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    • 17. 发明申请
    • NAPHTHALENE BASED EPOXY FOR HALOGEN-FREE AND FLAME RETARDANT COMPOSITIONS
    • 用于无卤素和阻燃组合物的基于萘基的环氧化合物
    • WO2016029452A1
    • 2016-03-03
    • PCT/CN2014/085580
    • 2014-08-29
    • BLUE CUBE IP LLCSONG, XiaomeiCHEN, HongyuMULLINS, Michael J.LU, Fujun
    • SONG, XiaomeiCHEN, HongyuMULLINS, Michael J.LU, Fujun
    • C08L63/00B32B15/14B32B15/092
    • C08G59/22C08G59/4071
    • A curable composition comprising, consisting of, or consisting essentially of a) an epoxy component comprising a dinaphthalene epoxy having the structure (X) wherein each R 1 group is independently a C1-C20 hydrocarbon; a is an integer in the range of from 0 to 6; m is an integer in the range of 0 to 5; and b) a hardener component comprising i) a naphthol novolac which is a reaction product of I) from 1 to 99 weight percent 1-naphthol and II) from 1 to 99 weight percent 2-naphthol; ii) a phosphorus-containing composition which is the reaction product of an etherified resole with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide; and iii) optionally a phenolic resin selected from the group consisting of a molecule having at least one substituted or unsubstituted naphthalene ring, a high functionality phenolic resin, and combinations thereof, is disclosed. The curable composition can be used to prepare prepregs and electrical laminates.
    • 一种可固化组合物,其包含由以下组成或基本上由a组成的环氧组分,该环氧组分包含具有结构(X)的二萘环氧化物,其中每个R 1基团独立地为C 1 -C 20烃; a为0〜6的整数; m为0〜5的整数; 和b)硬化剂组分,其包含i)萘酚酚醛清漆,其为I)1至99重量%的1-萘酚和II)1至99重量%的2-萘酚的反应产物; ii)含醚组合物,其为醚化甲阶酚醛与9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物的反应产物; 和iii)任选地,选自具有至少一个取代或未取代的萘环的分子,高官能度酚醛树脂及其组合的酚醛树脂。 可固化组合物可用于制备预浸料和电层压材料。
    • 18. 发明申请
    • HALOGEN-FREE AND FLAME RETARDANT COMPOSITIONS WITH LOW THERMAL EXPANSION FOR HIGH DENSITY PRINTED WIRING BOARDS
    • 低密度印刷布线板的低热膨胀的无卤素和阻燃组合物
    • WO2016029453A1
    • 2016-03-03
    • PCT/CN2014/085581
    • 2014-08-29
    • BLUE CUBE IP LLCSONG, XiaomeiCHEN, HongyuMULLINS, Michael J.
    • SONG, XiaomeiCHEN, HongyuMULLINS, Michael J.
    • C08L63/00B32B15/092
    • C08L63/04B32B15/092C08G59/24C08G59/245C08G59/3218C08G59/621C08L61/14C08L63/00
    • A multifunctional naphthol-based epoxy resin composition which is a reaction product of a) a naphthol which is a reaction product of i) from 1 to 99 weight percent 1-naphthol and ii) from 1 to 99 weight percent 2-naphthol; and b) an epihalohydrin, is disclosed. Also disclosed is a curable composition comprising: a) an epoxy component comprising the multifunctional naphthol-based epoxy resin composition; and b) a hardener component comprising i) a phenolic resin component selected from the group consisting of phenol novolac resins, triphenolalkane phenolic resins, aralkyl phenolic resins, biphenyl phenolic resin, biphenyl aralkyl phenolic resins, substituted naphthalene phenolic resins unsubstituted naphthalene phenolic resins, and combinations thereof; and ii) a phosphorus-containing composition which is the reaction product of an etherified resole with 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The curable composition can be used to prepare prepregs, electrical laminates, printed circuit boards, and printed wiring boards.
    • 一种多官能萘酚系环氧树脂组合物,其为a)萘酚,其为i)1〜99重量%的1-萘酚和ii)1〜99重量%的2-萘酚的反应产物; 和b)表卤代醇。 还公开了一种可固化组合物,其包含:a)包含多官能萘酚基环氧树脂组合物的环氧组分; 和b)硬化剂组分,其包含i)选自苯酚酚醛清漆树脂,三酚烷烃酚醛树脂,芳烷基酚醛树脂,联苯酚醛树脂,联苯芳烷基酚醛树脂,取代萘酚醛树脂,未取代的萘酚醛树脂的酚醛树脂组分和 其组合; 和ii)作为醚化的甲阶酚醛与9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO)的反应产物的含磷组合物。 可固化组合物可用于制备预浸料,电层压板,印刷电路板和印刷线路板。