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11. 发明申请

US20100137623A1 STABLE CATALYST PRECURSOR OF RH COMPLEX CATALYSTS 审中-公开
标题翻译： RH复合催化剂的稳定催化剂前体
公开(公告)号：US20100137623A1
公开(公告)日：2010-06-03
申请号：US12594602
申请日：2008-03-19
申请人： Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dieter Hess , Dirk Fridag
发明人： Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dieter Hess , Dirk Fridag
IPC分类号： C07C45/50 , C07F15/00 , B01J31/12
CPC分类号： C07F15/0073
摘要： The present invention relates to the preparation and use of stable catalyst precursors of rhodium complex catalysts.
摘要翻译：本发明涉及铑络合物催化剂的稳定催化剂前体的制备和应用。

12. 发明申请

US20160159718A1 MONOPHOSPHITES COMPRISING AN ANTHROL 审中-公开
标题翻译：包含ANTHROL的单磷虾
公开(公告)号：US20160159718A1
公开(公告)日：2016-06-09
申请号：US14953210
申请日：2015-11-27
申请人： Katrin Marie Dyballa , Robert Franke , Frank Geilen , Dirk Fridag , Dieter Hess , Detlef Selent , Armin Boerner
发明人： Katrin Marie Dyballa , Robert Franke , Frank Geilen , Dirk Fridag , Dieter Hess , Detlef Selent , Armin Boerner
IPC分类号： C07C45/50 , B01J31/18 , C07B41/06 , C07F9/6574 , C07F15/00
CPC分类号： C07C45/50 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07B41/06 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： Monophosphites comprising an anthrol are useful for catalyzing hydroformylation of an olefin to an aldehyde.
摘要翻译：包含蒽酮的单亚磷酸酯可用于催化烯烃向醛的加氢甲酰化。

13. 发明授权

US07495133B2 Method for hydroformylating olefins in the presence of organophosphoric compounds 失效
标题翻译：在有机磷化合物存在下加氢甲酰化烯烃的方法
公开(公告)号：US07495133B2
公开(公告)日：2009-02-24
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译：（EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃加氢甲酰化的用途。

14. 发明申请

US20070282130A1 Method for Hydroformylating Olefins in the Presence of Organophosphoric Compounds 失效
标题翻译：在有机磷化合物存在下加氢甲酰化烯烃的方法
公开(公告)号：US20070282130A1
公开(公告)日：2007-12-06
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
IPC分类号： C07F9/02 , C07C45/77
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译：（EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃的加氢甲酰基化。

15. 发明授权

US07009068B2 Phosphite compounds and the metal complexes thereof 失效
标题翻译：亚磷酸酯化合物及其金属络合物
公开(公告)号：US07009068B2
公开(公告)日：2006-03-07
申请号：US10485817
申请日：2002-08-07
申请人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
发明人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/02
CPC分类号： C07F15/0073 , B01J23/464 , B01J31/185 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65746 , C07C47/02
摘要： Phosphites of the formula I or II and their metal complexes, their preparation and the use of the phosphites as ligands in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
摘要翻译：描述了式I或II的亚磷酸酯及其金属络合物，它们的制备和在催化反应中亚磷酸酯作为配体的用途，特别是在烯烃的加氢甲酰化方法中。

16. 发明授权

US06818770B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US06818770B2
公开(公告)日：2004-11-16
申请号：US09989077
申请日：2001-11-21
申请人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
发明人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
IPC分类号： C07F928
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

17. 发明申请

US20090292146A1 CATALYST PRECURSOR FOR AN Rh COMPLEX CATALYST 审中-公开
标题翻译：催化剂前体用于Rh复合催化剂
公开(公告)号：US20090292146A1
公开(公告)日：2009-11-26
申请号：US12373921
申请日：2007-05-29
申请人： Dieter Hess , Klaus-Diether Wiese , Oliver Moeller , Dirk Fridag , Detlef Selent
发明人： Dieter Hess , Klaus-Diether Wiese , Oliver Moeller , Dirk Fridag , Detlef Selent
IPC分类号： C07C45/00 , C07F15/00 , B01J31/12
CPC分类号： B01J31/1845 , B01J31/185 , B01J2231/32 , B01J2531/822 , C07C45/50 , C07F9/65744 , C07F9/65746 , C07C47/02
摘要： The present invention relates to the preparation and use of stable catalyst precursors of rhodium complex catalysts.
摘要翻译：本发明涉及铑络合物催化剂的稳定催化剂前体的制备和应用。

