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11. 发明申请

WO2017019677A1 EPOXY THERMOSET MATERIALS AND THE USE THEREOF 审中-公开
标题翻译：环氧热固性材料及其用途
公开(公告)号：WO2017019677A1
公开(公告)日：2017-02-02
申请号：PCT/US2016/044027
申请日：2016-07-26
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： MEHTA, Rujul M. , GUPTA, Pankaj , HOLLEY, Whitney , LATHAM, Dwight D. , VYAKARANAM, Kamesh R.
IPC分类号： C08G59/06 , C08G59/22 , F16L59/14
CPC分类号： C08G59/066 , C08G59/223 , C08G59/226 , C08G2650/50
摘要： Thermoset compositions are disclosed. Such thermosets are the reaction product of (a) an ambient temperature liquid epoxy-terminated prepolymer formed by reacting a polyoxyalkyleneamine having a molecular weight of from 3000 to 20,000 with an excess of epoxide, wherein the polyoxyalkyleneamine has at least 3 active hydrogen atoms, (b) a low viscosity second epoxy, (c) optionally a filler, and (d) a curing agent comprising at least one amine or polyamine having an equivalent weight of less than 200 and having 2 to 5 active hydrogen atoms. Such thermosets can be used in applications such as for sealants, adhesives, coatings, gaskets, jointing and castings.
摘要翻译：公开了热固性组合物。这种热固性物质是（a）通过使分子量为3000至20,000的聚氧亚烷基胺与过量的环氧化物反应而形成的环境温度的液体环氧封端的预聚物的反应产物，其中聚氧化烯胺具有至少3个活性氢原子（ b）低粘度第二环氧树脂，（c）任选的填料，和（d）包含至少一种当量重量小于200且具有2-5个活性氢原子的胺或多胺的固化剂。这种热固性材料可用于诸如密封剂，粘合剂，涂料，垫圈，接合和铸件的应用中。

12. 发明授权

EP3274158B1 METHOD FOR INSULATING COMPLEX SUBSEA STRUCTURES 有权
公开(公告)号：EP3274158B1
公开(公告)日：2019-06-19
申请号：EP16715397.2
申请日：2016-03-18
申请人： Dow Global Technologies LLC
发明人： FENG, Jie , BROWN, Mark W. , CHEN, Xue , GUPTA, Pankaj , LATHAM, Dwight D. , MA, Liangkai , MALANGA, Michael T. , MEHTA, Rujul M. , VYAKARANAM, Kamesh R. , WENZEL, Jeffrey D. , ZAWISZA, Jeffery D.
IPC分类号： B29C67/24 , B29C45/14 , F16L58/10 , F16L59/14 , F16L59/16 , B29C39/10 , B29L23/00 , B29C39/32 , B29C45/00

13. 发明公开

EP2760913A1 IMPROVING COMPRESSION SET PROPERTY IN SILYLATED POLYMERS 审中-公开
标题翻译：提高压缩性能的硅烷化聚合物
公开(公告)号：EP2760913A1
公开(公告)日：2014-08-06
申请号：EP12769550.0
申请日：2012-09-17
申请人： Dow Global Technologies LLC
发明人： VYAKARANAM, Kamesh R. , Zhang, Ling , MINNIKANTI, Venkat S. , LATHAM, Dwight D. , ARSHAD, Sara , DUGGAL, Rajat , KOONCE, William A.
IPC分类号： C08G65/336 , C08L101/10 , C08L71/00
CPC分类号： C08L71/00 , C08G65/336 , C08K5/0025 , C08L71/02 , C08L75/04 , C08L75/08 , C08L83/00 , C08L83/06 , C08L101/10
摘要： Moisture curable compositions including silylated polymers and methods for producing the same are provided. A two component moisture curable system for producing a cured or cross-linked silylated polymer having improved compression set properties is provided. The two component system comprises a first formulation and a second formulation. The first formulation comprises a silylated polymer, water, and filler and the second formulation comprises the silylated polymer, a curing catalyst comprising at least one Brønsted acid, and a moisture scavenger. The final cured formulation may have a compression set, determined by ASTM D395 or ISO 815-1, of less than 100%, and in some examples less than 50% and in some examples less than 15%. This demonstrated improvement in compression set not only allows the silylated polymers to be used in applications where cyclic loads are applied but also enhances product durability.

