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11. 发明授权

US5221716A Comb polymers having a halobutyl rubber backbone 失效
标题翻译：具有卤代丁基橡胶主链的梳理聚合物
公开(公告)号：US5221716A
公开(公告)日：1993-06-22
申请号：US749787
申请日：1991-08-26
申请人： George Jalics , Richard G. Bauer
发明人： George Jalics , Richard G. Bauer
IPC分类号： C08G81/02
CPC分类号： C08G81/021
摘要： The subject invention relates to comb polymers having a halobutyl rubber backbone and to techniques for synthesizing such polymers. The comb polymers of this invention can be thermoplastic elastomers. For instance, halobutyl rubbers having sidechains which are derived from vinyl aromatic monomers are thermoplastic elastomers which can be made by a technique of the subject invention. Such thermoplastic elastomers typically have a chlorobutyl rubber backbone and side chains which are comprised of polystyrene. The subject invention more specifically discloses a process for grafting a lithium terminated vinyl aromatic polymer onto a halobutyl rubber which comprises: (1) capping the lithium terminated vinyl aromatic polymer with a diene monomer to produce a lithium terminated diene capped vinyl aromatic polymer, and (2) reacting the lithium terminated diene capped vinyl aromatic polymer with the halobutyl rubber to produce a halobutyl rubber having vinyl aromatic sidechains grafted thereto.
摘要翻译：本发明涉及具有卤代丁基橡胶骨架的梳形聚合物和用于合成这种聚合物的技术。本发明的梳状聚合物可以是热塑性弹性体。例如，具有衍生自乙烯基芳族单体的侧链的卤代丁基橡胶是可通过本发明的技术制备的热塑性弹性体。这种热塑性弹性体通常具有氯丁基橡胶骨架和由聚苯乙烯组成的侧链。本发明更具体地公开了一种将锂封端的乙烯基芳族聚合物接枝到卤代丁基橡胶上的方法，其包括：（1）用二烯单体封端锂封端的乙烯基芳族聚合物以制备锂封端的二烯封端的乙烯基芳族聚合物，和 2）使锂封端的二烯封端的乙烯基芳族聚合物与卤代丁基橡胶反应，以制备接枝有乙烯基芳族侧链的卤代丁基橡胶。

12. 发明授权

US4992513A High modulus rubber composition 失效
标题翻译：高模量橡胶组合物
公开(公告)号：US4992513A
公开(公告)日：1991-02-12
申请号：US242099
申请日：1988-09-09
申请人： Richard G. Bauer , James B. Pyke , Martin P. Cohen
发明人： Richard G. Bauer , James B. Pyke , Martin P. Cohen
IPC分类号： C08L63/00 , C08G59/00 , C08G59/14 , C08G81/02
CPC分类号： C08G81/028
摘要： It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for modifying rubbers to improve their modulus without sacrificing other properties. The subject invention more specifically relates to a process for preparing a rubber composition having a high modulus which comprises reacting at least one epoxidized rubber with from about 2 phr to about 55 phr of at least one nylon at a temperature which is within the range of about 140.degree. C. to about 300.degree. C.

