with the primary amino group and said nitrogen atoms in a molar ratio of (a):(b) of from 2.5:1 to 1:1.5 thereby forming a cyclic amine containing polymer containing primary or secondary amino groups and reacting said cyclic amine based polymer, withc) an alkylating agent selected from the group consisting of epoxides, alkyl halides, arylalkyl halides, dimethyl sulfate, diethyl sulfate, mixtures of formic acid and an aldehyde, and mixtures of formic acid and a ketone, to convert more than 80% of the primary and secondary nitrogen groups into tertiary nitrogen groups.
    • 一种基本上不含伯和仲氨基的含环胺的聚合物，其通过以下方法制备：a）选自以下的胺：i）环中具有至少一个氮原子的环胺和至少一个伯氨基烷基 基团与环的氮原子键合，以及ii）含有至少两个氮原子的环状胺的混合物，其与交联剂与至少一种含有1-6个氮原子的其它胺反应，其与交联反应 其中b）至少一个选自至少一种含有两个与伯氨基和所述氮原子反应的基团的化合物的交联剂以及至少一种含有两个与主要氨基反应的基团的化合物的混合物 氨基和所述氮原子与至少一种含有至少三个与伯氨基和所述氮原子反应的化合物，其摩尔比为（a）：（b）为2 1.5:1至1:1.5，由此形成含有伯胺或仲氨基的含环胺的聚合物，并使所述环胺基聚合物与c）选自环氧化物，烷基卤，芳烷基卤化物，二甲基 硫酸盐，二乙基硫酸盐，甲酸和醛的混合物，以及甲酸和酮的混合物，将80％以上的初级和次级氮基团转化为叔氮基团。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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