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11. 发明授权

US06676869B2 Continuous process for indirect printing of polymeric films having texture 失效
标题翻译：用于间接印刷具有纹理的聚合物膜的连续方法
公开(公告)号：US06676869B2
公开(公告)日：2004-01-13
申请号：US10028617
申请日：2001-12-21
申请人： Brandon T. Berg , Tony B. Hollobaugh , David D. Nguyen , Bruce H. Koehler , Bruce A. Nerad
发明人： Brandon T. Berg , Tony B. Hollobaugh , David D. Nguyen , Bruce H. Koehler , Bruce A. Nerad
IPC分类号： B29C4324
CPC分类号： B41M5/0064 , B29C37/0025 , B29C43/222 , B29C47/00 , B29C47/0021 , B29C59/025 , B29C2795/005 , B41M7/0081 , Y10T428/2462
摘要： Described is a method of indirect printing on a thermoplastic film having texture, wherein said method comprises: a) providing a heated thermoplastic melt; b) providing a tool having a molding portion that comprises a texture having a surface and a plurality of cavities in said surface, and that comprises a material having a surface energy sufficient to release ink; c) applying ink to said texture; d) substantially drying or curing said ink; e) contacting said thermoplastic melt with said molding portion having ink applied to it; f) forming a texture in said thermoplastic melt, wherein said texture comprises a plurality of protrusions and an area between said protrusions, that is the inverse of the texture of said molding surface; g) transferring said ink from said molding portion to said thermoplastic melt; h) quenching said thermoplastic melt to form a thermoplastic film; and i) removing said thermoplastic film from said molding portion.
摘要翻译：描述了在具有纹理的热塑性薄膜上进行间接印刷的方法，其中所述方法包括：a）提供加热的热塑性熔体; b）提供具有模制部分的工具，所述模制部分包括在所述表面中具有表面和多个空腔的纹理，并且包括具有足以释放油墨的表面能的材料; c）将油墨施加到所述纹理; d）基本干燥或固化所述油墨; e）使所述热塑性熔体与具有施加到其上的油墨的所述模制部分接触; f）在所述热塑性熔体中形成纹理，其中所述纹理包括多个突起和所述突起之间的区域，即所述模制表面的纹理相反; g）将所述油墨从所述模制部分转移到所述热塑性熔体; h）淬火所述热塑性熔体以形成热塑性薄膜; 和i）从所述模制部分去除所述热塑性膜。

12. 发明授权

US5641426A Light modulating device having a vinyl ether-based matrix 失效
标题翻译：具有乙烯基醚基的光调制装置
公开(公告)号：US5641426A
公开(公告)日：1997-06-24
申请号：US235561
申请日：1994-04-29
申请人： Bruce A. Nerad , George F. Vesley
发明人： Bruce A. Nerad , George F. Vesley
IPC分类号： G02F1/1333 , C08F290/02 , C08J5/18 , C08L29/10 , C08L33/00 , C08L101/00 , C09K19/54 , G02F1/1334 , C09K19/52 , F21V9/00
CPC分类号： G02F1/1334 , C09K19/544
摘要： An optically responsive film that includes liquid crystal dispersed in a crosslinked polymer matrix that includes the reaction product of an isotropic polymerizable mixture that includes at least one vinyl ether.
摘要翻译：一种光学响应性膜，其包括分散在交联聚合物基质中的液晶，其包括包含至少一种乙烯基醚的各向同性的可聚合混合物的反应产物。

13. 发明授权

US5593615A Light modulating device having a matrix prepared from acid reactants 失效
标题翻译：具有由酸反应物制备的基质的光调制装置
公开(公告)号：US5593615A
公开(公告)日：1997-01-14
申请号：US484690
申请日：1995-06-07
申请人： Bruce A. Nerad , George F. Vesley
发明人： Bruce A. Nerad , George F. Vesley
IPC分类号： G02F1/1333 , C08J5/18 , C08L33/02 , C08L33/04 , C08L101/00 , C09K19/38 , C09K19/54 , C09K19/52 , G02F1/13
CPC分类号： C09K19/544
摘要： An optically responsive film that includes liquid crystal dispersed in a polymer matrix that includes the reaction product of (1) one or more polymerizable matrix reactants other than an acid reactant and (2) at least one copolymerizable acid reactant.
摘要翻译：一种光学响应性膜，其包含分散在聚合物基质中的液晶，所述液晶包括（1）除了酸反应物之外的一种或多种可聚合基质反应物和（2）至少一种可共聚的酸反应物的反应产物。