13. 发明授权

US4148746A Aqueous gels 失效
标题翻译：水性凝胶
公开(公告)号：US4148746A
公开(公告)日：1979-04-10
申请号：US836863
申请日：1977-09-26
申请人： Daniel F. Klemmensen , Richard G. Bauer
发明人： Daniel F. Klemmensen , Richard G. Bauer
IPC分类号： C08F220/04 , C08F220/12 , C09K8/512 , C09K8/588 , C09K8/88 , E21B33/138
CPC分类号： C09K8/887 , C08F220/04 , C08F220/12 , C09K8/512 , C09K8/588 , Y10S507/936 , Y10S524/914
摘要： There is disclosed an aqueous medium comprising water to which has been added a water thickening amount of a water thickening polymer which is prepared by polymerizing at least one alkyl acrylate monomer and at least one carboxylic polymerizable monomer selected from the group consisting of acrylic acid and methacrylic acid which are present from 20 to 95 parts by weight per hundred parts of total monomer being polymerized and utilizing, as an ionic emulsifier, an emulsifier selected from the group consisting of disodium or diammonium nonylphenoxy polyethoxy sulfosuccinate having the general formula:CH.sub.3 (CH.sub.2).sub.8 C.sub.6 H.sub.4 O(CH.sub.2 CH.sub.2 O).sub.8-16 COCH.sub.2 CH(COOM)SO.sub.3 Qwherein Q is sodium or ammonium and a sodium or ammonium lauryl polyethoxysulfate having the general formula:CH.sub.2 (CH.sub.2).sub.11 O(CH.sub.2 CH.sub.2 O).sub.8-16 SO.sub.3 Qwherein Q is sodium or ammonium, said polymer in latex form being neutralized to a pH ranging between a pH of 5.5 to 11.5. Such polymers may also be gelled with water soluble polyvalent compounds such as sodium dichromate and water soluble reducing agents such as sodium hydrosulfite. The aqueous gels are employed in enhanced oil recovery.
摘要翻译：公开了包含水的水性介质，其中加入了水增稠量的水增稠聚合物，其通过聚合至少一种丙烯酸烷基酯单体和至少一种选自丙烯酸和甲基丙烯酸酯的羧基可聚合单体制备酸，其以每100份总共单体为20至95重量份聚合并且作为离子乳化剂使用选自具有以下通式的二钠或壬基苯氧基聚乙氧基磺基琥珀酸二铵的乳化剂：

14. 发明授权

US3959550A Films prepared from PVC grafted with acrylate-nitrile mixtures 失效
标题翻译：由PVC接枝丙烯腈 - 腈混合物制备的膜
公开(公告)号：US3959550A
公开(公告)日：1976-05-25
申请号：US493356
申请日：1974-07-31
申请人： Mark S. Guillod , Richard G. Bauer
发明人： Mark S. Guillod , Richard G. Bauer
IPC分类号： C08F2/06 , C08F259/04 , C08L27/02 , C08L31/02 , C08L33/20 , C08L51/00
CPC分类号： C08F259/04
摘要： Sheeting which is flexible and tear resistant, and optionally clear and transparent, is prepared from resins prepared by grafting PVC-type polymers with a combination of an acrylic ester such as methyl acrylate and an acrylic nitrile such as acrylonitrile.
摘要翻译：通过用丙烯酸酯如丙烯酸甲酯和丙烯腈如丙烯腈的组合接枝PVC型聚合物制备的树脂制备柔性和抗撕裂性以及任选透明和透明的片材。

15. 发明授权

US5238997A Polyolefin/nylon reinforced rubber 失效
标题翻译：聚烯烃/尼龙增强橡胶
公开(公告)号：US5238997A
公开(公告)日：1993-08-24
申请号：US772299
申请日：1991-10-07
申请人： Richard G. Bauer , Joseph W. Miller, Jr.
发明人： Richard G. Bauer , Joseph W. Miller, Jr.
IPC分类号： C08K5/372 , C08L21/00
CPC分类号： C08L21/00 , C08K5/372 , C08L9/00
摘要： The present invention relates to a modified rubber composition comprising:(a) an uncured diene rubber selected from the group consisting of polybutadiene, styrene-butadiene rubber, isoprene-butadiene rubber, isoprene-butadiene-styrene rubber, nitrile rubber and carboxylated nitrile rubber;(b) from about 1 to 100 phr of a polymeric blend containing(i) from about 10 to 35 weight percent of at least one nylon,(ii) from about 65 to 90 weight percent of at least one polyolefin selected from the group consisting of polypropylene, polypropylene modified with ethylene, and ethylene/propylene copolymers, and(iii) from about 1 to about 10 weight percent of an anhydride modified polyolefin containing from 0.2 to 9% by weight of chemically combined anhydride; and(c) at least one dithio diacid having the formula HOOC--A--S--S--A--COOH wherein A represents an alkylene group containing from about 1 to 10 carbon atoms.
摘要翻译：本发明涉及一种改性橡胶组合物，其包含：（a）选自聚丁二烯，苯乙烯 - 丁二烯橡胶，异戊二烯 - 丁二烯橡胶，异戊二烯 - 丁二烯 - 苯乙烯橡胶，丁腈橡胶和羧化丁腈橡胶的未固化二烯橡胶; （b）约1至100phr的聚合物共混物，其包含（i）约10至35重量％的至少一种尼龙，（ii）约65至90重量％的至少一种选自以下的聚烯烃的聚丙烯，用乙烯改性的聚丙烯和乙烯/丙烯共聚物，和（iii）约1至约10重量％的含有0.2至9重量％化学结合的酸酐的酸酐改性聚烯烃; 和（c）至少一种具有式HOOC-A-S-S-A-COOH的二硫代二酸，其中A表示含有约1至10个碳原子的亚烷基。

