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    • 11. 发明授权
    • Method of controlling infiltration of complex-shaped ceramic-metal composite articles and the products produced thereby
    • 控制复合陶瓷 - 金属复合制品渗透的方法及由此产生的产品
    • US06200526B1
    • 2001-03-13
    • US09297968
    • 1999-05-11
    • Richard T. FoxAleksander J. PyzikChan HanRobert T. Nilsson
    • Richard T. FoxAleksander J. PyzikChan HanRobert T. Nilsson
    • B22F326
    • G11B5/7315C04B41/5155C04B41/52C04B41/88C04B41/89C22C1/1036C22C2001/1021C22C2001/1057G11B5/8404
    • A process for preparing complex-shaped, ceramic-metal composite articles, comprising: (a) contacting a non-wettable powder that is non-wetting to a metal to be used for infiltration with a shaped ceramic body to form a layer of the non-wettable powder on one or more surfaces of the shaped ceramic body, wherein the shaped ceramic body has a region where there is no layer of the non-wettable powder, and (b) infiltration the shaped ceramic body with the metal through the region or regions where there is no layer of the non-wettable powder, such that a complex-shaped ceramic-metal composite comprising one or more metal phases and one or more ceramic phases is formed, wherein the article has substantially the net shape of the shaped ceramic body and undesirable regions of excess metal on the surface and undesirable phases within the complex-shaped ceramic-metal composite article near the surface are located only in the region or regions where there is no layer of the non-wettable powder. The process of the invention allows the preparation of complex-shaped ceramic-metal composite articles with undesirable regions of excess metal and undesirable phases on the surface(s), of, or within, the article only in the regions where there is, or was, no layer of non-wettable powder. The process of the invention allows the preparation of a complex-shaped ceramic-metal composite article which requires little or no machining of the surface(s) to achieve a finished article. A complex-shaped ceramic-metal composite article is prepared which contains few undesirable regions of excess metal and undesirable phases.
    • 一种制备复杂形状的陶瓷 - 金属复合制品的方法,包括:(a)将不湿润的非可润湿粉末与用于渗透的金属与成形陶瓷体接触以形成非 - 在成形陶瓷体的一个或多个表面上的可润湿粉末,其中成形陶瓷体具有不存在不可湿性粉末层的区域,(b)使成形陶瓷体与金属渗透穿过该区域或 没有不可湿粉末层的区域,使得形成包含一个或多个金属相和一个或多个陶瓷相的复合形状的陶瓷 - 金属复合材料,其中制品具有基本上成形陶瓷的净形状 表面上的多余金属的主体和不期望的区域以及表面附近的复合陶瓷 - 金属复合制品内的不期望的相位仅位于不具有不可湿性粉末层的区域或区域中。 本发明的方法允许制备复合形状的陶瓷 - 金属复合制品,其具有不需要的过量金属区域和不期望的相,仅在制品的表面上或内部存在, ,无层不可湿粉。 本发明的方法允许制备复杂形状的陶瓷 - 金属复合制品,其需要很少或不需要加工表面以实现最终制品。 制备复杂形状的陶瓷 - 金属复合制品,其包含少量不需要的过量金属和不期望的相的区域。
    • 12. 发明授权
    • Home bathing unit
    • 家庭洗浴单元
    • US4546506A
    • 1985-10-15
    • US653558
    • 1984-09-24
    • Raymond T. HouleFrederick A. KilbournJames E. De KrakerRobert T. Nilsson
    • Raymond T. HouleFrederick A. KilbournJames E. De KrakerRobert T. Nilsson
    • A61H33/00A47K3/00E04H1/12A47K3/02
    • A47K3/006
    • A bathing unit is particularly designed for home use, and includes a bathtub with an access opening in one side for easy ingress and egress, and a vertically sliding door to close the access opening. The bathing unit has a unique, combination door guide and grab bar arrangement, an adjustable control console, and a power door lock, all of which permit the bather to readily operate the door by himself, and to adjust the water temperature, flow and whirlpool from a seated position within the bathtub. The bather can receive total bathing and whirlpool therapy in private, without the need for an assistant. The combination door guide and grab bar arrangement includes a pair of support rods located on either side of the access opening, which function both as a track on which the door smoothly and easily glides, and also as vertical grab bars, which greatly facilitate entering and exiting the bathtub, and do not interfer with the operation of the door. The adjustable control console allows a seated bather to move the bathing controls to a convenient location within easy reach. The power door lock securely closes the door to a fully closed and sealed position without significant manual effort, and includes a remote actuator located on the control console to further facilitate the use of the bathing unit without an attendant, or other assistance.