18. 发明授权

US06570033B2 Bisphosphite compounds and their metal complexes 有权
标题翻译：二亚磷酸酯化合物及其金属络合物
公开(公告)号：US06570033B2
公开(公告)日：2003-05-27
申请号：US09984263
申请日：2001-10-29
申请人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
发明人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
IPC分类号： C07F908
CPC分类号： C07F9/65746 , C07C45/50 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： A bisphosphite of the formula I wherein R1, R2, R3 and R4 are each hydrogen, an aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon or heterocyclic or aliphatic-heterocyclic group having from 1 to 50 carbon atoms, F, Cl, Br, I, —CF3, —OR7, —COR7, —CO2R7, —CO2M, —SR7, —SO2R7, —SOR7, —SO3R7, —SO3M, —CO2NR7R8, NR7R8, N═CR7R8, NH2, where R1 to R4 are identical or different and may be covalently linked to one another; R7 and R8 are each hydrogen, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and may be identical or different; M is an alkali metal, alkaline earth metal, ammonium or phosphonium ion; Q is a substituted or unsubstituted divalent aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms where HO-Q-OH is a diol; W and X are each a substituted or unsubstituted aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms which may be identical or different or covalently linked to one another, provided that when the phosphite oxygens linked to W and X are each linked to an aromatic ring, then they are linked to different aromatic rings, metal complexes thereof, and a method for the hydroformylation of olefins.
摘要翻译：式I的二亚磷酸酯，其中R 1，R 2，R 3和R 4各自为氢，具有1至50个碳原子的脂族，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃或杂环或脂族杂环基，F，Cl，Br，I，-CF 3，-OR 7，-COR 7，-CO 2 R 7，-CO 2 M，-SR 7，-SO 2 R 7，-SOR 7，-SO 3 R 7，-SO 3 M，-CO 2 NR 7 R 8，NR 7 R 8，N = CR 7 R 8，NH 2，其中R 1至R 4相同或不同并且可以彼此共价连接; R 7和R 8各自为氢，具有1至25个碳原子的取代或未取代的脂族或芳族烃基，并且可以相同或不同; M 是碱金属，碱土金属，铵或鏻离子; Q是具有1至50个碳原子的取代或未取代的二价脂族，脂环族，脂族 - 脂环族，芳族，脂族 - 芳族烃，杂环或脂族杂环基团，其中 HO-Q-OH是二醇; W和X各自是取代或未取代的脂族基，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃，具有1至50个碳原子的杂环或脂族 - 杂环基，其可以相同或不同或共价连接，条件是当亚磷酸酯连接到W和X各自连接到芳香环，然后它们连接到不同的芳环，其金属络合物和烯烃的加氢甲酰化方法。

19. 发明授权

US06482992B2 Multistage process for the preparation of oxo aldehydes and/or alcohols 有权
标题翻译：用于制备羰基醛和/或醇的多步法
公开(公告)号：US06482992B2
公开(公告)日：2002-11-19
申请号：US09904893
申请日：2001-07-16
申请人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
发明人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C29/16 , C07C31/125 , C07C47/02
摘要： Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.
摘要翻译：烯烃被加氢甲酰化以在多个加氢甲酰化阶段中产生醇和/或醛，其各自包括：a）在反应器中的钴或铑催化剂存在下，碳原子含量为6至24个碳原子的烯烃加氢甲酰化到烯烃反应物转化为产物的程度为20至98％; b）从从反应器排出的所得液体中除去催化剂; c）将所得液体加氢甲酰化混合物分离成包含烯烃和链烷烃的低沸点馏分，以及包含醛和/或醇的底部馏分; 和在下列工艺阶段中存在的低沸点馏分中存在的烯烃反应，包括步骤a，b和c，并组合所有工艺步骤的工艺步骤c）的底部馏分。

20. 发明授权

US10927834B2 Method of operating a lubricating device, lubricating device and compressor with such a lubricating device 有权
公开(公告)号：US10927834B2
公开(公告)日：2021-02-23
申请号：US14644782
申请日：2015-03-11
申请人： Armin Buergy , Dieter Hess , Andreas Schoenfeld , Stefan Schuermann
发明人： Armin Buergy , Dieter Hess , Andreas Schoenfeld , Stefan Schuermann
IPC分类号： F04C15/00 , F01M1/02 , F01M1/16 , F04C11/00 , F04B49/10 , F04B49/06 , F04C2/08 , F04C14/08
摘要： A lubricant supplying device includes a feed pump that serves to pump lubricant from a lubricant reservoir to at least one lubrication point. A method for operating the lubricant supplying device includes measuring at least one operating parameter, such as temperature (T), of at least one part of a system to be lubricated and/or of the lubricant and/or of the environment. The at least one measured operating parameter (T) is supplied to a controller, where a required volumetric flow ({dot over (V)}target) of lubricant is determined based on a stored functional relationship ({dot over (V)}target=ƒ (T)) that generates the required volumetric flow ({dot over (V)}target) based upon the measured operating parameter (T). The feed pump is then actuated in order to achieve the determined, required volumetric flow ({dot over (V)}target).

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