16. 发明授权

US5118545A Adhesion of aramid cord to rubber 失效
标题翻译：芳纶绳对橡胶的粘合
公开(公告)号：US5118545A
公开(公告)日：1992-06-02
申请号：US489147
申请日：1990-03-05
申请人： Donald J. Burlett , Richard G. Bauer
发明人： Donald J. Burlett , Richard G. Bauer
IPC分类号： C08J5/12 , C08J5/06 , C09J5/02 , C09J177/00 , D02G3/48 , D06M13/02 , D06M13/322 , D06M13/402 , D06M13/41 , D06M13/415 , D06M15/59 , D06M15/693 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34 , D06M101/36
CPC分类号： C08J5/06 , C08J2321/00 , Y10S156/91 , Y10T428/12146 , Y10T428/1362 , Y10T428/1369 , Y10T428/249933
摘要： The present invention relates to a method of improving the adhesion between an aramid cord and sulfur vulcanized rubber comprising (a) treating the aramid cord with a copolymer of the structural formula: ##STR1## wherein w is an integer of from 1 to 100, y is an integer of from 10 to 500; z is an integer of from 1 to 120; X is: ##STR2## or mixtures thereof; B is: ##STR3## or mixtures thereof; wherein R is selected from the group consisting of H, Cl or CH.sub.3 ; and(b) vulcanizing a composite of the treated cord and rubber.

17. 发明授权

US4124546A Green strength of elastomers 失效
标题翻译：弹性体的绿色强度
公开(公告)号：US4124546A
公开(公告)日：1978-11-07
申请号：US692267
申请日：1976-06-03
申请人： Diego C. Rubio, Jr. , Richard G. Bauer , Richard M. Scriver, Jr.
发明人： Diego C. Rubio, Jr. , Richard G. Bauer , Richard M. Scriver, Jr.
IPC分类号： C08F36/04 , C08L21/00 , C08L7/00 , C08L9/00
CPC分类号： C08F36/045 , C08L21/00
摘要： Improved green strength of elastomers made from monomers selected from the class consisting of at least one conjugated diene having from 4 to 10 carbon atoms, olefins having from 2 to 14 carbon atoms along with a diene having from 4 to 6 carbon atoms, and combinations thereof, is achieved by adding an amount of a polydimethylbutadiene compound to form a blend having a glass transition temperature of from about 0.degree. C to about -100.degree. C. The polydimethylbutadiene compound may be merely the homopolymer of dimetylbutadiene, the copolymer, the terpolymer or the tetrapolymer of dimethylbutadiene in various combinations with monomers such as butadiene, isoprene, piperylene, acrylonitrile, vinylidene chloride, vinyl pyridine, methacrylic acid and vinyl substituted aromatic compounds.
摘要翻译：由选自至少一种具有4至10个碳原子的共轭二烯，具有2至14个碳原子的烯烃以及具有4至6个碳原子的二烯的单体制成的弹性体的改善的生坯强度，以及其组合通过加入一定量的聚二甲基丁二烯化合物以形成玻璃化转变温度为约0℃至约-100℃的共混物来实现。聚二甲基丁二烯化合物可以仅仅是二甲基丁二烯的均聚物，共聚物，三元共聚物或与丁二烯，异戊二烯，戊间二烯，丙烯腈，偏二氯乙烯，乙烯基吡啶，甲基丙烯酸和乙烯基取代的芳族化合物等单体的各种组合的二甲基丁二烯的四元共聚物。

