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11. 发明授权

US4464478A Catalyst components and catalysts for polymerizing olefins 失效
标题翻译：用于聚合烯烃的催化剂组分和催化剂
公开(公告)号：US4464478A
公开(公告)日：1984-08-07
申请号：US428976
申请日：1982-09-30
申请人： Umberto Scata , Enrico Albizzati , Enzo Giannetti
发明人： Umberto Scata , Enrico Albizzati , Enzo Giannetti
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022
摘要： Catalyst-forming components are prepared from(a) a halogenated Ti compound containing at least a Ti-halogen bond;(b) an electron-donor compound free of active hydrogen atoms;and(c) the solid product of the reaction between at least one electron-donor compound containing active hydrogen atoms and a Mg dihalide or a complex thereof with an electron-donor compound free of active hydrogen atoms, obtained by decomposing organic Mg compounds containing at least one Mg-R or Mg-OR group, in which R is an alkyl, aryl, cycloalkyl or alkenyl radical having 1 to 20 carbon atoms, by means of a halogenating agent different from (a).Catalysts for polymerizing olefins and prepared by mixing the aforesaid catalyst-forming components with an organometallic compound of Al are also disclosed.
摘要翻译：催化剂形成成分由（a）至少含有Ti-卤素键的卤化Ti化合物制备; （b）不含活性氢原子的电子给体化合物; 和（c）包含活性氢原子的至少一种电子给体化合物与二卤化镁或其配合物与不含活性氢原子的电子给体化合物之间的反应的固体产物，通过分解含有至少一个Mg-R或Mg-OR基团，其中R是具有1至20个碳原子的烷基，芳基，环烷基或烯基，通过不同于（a）的卤化剂。还公开了用于聚合烯烃并通过将上述催化剂形成组分与Al的有机金属化合物混合制备的催化剂。

12. 发明授权

US4399054A Catalyst components and catalysts for the polymerization of alpha-olefins 失效
标题翻译：用于α-烯烃聚合的催化剂组分和催化剂
公开(公告)号：US4399054A
公开(公告)日：1983-08-16
申请号：US226837
申请日：1981-01-21
申请人： Mario Ferraris , Francesco Rosati , Sandro Parodi , Enzo Giannetti , Giuseppe Motroni , Enrico Albizzati
发明人： Mario Ferraris , Francesco Rosati , Sandro Parodi , Enzo Giannetti , Giuseppe Motroni , Enrico Albizzati
IPC分类号： C08F4/00 , B01J31/38 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/65 , C08F4/654 , C08F10/00
CPC分类号： C08F4/022 , C08F10/00
摘要： Catalyst components which comprise the reaction product of a Ti compound and a Mg dihalide and which are in the form of spherical particles having an average diameter of 1 to 100 microns, a surface area of 300 to 500 m.sup.2 /g, and a porosity of 0.3 to 0.4 cc/g are disclosed, as are catalysts also in the form of spherical particles prepared therefrom and useful in the polymerization of ethylene and of alpha-olefins CH.sub.2 .dbd.CHR in which R is alkyl radical having from 1 to 6 carbon atoms, and the polymerization of the alpha-olefins therewith.
摘要翻译：催化剂组分包括Ti化合物和二卤化镁的反应产物，其呈球形颗粒形式，平均直径为1至100微米，表面积为300至500m 2 / g，孔隙率为0.3 公开了0.4cc / g，作为由其制备的球形颗粒形式的催化剂也可用于乙烯和其中R为具有1至6个碳原子的烷基的α-烯烃CH 2 = CHR的聚合，以及 α-烯烃的聚合反应。

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