    • 洗浴单元特别设计用于家庭使用,并且包括具有一侧的入口开口用于容易进出的浴缸和用于关闭进入开口的垂直滑动门。 洗澡单元具有独特的组合门引导和抓斗布置,可调控制台和电动门锁,所有这些都允许沐浴者自己轻松操作门,并调节水温,流量和漩涡 从浴缸内的就座位置。 沐浴者可以私人接受全面的沐浴和漩涡疗法,无需助手。 组合门引导和抓斗布置包括位于进入开口两侧的一对支撑杆,其作用在门平滑且容易地滑动的轨道上,并且还用作垂直抓杆,这极大地方便了进入和 离开浴缸,不要干扰门的操作。 可调节的控制台允许一个坐着的沐浴者将洗澡控制器移动到方便的位置,方便到达。 电动门锁牢固地将门关闭到完全关闭和密封的位置,而不需要大量的手动操作,并且包括位于控制台上的远程致动器,以进一步方便使用洗浴单元而无需服务员或其他帮助。
    • 15. 发明申请
    • CHALCOGENIDE-BASED MATERIALS AND IMPROVED METHODS OF MAKING SUCH MATERIALS
    • 基于氯化铝的材料和改进的制造这种材料的方法
    • US20110226336A1
    • 2011-09-22
    • US13047190
    • 2011-03-14
    • Jennifer E. GerbiMarc G. LangloisRobert T. Nilsson
    • Jennifer E. GerbiMarc G. LangloisRobert T. Nilsson
    • H01L31/0264C23C14/34C23C14/06G02F1/361
    • H01L31/0749C23C14/0623C23C14/3464C23C14/5866H01L21/02568H01L21/02614H01L21/02631
    • The present invention provides strategies for making high quality CIGS photoabsorbing materials from precursor films that incorporate a sub-stoichiometric amount of chalcogen(s). Chalcogen(s) are incorporated into the CIGS precursor film via co-sputtering with one or more other constituents of the precursor. Optional annealing also may be practiced to convert precursor into more desirable chalcopyrite crystalline form in event all or a portion of the precursor has another constitution. The resultant precursors generally are sub-stoichiometric with respect to chalcogen and have very poor electronic characteristics. The conversion of these precursors into CMS photoabsorbing material via chalcogenizing treatment occurs with dramatically reduced interfacial void content. The resultant CIGS material displays excellent adhesion to other layers in the resultant photovoltaic devices. Ga migration also is dramatically reduced, and the resultant films have optimized Ga profiles in the top or bottom portion of the film that improve the quality of photovoltaic devices made using the films.
    • 本发明提供了从含有亚化学计量量的硫族元素的前体膜制备高品质CIGS光吸收材料的策略。 通过与前体的一种或多种其它组分的共溅射将硫族化合物并入到CIGS前体膜中。 当前体的全部或一部分具有其它结构的情况下,还可以进行任选的退火以将前体转化为更理想的黄铜矿结晶形式。 所得前体通常相对于硫属元素是亚化学计量的并且具有非常差的电子特性。 通过硫属化处理将这些前体转化成CMS光吸收材料发生显着降低的界面空隙含量。 所得到的CIGS材料在所得到的光伏器件中显示出对其它层的优异粘合性。 Ga迁移也显着降低,并且所得膜在膜的顶部或底部具有优化的Ga分布,其改善了使用该膜制备的光电装置的质量。
    • 17. 发明授权
    • B4C/Al cermets and method for making same
    • B4C / Al金属陶瓷及其制造方法
    • US5039633A
    • 1991-08-13
    • US407393
    • 1989-09-14
    • Aleksander J. PyzikRobert T. Nilsson
    • Aleksander J. PyzikRobert T. Nilsson
    • B22F3/26C04B35/65C04B41/50C04B41/51C04B41/87C04B41/88C22C1/10C22C29/00C22C29/02C22C29/06
    • C04B41/009C04B35/652C04B41/507C04B41/515C04B41/5155C04B41/87C04B41/88C22C1/1036C22C29/062
    • Reactive ceramic-metal compositions are described that include a ceramic phase of at least 70 percent by volume, 95 percent of theoretical density and a metal phase that retains its chemical reactivity with the ceramic phase after the composition has been fully densified. The composition may be heat treated after densification to form additional ceramic phases in a controllable manner. Preferred ceramic metal compositions wherein the metal and ceramic components retain reactivity after densification include boron carbide ceramic and Al or Mg metals. The process employed in forming said compositions requires first forming a sintered porous body of the ceramic material followed by contacting with the metal component, which may be in chip or solid bar form. The system is then heated to the melting point of the metal and a pressure of at least 200 MPa is employed such that the porous body is filled with metal and the composition is substantially fully densified. Subsequent heating reacts the metal with the ceramic to form additional B-C-metal phases as desired.