18. 发明授权

US5364905A Process for the in-situ formation of reinforcing members in an elastomer and elastomer made thereby 失效
标题翻译：用于在由其制成的弹性体和弹性体中原位形成加强构件的方法
公开(公告)号：US5364905A
公开(公告)日：1994-11-15
申请号：US692338
申请日：1991-04-26
申请人： Richard G. Bauer , Donald J. Burlett , Joseph W. Miller, Jr. , Gordon R. Schorr , Pradeep M. Bapat
发明人： Richard G. Bauer , Donald J. Burlett , Joseph W. Miller, Jr. , Gordon R. Schorr , Pradeep M. Bapat
IPC分类号： C08L21/00 , C08F2/44 , C08G18/08 , C08G85/00 , C08L75/02 , C08L87/00 , C08L55/02 , C08L75/04
CPC分类号： C08G18/0895 , B29C47/6025 , B29C47/605 , B29C47/6056 , B29C47/6062 , C08L75/02
摘要： A continuous method for the in-situ polymerization of plastic in an elastomeric material in a form suitable for reinforcing the elastomeric material is provided. The method comprises feeding elastomer and a monomer or monomer precursor of a reinforcing material into a mixing device, mixing the elastomer and the monomer or monomer precursor vigorously, initiating polymerization, and causing the monomers to continue to polymerize until the polymer solidifies when the melting point of the polymer produced exceeds the mixing temperature of the elastomer, terminating polymerization.
摘要翻译：提供了一种用于以适于增强弹性体材料的形式在弹性体材料中原位聚合塑料的连续方法。该方法包括将弹性体和增强材料的单体或单体前体进料到混合装置中，强烈混合弹性体和单体或单体前体，引发聚合，并使单体继续聚合，直到聚合物在熔点所生产的聚合物超过弹性体的混合温度，终止聚合。

19. 发明授权

US5239004A Polyether ester amide-sulfur vulcanized rubber compounds 失效
标题翻译：聚醚酯酰胺 - 硫硫化橡胶化合物
公开(公告)号：US5239004A
公开(公告)日：1993-08-24
申请号：US913324
申请日：1992-07-15
申请人： James B. Pyke , Richard G. Bauer
发明人： James B. Pyke , Richard G. Bauer
IPC分类号： C08F8/34 , C08K5/372 , C08L21/00
CPC分类号： C08K5/372 , C08L21/00
摘要： This invention discloses a unique blend of polyether ester amide and sulfur vulcanized rubber having higher modulus than the rubber component without sacrificing other properties of the rubber component.
摘要翻译：本发明公开了聚醚酯酰胺和硫磺硫化橡胶的独特共混物，其具有比橡胶组分更高的模量，而不牺牲橡胶组分的其它性能。

20. 发明授权

US5225457A Reinforced polymer matrix and product containing micro and macro reinforcement 失效
标题翻译：增强聚合物基质和含微量和强化的产品
公开(公告)号：US5225457A
公开(公告)日：1993-07-06
申请号：US533318
申请日：1990-06-05
申请人： Marc Borowczak , Donald J. Burlett , Richard G. Bauer , Joseph W. Miller, Jr.
发明人： Marc Borowczak , Donald J. Burlett , Richard G. Bauer , Joseph W. Miller, Jr.
IPC分类号： B60C1/00 , B60C9/00 , C08J5/04 , C08K7/00 , C08K7/02 , C08L21/00 , C08L101/00
CPC分类号： B60C9/0042 , C08J5/047 , B29D2030/665
摘要： A method of mixing micro and macro fibers into a polymer matrix and products made thereby are provided. In the illustrated method, a micro reinforcing polymer is mixed with an elastomeric base polymer and preformed macro fibers are added thereto. In one embodiment, the micro reinforcing polymer forms micro fibers in a resulting elastomeric matrix which is interspersed with macro fibers. A base polymer matrix interspersed with micro reinforcing polymer and macro fibers made according to the invention can be used in reinforced elastomeric products such as tires.

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