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11. 发明申请

WO2005068532A1 PROCESS FOR PREPARING A HIGH MOLECULAR POLYCONDENSATE 审中-公开
标题翻译：制备高分子量聚碳酸酯的方法
公开(公告)号：WO2005068532A1
公开(公告)日：2005-07-28
申请号：PCT/EP2004/014886
申请日：2004-12-29
申请人： DSM IP ASSETS B.V. , LOONTJENS, Jacobus, Antonius , SCHOLTENS, Boudewijn, Jan, Robert
发明人： LOONTJENS, Jacobus, Antonius , SCHOLTENS, Boudewijn, Jan, Robert
IPC分类号： C08G63/91
CPC分类号： C08G69/04 , C08G63/91 , C08G64/42 , C08G69/28 , C08G69/44 , C08G69/48
摘要： The invention relates to a process for preparing a high-molecular polycondensate, i.e. a polyester, a polyamide, a polyester-amide, a polycarbonate, a polyether or a block copolymer by melt-mixing a polyester, a polyamide, a polycarbonate, a polyether or a mixture of at least two of these said polycondensates with a carbonyl bislactam according to formula (I) in which formula n is an integer of between 3 and 15, and a diepoxide. Preferably said diepoxide is a compound containing epoxy radicals of formula (II), which radicals are linked direct to carbon, oxygen, nitrogen or sulfur atoms, wherein R 1 and R 3 are both hydrogen, R 2 is hydrogen or methyl, and m=0, or wherein R 1 and R 3 , taken together, are - CH 2 -CH 2 - or -CH 2 -CH 2 -CH 2 -, in which case R 2 is hydrogen and m=0 or 1. The present invention results in a more stable process for the production of a polycondensate with a high molecular mass. Furthermore the polycondensate obtained with the process according to the invention has, even under extreme process conditions such as high temperature, less discoloration. With the process according to the invention a permanent increase in the molecular weight of a polycondensate is obtained in an even faster way than with processes according to the state of the art.
摘要翻译：本发明涉及通过熔融混合聚酯，聚酰胺，聚碳酸酯，聚醚等制备高分子缩聚物，即聚酯，聚酰胺，聚酯 - 酰胺，聚碳酸酯，聚醚或嵌段共聚物的方法或这些所述缩聚物中的至少两种与根据式（I）的羰基双内酰胺的混合物，其中式n为3至15的整数，和二环氧化物。优选地，所述二环氧化物是含有式（II）的环氧基的化合物，其基团直接连接到碳，氧，氮或硫原子上，其中R 1和R 3都是氢，R 2是氢或甲基，m = 0，或其中R 1和R 3一起是-CH 2 -CH 2 - 或-CH 2 -CH 2 -CH 2 - ，在这种情况下，R 2是氢并且m = 0或1.本发明导致更稳定的具有高分子量的缩聚物。此外，通过本发明的方法获得的缩聚物即使在极端的工艺条件下，例如高温，较少变色。通过根据本发明的方法，以比根据现有技术的方法更快的方式获得缩聚物的分子量的永久增加。

12. 发明申请

WO2004020501A1 PROCESS FOR PREPARING BIOCOMPATIBLE POLYUREA 审中-公开
标题翻译：制备生物降解聚氨酯的方法
公开(公告)号：WO2004020501A1
公开(公告)日：2004-03-11
申请号：PCT/NL2003/000567
申请日：2003-08-07
申请人： DSM IP ASSETS B.V. , MÜLHAUPT, Rolf , LOONTJENS, Jacobus, Antonius , MAIER, Steffen , ZIMMERMANN, Jörg
发明人： MÜLHAUPT, Rolf , LOONTJENS, Jacobus, Antonius , MAIER, Steffen , ZIMMERMANN, Jörg
IPC分类号： C08G71/02
CPC分类号： C08G71/02
摘要： A process is provided for preparing urea-containing polymers by contacting a hydroxy-functional organic compound having a functionality of two or more, with a coupling agent in the presence of a strong base, wherein the coupling agent is a carbonylbislactam compound having the general formula (I): wherein n is an integer from 3 to 15, and that the contacting is conducted at a temperature between 0°C and 80°C. The polymers thus obtained are believed to be new and are useful e.g. in tissue engineering and coatings applications.
摘要翻译：提供了一种制备含尿素聚合物的方法，其通过使具有两个或多个官能度的羟基官能的有机化合物与强碱的存在下与偶联剂接触，其中偶联剂是具有通式的羰基双内酰胺化合物（I）：其中n为3至15的整数，并且接触在0℃和80℃之间的温度下进行。由此获得的聚合物被认为是新的并且可用于例如在组织工程和涂料应用中。