14. 发明申请

US20090218707A1 METHOD FOR MAKING PEN/PMMA MULTILAYER OPTICAL FILMS 审中-公开
标题翻译：用于制造PEN / PMMA多层光学膜的方法
公开(公告)号：US20090218707A1
公开(公告)日：2009-09-03
申请号：US12391002
申请日：2009-02-23
申请人： Carl A. Stover , Timothy J. Hebrink , Yaoqi Liu , William W. Merrill , Bruce A. Nerad , John A. Wheatley
发明人： Carl A. Stover , Timothy J. Hebrink , Yaoqi Liu , William W. Merrill , Bruce A. Nerad , John A. Wheatley
IPC分类号： B29D11/00 , B29D7/01
CPC分类号： B29C48/71 , B29C48/08 , B29C48/21 , B29C48/22 , B29C48/255 , B29C48/49 , Y10T428/24942
摘要： Methods and apparatuses are provided for the manufacture of coextruded polymeric multilayer optical films. The multilayer optical films have an ordered arrangement of layers of two or more materials having particular layer thicknesses and a prescribed layer thickness gradient throughout the multilayer optical stack. The methods and apparatuses described allow improved control over individual layer thicknesses, layer thickness gradients, indices of refraction, interlayer adhesion, and surface characteristics of the optical films. The methods and apparatuses described are useful for making interference polarizers, mirrors, and colored films that are optically effective over diverse portions of the ultraviolet, visible, and infrared spectra.
摘要翻译：提供了用于制造共挤出聚合物多层光学膜的方法和装置。所述多层光学膜具有层叠的两层或多层具有特定层厚度和规定的层厚度梯度的多层光学叠层的层序排列。所描述的方法和装置允许改进对单个层厚度，层厚度梯度，折射率，层间粘合和光学膜的表面特性的控制。所描述的方法和装置可用于制造在紫外线，可见光和红外光谱的不同部分上光学有效的干涉偏振器，反射镜和着色膜。

15. 发明授权

US07341621B2 Ink set and ink jet recording method 有权
标题翻译：油墨和喷墨记录方法
公开(公告)号：US07341621B2
公开(公告)日：2008-03-11
申请号：US11076885
申请日：2005-03-10
申请人： Bruce A. Nerad , Richard L. Rosenberg
发明人： Bruce A. Nerad , Richard L. Rosenberg
IPC分类号： C09D11/02
CPC分类号： C09D11/40 , C09D11/101
摘要： An ink set is disclosed that comprises a first ink composition containing a first colorant, and a second ink composition containing a second colorant, wherein the first colorant is different from the second colorant; wherein each ink composition, when printed at 100% fill on the same substrate, produces a color having a hue angle, h°n, and a lightness relative to that of the substrate, ΔL*n, according to: h°n=tan−1(b*n/a*n) ΔL*n=L*substrate−L*n wherein n=1 or 2 for the first and second ink compositions, respectively; h°1 and h°2 differ from each other by no more than 15°; and ΔL*1>ΔL*2. An ink jet printing method that employs the ink set is also disclosed, as well as a printed image prepared with the ink set.
摘要翻译：公开了一种油墨组，其包含含有第一着色剂的第一油墨组合物和含有第二着色剂的第二油墨组合物，其中所述第一着色剂不同于所述第二着色剂; 其中每个油墨组合物当以100％填充在相同的基底上印刷时，产生具有相对于基底的色调角的亮度的颜色，以及相对于基底的色调的亮度，ΔL* n ，根据：<？in-line-formula description =“In-line Formulas”end =“lead”？> h°n = tan < SUP>（b * / a * ）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in -line-formula description =“In-line Formulas”end =“lead”？> DeltaL * n = L *底物-L * <？in-line-formula description =“In-line formula”end =“tail”？>其中n = 1或2分别表示第一和第二墨水组合物; h°1和h 2 <2 彼此不大于15°; 和DeltaL * 1 DeltaL * 2 。还公开了采用该油墨组的喷墨打印方法，以及使用该油墨组准备的印刷图像。

