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    • 11. 发明授权
    • Compact storage and shipping system for glyphosate herbicide
    • US06544930B2
    • 2003-04-08
    • US09992728
    • 2001-11-16
    • Daniel R. Wright
    • Daniel R. Wright
    • A01N5702
    • A01N57/20A01N25/30A01N25/02A01N2300/00
    • A storage and shipping system for glyphosate herbicide is provided, comprising a container having a capacity of about 0.1 to about 100,000 liters or more, substantially filled with an aqueous solution of glyphosate, predominantly in the form of one or a mixture of the potassium and monoethanolammonium salts thereof, the solution having a glyphosate acid equivalent concentration of at least about 30 percent by weight. The storage and shipping system, by virtue of the relatively high specific gravity of the glyphosate salt solution, holds a greater weight of glyphosate than a system comprising an identical container substantially filled with an aqueous solution of the isopropylammonium salt of glyphosate at the same glyphosate concentration by weight. Alternatively, the container of the storage and shipping system can be smaller than that of a container holding the same weight of glyphosate in the form of the isopropylammonium salt. Further, a larger number of such smaller containers can be shipped in a given enclosed volume, thereby enabling the shipment of a larger weight of glyphosate in a single consignment.
    • 15. 发明授权
    • Herbicide compatibility improvement
    • 除草剂兼容性改善
    • US08492309B2
    • 2013-07-23
    • US13550108
    • 2012-07-16
    • Daniel R. WrightJohn W. HemminghausDavid R. Eaton
    • Daniel R. WrightJohn W. HemminghausDavid R. Eaton
    • A01N57/00
    • A01N57/20A01N37/10A01N25/02A01N39/04
    • A process for preparing an aqueous concentrate glyphosate salt composition comprises (i) neutralizing glyphosate acid with potassium hydroxide and a minor amount of a low molecular weight organic amine in presence of water to produce a glyphosate salt solution having a pH of about 4.8 to about 5.0, where the neutralizing operation comprises a first neutralization step in which a slurry or glyphosate salt solution having a pH of about 4.4 to about 4.7 is produced and a second neutralization step in which the pH is adjusted to about 4.8 to about 5.0; and (ii) after the first neutralization step and before, during or after the second neutralization step, adding further water if necessary and optionally at least one surfactant to produce a final composition having a total glyphosate a.e. concentration not less than about 360 g/l.
    • 一种制备含水浓缩草甘膦盐组合物的方法包括(i)在水存在下用氢氧化钾和少量低分子量有机胺中和草甘膦酸,以产生pH为约4.8至约5.0的草甘膦盐溶液 其中中和操作包括第一中和步骤,其中产生pH为约4.4至约4.7的浆料或草甘膦盐溶液,以及将pH调节至约4.8至约5.0的第二中和步骤; 和(ii)在第一中和步骤之后,在第二中和步骤之前,之前或之后,如果需要,再加入水,以及任选的至少一种表面活性剂,以产生具有总草甘膦的最终组合物。 浓度不低于约360g / l。
    • 19. 发明授权
    • Highly concentrated aqueous glyphosate compositions
    • 高度浓缩的草甘膦草甘膦组合物
    • US06277788B1
    • 2001-08-21
    • US09444768
    • 1999-11-22
    • Daniel R. Wright
    • Daniel R. Wright
    • A01N5702
    • A01N57/20A01N25/30A01N25/02A01N2300/00
    • A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the monoethanolammonium salt thereof, at a concentration of about 30% to about 48% N-phosphonomethylglycine acid equivalent by weight. In a particular embodiment, a herbicidal composition comprises water; N-phosphonomethylglycine predominantly in the form of the monoethanolammonium salt thereof in solution in the water in an amount of about 360 to about 570 g a.e./l of the composition; and a surfactant component in solution or stable dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 200 g/l of the composition, this surfactant component being selected such that the composition has a cloud point not lower than about 50° C.
    • 提供了除草组合物,其包含主要以其单乙醇铵盐形式的N-膦酰基甲基甘氨酸的水溶液,其浓度为约30%至约48%重量的N-膦酰基甲基甘氨酸。 在一个具体实施方案中,除草组合物包含水; N-膦酰基甲基甘氨酸主要以其单水乙醇铵盐的形式在水中的溶液中的量为组合物约360至约570g a.e./l; 和在水中的溶液或稳定分散体中的表面活性剂组分,其包含一种或多种总量为组合物约20至约200g / l的表面活性剂,该表面活性剂组分被选择为使得组合物的浊点不低于 比约50℃