14. 发明公开

EP3274158A1 METHOD FOR INSULATING COMPLEX SUBSEA STRUCTURES 审中-公开
标题翻译：用于绝缘复杂海底结构的方法
公开(公告)号：EP3274158A1
公开(公告)日：2018-01-31
申请号：EP16715397.2
申请日：2016-03-18
申请人： Dow Global Technologies LLC
发明人： FENG, Jie , BROWN, Mark W. , CHEN, Xue , GUPTA, Pankaj , LATHAM, Dwight D. , MA, Liangkai , MALANGA, Michael T. , MEHTA, Rujul M. , VYAKARANAM, Kamesh R. , WENZEL, Jeffrey D. , ZAWISZA, Jeffery D.
IPC分类号： B29C67/24 , B29C45/14 , F16L58/10 , F16L59/14 , F16L59/16
CPC分类号： B29C39/32 , B29C39/10 , B29C45/0001 , B29C45/14622 , B29L2023/225 , F16L59/161 , F16L59/163
摘要： The present invention relates to a process to reduce internal stresses in insulation molded onto complex pipes, preferably complex subsea pipe, to reduce cracking in the molded insulation. Insulation materials applies to complex pipes comprising branches, i.e., valves, and the like, may be susceptible to cracking at, or near where the branch connects to the pipe as the coating of insulation material cures or hardens. The process of the present invention aims to reduce post molded cracking by reducing molded in stress at the branch/pipe junction. This is accomplished by providing a preform at or near a branch/pipe junction prior to applying the coating of insulation material.

15. 发明公开

EP3233437A1 PROCESS FOR PRODUCING A COMPOSITE ARTICLE 审中-公开
标题翻译：生产复合制品的方法
公开(公告)号：EP3233437A1
公开(公告)日：2017-10-25
申请号：EP15819913.3
申请日：2015-11-24
申请人： Dow Global Technologies LLC
发明人： SHAFI, Asjad , KARUNAKARAN, Krishnan , VYAKARANAM, Kamesh R.
IPC分类号： B29C70/32 , C08J5/24 , B29C53/56
CPC分类号： C08J5/04 , B29C53/58 , B29C2035/0827 , B29D23/001 , C08J3/243 , C08J2363/10
摘要： A multistage filament winding process for manufacturing a composite article using a dual chemistry formulation including the steps of (a) providing a dual chemistry formulation containing components to effectuate dual cure of the formulation; (b) winding fibers on a liner or on a mandrel; (c) impregnating the wound fibers of step (b) with the dual chemistry formulation; (d) activating a first reaction (A) by UV or thermal-free radical initiation sufficient to form first macroscopic gels and to allow the first macroscopic gels to phase separate from the remaining substantially unreacted components in the formulation; (e) optionally, activating a second reaction by heating through IR lamps or other heating apparatus and controlling the second reaction sufficient to form second macroscopic gels subsequent to the formation of the first macroscopic gels which have gelled and phase separated in the formulation; (f) repeating steps (a)-(d) until a composite article having a predetermined thickness is formed; and (g) heating the formed composite article of step (f) sufficient to form a final composite article product having a predetermined glass transition temperature; a cured thermoset article prepared by the above process; and a process for manufacturing spoolable pipe.
摘要翻译：一种使用双重化学配方制造复合制品的多级纤维缠绕工艺，包括以下步骤：（a）提供含有组分的双重化学配方以实现配方的双重固化; （b）将纤维缠绕在衬垫上或心轴上; （c）用双重化学配方浸渍步骤（b）的卷绕纤维; （d）通过UV或无热自由基引发活化第一反应（A），足以形成第一宏观凝胶并使第一宏观凝胶与制剂中剩余的基本上未反应的组分相分离; （e）任选地，通过经IR灯或其他加热设备加热来激活第二反应，并且在形成已在配方中凝胶化和相分离的第一宏观凝胶之后控制第二反应足以形成第二宏观凝胶; （f）重复步骤（a） - （d）直到形成具有预定厚度的复合制品; 和（g）加热步骤（f）形成的复合制品足以形成具有预定玻璃化转变温度的最终复合制品产品; 通过上述方法制备的固化热固性制品; 和一种制造缠绕管的方法。