13. 发明公开

EP1263808A1 THERMOSETTING COMPOSITION 审中-公开
标题翻译：热固性组合物
公开(公告)号：EP1263808A1
公开(公告)日：2002-12-11
申请号：EP01917967.0
申请日：2001-03-09
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , VAN BENTHEM, Rudolfus, Antonius, Theodorus, Maria , PLUM, Bartholomeus, Johannes, Margretha , RIETBERG, Johan
IPC分类号： C08F8/30 , C08K5/34 , C08G63/91 , C09D167/02
CPC分类号： C08G63/914
摘要： The invention is related to a thermosetting composition containing a functional resin with -OH or -NH2 groups, a functionality of more than 2, and a crosslinking agent, wherein the crosslinking agent is a carbonylbislactamate. The composition preferably contains also an acid or a base as a catalyst. The invention further relates to the use of a carbonylbislactamate for curing of a functional resin with -OH or -NH2 groups and a functionality of more than 2.

14. 发明公开

EP1196480A1 PROCESS FOR THE PRODUCTION OF A POLYOLEFIN-BASED COMPOSITE MATERIAL OF HIGH RIGIDITY 有权
标题翻译：工艺生产具有高强度的聚烯烃
公开(公告)号：EP1196480A1
公开(公告)日：2002-04-17
申请号：EP00946524.6
申请日：2000-07-03
申请人： DSM N.V.
发明人： LANGEREIS, Sander , LOONTJENS, Jacobus, Antonius
IPC分类号： C08J3/20 , C08K9/04 , C08L23/02 , C08F2/44 , C01B33/38
CPC分类号： C08K9/04 , C08L23/02
摘要： The invention relates to a process for the production of a polyolefin-based composite material of high rigidity, containing a polyolefin and a layered clay, by impregnating a layered, swellable clay which is interstratified with a tetraalkyl cation, with at least one polymerizable monomer and then mixing this impregnated clay with a polyolefin and a peroxide, at a temperature above the melting point of the polyolefin. The invention also relates to a polyolefin-based composite material of high rigidity containing 98-50 wt.% of a polyolefin, 1-50 wt.% of another homo- or copolymer and 1-50 wt.% of a layered clay, wherein the ratio between the modulus of elasticity of the material and that of the initial polyolefine, at a temperature which is 30 °C below the melting temperature of the polyolefin, is higher than or equal to 1.

15. 发明公开

EP1263863A2 PROCESS FOR PREPARING A BRANCHED POLYMER 有权
标题翻译：用于生产支化聚合物
公开(公告)号：EP1263863A2
公开(公告)日：2002-12-11
申请号：EP01915911.0
申请日：2001-03-09
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , PLUM, Bartholomeus, Johannes, Margretha
IPC分类号： C08K5/35 , C08G69/48 , C08G69/20 , C08G63/91
CPC分类号： C08G63/916 , C08G18/8074 , C08G69/04 , C08G69/16 , C08G69/28 , C08G69/48 , C08G2150/20
摘要： The invention relates to a process for preparing a branched polymer by contacting a monofunctional or difunctional polymer whose functional group is at least an -OH or an -NH2 group with a multifunctional compound RYn, where n > 2 and Y is an -OH group, an -NHm group where m=1,2 or a -COOH group and R is an alkyl, an aryl group or a cyclic group and in which the Y groups need not be the same and in which carbonyl bislactamate is also present.

16. 发明公开

EP1194420A1 PREPARATION OF AN AROMATIC BISOXAZOLINE 审中-公开
标题翻译：制备芳香二恶唑啉
公开(公告)号：EP1194420A1
公开(公告)日：2002-04-10
申请号：EP00944463.9
申请日：2000-06-27
申请人： DSM N.V.
发明人： VAN BENTHEM, Rudolfus, Antonius, Theodorus, Maria , LOONTJENS, Jacobus, Antonius , HENDRIKS, Patrick, Herman, Marie , PLUM, Bartholomeus, Johannes, Magretha
IPC分类号： C07D263/10 , C07C233/69 , C08K5/353 , C09D5/03 , C07D263/14
CPC分类号： C09D5/033 , C07D263/10 , C07D263/14
摘要： The invention relates to a process for the preparation of an aromatic bisoxazoline in which, in a first step, an aromatic carboxylic acid or an ester hereof reacts with an alkanolamine, after which the hydroxyalkylamide obtained is in a second step converted into an aromatic bisoxazoline in the presence of a catalyst. The catalyst is phosphinic acid, a (C1-C26) alkyl phosphinic acid, a (C6-C20) aryl phosphinic acid or an ester or an anhydride derived from one of these acids.