16. 发明授权

US5585035A Light modulating device having a silicon-containing matrix 失效
标题翻译：具有含硅基体的光调制装置
公开(公告)号：US5585035A
公开(公告)日：1996-12-17
申请号：US103271
申请日：1993-08-06
申请人： Bruce A. Nerad , George F. Vesley
发明人： Bruce A. Nerad , George F. Vesley
IPC分类号： G02F1/1333 , C08J5/18 , C08L83/04 , C09K19/54 , C09K17/52 , G02F1/13
CPC分类号： C09K19/544 , Y10T428/1068
摘要： In one aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes siloxane linkages. The film has a transmissivity at -20.degree. C. that is substantially the same as the transmissivity at 20.degree. C. and a V.sub.90 at -20.degree. C. that is less than twice the value at 20.degree. C.In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the polymerization product of at least one mercapto-functional siloxane.In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the polymerization product of at least one multi-functional ene and at least one multi-functional silicon hydride.In another aspect, an optically responsive film in which liquid crystal is dispersed in a matrix that includes the reaction product of at least one multi-functional vinyl silane and at least one multi-functional thiol.
摘要翻译：在一个方面，其中液晶分散在包含硅氧烷键的基质中的光学响应膜。该膜在-20℃下的透射率与20℃下的透射率和-20℃的V90基本相同，小于20℃时的值的两倍。另一方面，液晶分散在包含至少一个巯基官能的硅氧烷的聚合产物的基质中的光学响应性薄膜。在另一方面，一种光学响应性膜，其中液晶分散在包含至少一种多官能烯和至少一种多官能氢化硅的聚合产物的基质中。在另一方面，一种光学响应性膜，其中液晶分散在包含至少一种多官能乙烯基硅烷和至少一种多官能硫醇的反应产物的基质中。

17. 发明授权

US4459470A Glass heating panels and method for preparing the same from architectural reflective glass 失效
标题翻译：玻璃加热板及其从建筑反光玻璃制备的方法
公开(公告)号：US4459470A
公开(公告)日：1984-07-10
申请号：US342871
申请日：1982-01-26
申请人： Paul J. Shlichta , Bruce A. Nerad
发明人： Paul J. Shlichta , Bruce A. Nerad
IPC分类号： H05B3/84 , H05B3/06
CPC分类号： H05B3/84 , H05B2203/013
摘要： Electrodes (18) are positioned in intimate contact with an outer surface of a thin electrically-insulating protecting layer (16) of architectural reflective glass (20). Application of a voltage of sufficient magnitude substantially destroys the insulating layer (16) located beneath the electrodes (18). A subsequent application of voltage results in a passage of current through the underlying thin, light-reflective metal or metal oxide layer (14) and in concomitant output of heat.
摘要翻译：电极（18）定位成与建筑反射玻璃（20）的薄的电绝缘保护层（16）的外表面紧密接触。施加足够大的电压基本上破坏位于电极（18）下方的绝缘层（16）。随后的电压施加导致电流通过下面的薄的，光反射的金属或金属氧化物层（14）和伴随的热输出。

18. 发明申请

US20090286049A1 METHODS OF APPLYING UV-CURABLE INKS TO RETROREFLECTIVE SHEETING 审中-公开
标题翻译：将紫外线固化油墨应用于回复薄膜的方法
公开(公告)号：US20090286049A1
公开(公告)日：2009-11-19
申请号：US12121170
申请日：2008-05-15
申请人： Bran W. McFarland , Bruce A. Nerad
发明人： Bran W. McFarland , Bruce A. Nerad
IPC分类号： B32B33/00 , B05B5/00
CPC分类号： B41J11/002 , Y10T428/24802
摘要： The present application relates to methods of forming a signage including a radiation curable ink. One exemplary embodiment involves heating at least a portion of a retroreflective article; applying a radiation curable ink to the heated portion of the retroreflective article; and curing the radiation curable ink. In most instances, a heated retroreflective article has a temperate that is greater than room temperature.
摘要翻译：本申请涉及形成包括可辐射固化油墨的标牌的方法。一个示例性实施例涉及加热回射制品的至少一部分; 将可辐射固化油墨施加到所述回射制品的加热部分; 并固化可辐射固化油墨。在大多数情况下，加热的回射制品具有大于室温的温度。