16. 发明授权

EP3041878B1 COATING COMPOSITION 有权
标题翻译：涂料组合物
公开(公告)号：EP3041878B1
公开(公告)日：2017-08-30
申请号：EP14780653.3
申请日：2014-09-04
申请人： Dow Global Technologies LLC
发明人： MINNIKANTI, Venkat S. , PFARHERR, Marcus , MICHALSKI, Eva-Maria , VYAKARANAM, Kamesh R. , HEATH, William H. , CHANG, Kwanho , TURAKHIA, Rajesh H. , FALSARELLA, Larissa , COLSON, Adam C.
IPC分类号： C08G59/06 , C08G59/50 , C09D163/00
CPC分类号： C09D163/00 , C08G59/066 , C08G59/50 , E04C2/24 , E04C2/26 , E04C2/50 , C08L63/00 , C08L75/16

17. 发明公开

EP2726524A1 SILANE TERMINATED POLYMER FOR COATING, ADHESIVES, SEALANT AND ELASTOMER APPLICATIONS 有权
标题翻译：硅烷聚合物涂料，粘合剂，密封剂和弹性体应用
公开(公告)号：EP2726524A1
公开(公告)日：2014-05-07
申请号：EP12730105.9
申请日：2012-06-14
申请人： Dow Global Technologies LLC
发明人： VYAKARANAM, Kamesh R. , KOONCE, William A. , ZHANG, Ling , ROSER, Jean-Luc
IPC分类号： C08G18/10 , C08G18/28 , C08G18/63 , C08G18/71 , C08G18/76
CPC分类号： C08G81/025 , C08G18/10 , C08G18/289 , C08G18/632 , C08G18/718 , C08G18/7621 , C08G18/63
摘要： A copolymer-filled crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule is provided. The copolymer-filled crosslinkable silane-terminated polymer is the reaction product of a copolymer-filled polyol and an isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer is the reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer is the reaction product of a polymer having at least one unsaturated group and at least one alcoholic group in each molecule and a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule. The copolymer-filled crosslinkable silane-terminated polymers exhibit improved modulus and tensile strength properties while maintaining elongation properties.