17. 发明公开

EP1021422A1 INITIATOR FOR CATIONIC POLYMERIZATION, A PROCESS FOR ITS PREPARATION, USES AND A POLYMER THAT CAN BE OBTAINED USING THE INITIATOR 失效
标题翻译：引发剂阳离子聚合方法所周之，用途以及使用所INIATIATORS HERGESTELTES聚合物
公开(公告)号：EP1021422A1
公开(公告)日：2000-07-26
申请号：EP97943222.6
申请日：1997-10-07
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , DERKS, Franciscus, Johannes, Marie
IPC分类号： C07D251/70
CPC分类号： C07D251/70 , C08F16/12 , C08G65/2621
摘要： The invention relates to Xn(alkoxy)(6-n)alkyl melamine, in which X = halide, n = 1-6, and the alkoxy group and the alkyl group contain 1 to 6 carbon atoms, a process for the preparation of these compounds and the use of these compounds as initiator in a cationic polymerization of monomers to form a polymer. The invention also relates to the polymer obtained with this initiator and to the use of the resulting polymer as impact modifier in melamine, phenol or urea containing resins.

18. 发明公开

EP0835276A1 HIGH-MOLECULAR POLYAMIDE 失效
标题翻译：高分子量的聚酰胺
公开(公告)号：EP0835276A1
公开(公告)日：1998-04-15
申请号：EP96911108.0
申请日：1996-04-18
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , DERKS, Franciscus, Johannes, Marie , SHAM, Chi, Keung
IPC分类号： C08G69 , C08K5
CPC分类号： C08K5/353 , C08G69/44 , C08G69/48 , C08K5/357 , C08L77/00
摘要： The invention relates to a process for the preparation of a high-molecular polyamide by adding a bislactam and a bisoxazoline or bisoxazine to the melt of a polyamide of a lower molecular weight. An increased and very stable melt viscosity is obtained. The invention also covers a polyamide composition which comprises both bislactam and bisoxazoline or bisoxazine.

19. 发明公开

EP1476478A1 PROCESS FOR THE PREPARATION OF A FUNCTIONALIZED POLYMERS AND INTERMEDIATE PRODUCTS, COMPOSITIONS AND SHAPED PARTS 有权
标题翻译：用于生产官能化聚合物及其中间体，组合物和线条
公开(公告)号：EP1476478A1
公开(公告)日：2004-11-17
申请号：EP03742683.0
申请日：2003-02-20
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , PLUM, Bartholomeus, Johannes, Margretha , VAN GEENEN, Albert, Arnold , MING, Weihua
IPC分类号： C08F8/30 , C08C19/30 , C08G85/00
CPC分类号： C08C19/30 , C08F8/30 , C08G85/004 , Y10T428/31551
摘要： Process for the preparation of a functionalized polymer containing an additive, in which process there is formed a compound that contains, besides at least one blocked isocyanate group, a free amino, hydroxy or carboxy group; this compound is linked to an additive via the free amino, hydroxy or carboxy group in the additive; this additive linked to the compound mentioned is contacted with a polymer that contains at least one free amino or hydroxyl group, at a temperature above the polymer's melting point and at least above (150) °C, such that the blocked isocyanate group reacts with the free amino or hydroxy group of the polymer to form the functionalized polymer. The invention also relates to the intermediate products formed in the process and in the preparation thereof. Lastly, the invention relates to functionalized polymers and polymer compositions containing the functionalized polymer.

20. 发明授权

EP0835276B1 HIGH-MOLECULAR POLYAMIDE 失效
标题翻译：高分子量的聚酰胺
公开(公告)号：EP0835276B1
公开(公告)日：1999-07-28
申请号：EP96911108.7
申请日：1996-04-18
申请人： DSM N.V.
发明人： LOONTJENS, Jacobus, Antonius , DERKS, Franciscus, Johannes, Marie , SHAM, Chi, Keung
IPC分类号： C08G69/48 , C08G69/44 , C08K5/353 , C08K5/357
CPC分类号： C08K5/353 , C08G69/44 , C08G69/48 , C08K5/357 , C08L77/00
摘要： The invention relates to a process for the preparation of a high-molecular polyamide by adding a bislactam and a bisoxazoline or bisoxazine to the melt of a polyamide of a lower molecular weight. An increased and very stable melt viscosity is obtained. The invention also covers a polyamide composition which comprises both bislactam and bisoxazoline or bisoxazine.

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