    • 描述了活性陶瓷 - 金属组合物,其包括至少70体积%,理论密度的95%的陶瓷相和在组合物完全致密化后保持其与陶瓷相的化学反应性的金属相。 组合物可以在致密化之后进行热处理,以可控的方式形成额外的陶瓷相。 其中金属和陶瓷组分在致密化后保持反应性的优选陶瓷金属组合物包括碳化硼陶瓷和Al或Mg金属。 用于形成所述组合物的方法需要首先形成陶瓷材料的烧结多孔体,然后与金属组分接触,金属组分可以是片状或固体棒形式。 然后将该系统加热到金属的熔点,并且使用至少200MPa的压力,使得多孔体填充金属并且组合物基本上完全致密化。 随后加热使金属与陶瓷反应,形成额外的B-C金属相。
    • 18. 发明授权
    • Chalcogenide-based materials and improved methods of making such materials
    • 基于硫族化物的材料和制备这种材料的改进方法
    • US08993882B2
    • 2015-03-31
    • US13047190
    • 2011-03-14
    • Jennifer E. GerbiMarc G. LangloisRobert T. Nilsson
    • Jennifer E. GerbiMarc G. LangloisRobert T. Nilsson
    • H01L31/0264H01L21/02C23C14/06C23C14/34C23C14/58
    • H01L31/0749C23C14/0623C23C14/3464C23C14/5866H01L21/02568H01L21/02614H01L21/02631
    • The present invention provides strategies for making high quality CIGS photoabsorbing materials from precursor films that incorporate a sub-stoichiometric amount of chalcogen(s). Chalcogen(s) are incorporated into the CIGS precursor film via co-sputtering with one or more other constituents of the precursor. Optional annealing also may be practiced to convert precursor into more desirable chalcopyrite crystalline form in event all or a portion of the precursor has another constitution. The resultant precursors generally are sub-stoichiometric with respect to chalcogen and have very poor electronic characteristics. The conversion of these precursors into CMS photoabsorbing material via chalcogenizing treatment occurs with dramatically reduced interfacial void content. The resultant CIGS material displays excellent adhesion to other layers in the resultant photovoltaic devices. Ga migration also is dramatically reduced, and the resultant films have optimized Ga profiles in the top or bottom portion of the film that improve the quality of photovoltaic devices made using the films.
    • 本发明提供了从含有亚化学计量量的硫族元素的前体膜制备高品质CIGS光吸收材料的策略。 通过与前体的一种或多种其它组分的共溅射将硫族化合物并入到CIGS前体膜中。 当前体的全部或一部分具有其它结构的情况下,还可以进行任选的退火以将前体转化为更理想的黄铜矿结晶形式。 所得前体通常相对于硫属元素是亚化学计量的并且具有非常差的电子特性。 通过硫属化处理将这些前体转化成CMS光吸收材料发生显着降低的界面空隙含量。 所得到的CIGS材料在所得到的光伏器件中显示出对其它层的优异粘合性。 Ga迁移也显着降低,并且所得膜在膜的顶部或底部具有优化的Ga分布,其改善了使用该膜制备的光电装置的质量。