18. 发明公开

EP3041878A1 COATING COMPOSITION 有权
标题翻译： BESCHICHTUNGSZUSAMMENSETZUNG
公开(公告)号：EP3041878A1
公开(公告)日：2016-07-13
申请号：EP14780653.3
申请日：2014-09-04
申请人： Dow Global Technologies LLC
发明人： MINNIKANTI, Venkat S. , PFARHERR, Marcus , MICHALSKI, Eva-Maria , VYAKARANAM, Kamesh R. , HEATH, William H. , CHANG, Kwanho , TURAKHIA, Rajesh H. , FALSARELLA, Larissa , COLSON, Adam C.
IPC分类号： C08G59/06 , C08G59/50 , C09D163/00
CPC分类号： C09D163/00 , C08G59/066 , C08G59/50 , E04C2/24 , E04C2/26 , E04C2/50 , C08L63/00 , C08L75/16
摘要： A flooring coating composition includes a coating agent that is a reaction product of an epoxy based formulation, the epoxy based formulation being at least one of an epoxy prepolymer formulation, an epoxy-silane hybrid formulation, and an epoxy thiol acrylate formulation. The coating agent in a cured state exhibits a first tan delta peak between a first temperature range of 75 C to 0 C and a second tan delta peak between a second temperature range of 20 C and 75 C, according to a tan delta plot over a range of temperatures. A value of the first tan delta peak and a value of the second tan delta peak each represents a ratio of a loss modulus of the coating agent and a storage modulus of the coating agent at a specific temperature within the range of temperatures, as measured according to dynamic mechanical thermal analysis. The values of the first and the second tan delta peaks are from 0.10 to 0.80.
摘要翻译：地板涂料组合物包括作为环氧基配方的反应产物的涂层剂，环氧基配方为环氧预聚物配方，环氧硅烷混合配方和环氧硫醇丙烯酸酯配方中的至少一种。处于固化状态的涂层剂在75℃至0℃的第一温度范围和20℃至75℃的第二温度范围内的第二tanδ峰之间显示第一tanδ峰，根据温度范围第一tanδ峰的值和第二tanδ峰的值各自表示涂布剂的损耗模量与涂布剂在特定温度下在温度范围内的储能模量的比例，如根据进行动态机械热分析。第一和第二tanδ峰的值为0.10至0.80。

19. 发明授权

EP2726524B1 SILANE TERMINATED POLYMER FOR COATING, ADHESIVES, SEALANT AND ELASTOMER APPLICATIONS 有权
标题翻译：硅烷聚合物涂料，粘合剂，密封剂和弹性体应用
公开(公告)号：EP2726524B1
公开(公告)日：2015-07-22
申请号：EP12730105.9
申请日：2012-06-14
申请人： Dow Global Technologies LLC
发明人： VYAKARANAM, Kamesh R. , KOONCE, William A. , ZHANG, Ling , ROSER, Jean-Luc
IPC分类号： C08G18/10 , C08G18/28 , C08G18/63 , C08G18/71 , C08G18/76
CPC分类号： C08G81/025 , C08G18/10 , C08G18/289 , C08G18/632 , C08G18/718 , C08G18/7621 , C08G18/63

20. 发明公开

EP2726525A1 IMPROVED PROCESS FOR MAKING LOW VISCOSITY, FAST CURING SILANE TERMINATED POLYMERS 有权
标题翻译：用于生产低粘度，快速固化的硅烷封端的聚合物
公开(公告)号：EP2726525A1
公开(公告)日：2014-05-07
申请号：EP12730328.7
申请日：2012-06-14
申请人： Dow Global Technologies LLC
发明人： VYAKARANAM, Kamesh R. , ZHANG, Ling , MINNIKANTI, Venkat S. , DUGGAL, Rajat , KOONCE, William A. , SINGH, Amarnath , ATHEY, Phillip S.
IPC分类号： C08G18/10 , C08G18/28 , C08G18/71 , C08G18/76
CPC分类号： C08G18/10 , C08G18/289 , C08G18/718 , C08G18/7621 , C08G2190/00 , C08G18/4825 , C08G18/4829
摘要： Methods of producing a composition comprising a crosslinkable silane-terminated polymer having at least one crosslinkable silyl group in each molecule are provided. The method may comprise providing a polymer having at least one unsaturated group and at least one alcohol hydroxyl group in each molecule and having a number average molecular weight between about 100 and about 5,000, adding to the polymer a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule and a hydrosilylation catalyst to thereby carry out a hydrosilylation reaction to form a composition comprising hydrosilylated polymers, wherein the hydrosilylation reaction has a hydrosilylation efficiency greater than 50% as determined by 1H-NMR, capping the hydrosilylated polymers by adding the hydrosilylated polymer to at least one isocyanate at an index of between about 100 and about 250, and reacting the isocyanate capped hydrosilylated polymer with a polyol having a nominal functionality of at least 2 to form the composition comprising a crosslinkable silane-terminated polymer.

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