19. 发明授权

US06569515B2 Multilayered polymer films with recyclable or recycled layers 失效
标题翻译：具有可回收或再循环层的多层聚合物膜
公开(公告)号：US06569515B2
公开(公告)日：2003-05-27
申请号：US09006456
申请日：1998-01-13
申请人： Timothy J. Hebrink , Yaoqui Joe Liu , William W. Merrill , Bruce A. Nerad
发明人： Timothy J. Hebrink , Yaoqui Joe Liu , William W. Merrill , Bruce A. Nerad
IPC分类号： B32B702
CPC分类号： B32B27/08 , B32B7/02 , B32B27/36 , B32B2367/00 , G02B5/0841 , G02B5/305 , Y10T428/24942 , Y10T428/31507 , Y10T428/31786 , Y10T428/31797 , Y10T428/31928
摘要： A multilayered polymer film is formed with a stack of one or more first optical layers, one or more second optical layers, and one or more non-optical layers. These optical and non-optical layers are typically made using polymer materials, such as polyesters. In one embodiment, the non-optical layers are made from a polyester having a composition which corresponds to the average molar composition of the combination of all of the first and second optical layers. Using this formulation, scrap material from the manufacture of multilayered polymer films may be used to generate the non-optical layers in subsequent films. Alternatively, the non-optical layers of a multilayered polymer film are made using scrap material from prior-manufactured multilayered polymer films with the optional addition of other polymer material which may be either new or recycled.
摘要翻译：多层聚合物膜由一层或多层第一光学层，一个或多个第二光学层和一个或多个非光学层组成。这些光学和非光学层通常使用聚合物材料制成，例如聚酯。在一个实施例中，非光学层由具有对应于所有第一和第二光学层的组合的平均摩尔组成的组成的聚酯制成。使用该配方，可以使用来自制造多层聚合物膜的废料在随后的膜中产生非光学层。或者，多层聚合物膜的非光学层使用来自先前制造的多层聚合物膜的废料制备，任选地加入可以是新的或再循环的其它聚合物材料。

20. 发明授权

US06208466B1 Multilayer reflector with selective transmission 有权
标题翻译：具有选择性传输的多层反射器
公开(公告)号：US06208466B1
公开(公告)日：2001-03-27
申请号：US09199602
申请日：1998-11-25
申请人： Yaoqi Joe Liu , Bruce A. Nerad , Laurence R. Gilbert , Robert L. Brott , Michael F. Weber , Kelly M. Roscoe , John A. Wheatley
发明人： Yaoqi Joe Liu , Bruce A. Nerad , Laurence R. Gilbert , Robert L. Brott , Michael F. Weber , Kelly M. Roscoe , John A. Wheatley
IPC分类号： G02B528
CPC分类号： G02B5/0278 , G02B5/021 , G02B5/0236 , G02B5/0242 , G02B5/0252 , G02B5/0294 , G02B5/0825 , G02B5/0841 , G02B5/1861 , G02B5/305
摘要： In a multilayer dielectric reflector, treating the surface of the reflector selectively increases the amount of light transmitted through the reflector. Various surface treatments can be used to permit light to transmit through the reflector that would otherwise be reflected by the reflector. In one such reflector, different portions of the surface have different coupling efficiencies for coupling light having a high propagation angle into the multilayer reflector. Those portions having higher coupling efficiencies on each side of the reflector have a higher degree of transmission.
摘要翻译：在多层电介质反射器中，处理反射器的表面选择性地增加透过反射器的光量。可以使用各种表面处理来允许光通过反射器透射，否则反射器将被反射。在一个这样的反射器中，表面的不同部分具有不同的耦合效率，用于将具有高传播角度的光耦合到多层反射器中。在反射器的每一侧上具有较高耦合效率的部分具有较高的透射度。

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