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    • 13. 发明申请
    • CURABLE SILICONE COMPOSITION THAT PROVIDES A HIGHLY TRANSPARENT CURED SILICONE MATERIAL
    • 提供高度透明的固化硅材料的可固化硅胶组合物
    • WO2010087522A1
    • 2010-08-05
    • PCT/JP2010/051660
    • 2010-01-29
    • DOW CORNING TORAY CO., LTD.HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • C08L83/04
    • C08L83/04C08G77/12C08G77/20C08L83/00
    • A curable silicone composition characteristically comprises (A) (A-I) an alkenyl- containingdialkylpolysiloxane and a viscosity of at least 1,000 mPa ­ s to not more than 20,000 mPa-s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO 4/2 unit, R 1 2 R 2 SiO 1/2 unit, and R 1 3 SiO 1/2 unit wherein R 1 is alkyl and R 2 is alkenyl, that contains from 2.5 to 5.0 mass% alkenyl group, and that has a ratio for the total number of moles of R 1 2 R 2 SiO 1/2 and R 1 3 SiO 1/2 units to 1 mole of the SiO 4/2 unit in the range from 0.70 to 1.10; (B) an organopolysiloxane that contains at least 0.9 mass% silicon-bonded hydrogen; and (C) a hydrosilylation reaction catalyst and provides a bending-tolerant and highly transparent cured silicone material that characteristically has a hardness is in the range from 80 to 95, the parallel light transmittance at 200°C is a value that is at least 99% of the parallel light transmittance at 25°C.
    • 一种可固化有机硅组合物特征在于包含(A)(A1)含链烯基的二烷基聚硅氧烷和至少1,000mPa·s至不大于20,000mPa·s的粘度和(A-2)含链烯基的树脂型有机基聚硅氧烷,其包含 SiO 4/2单元,R 1 2R 2 SiO 1/2单元和R 1 3 SiO 1/2单元,其中R 1是烷基,R 2是含有2.5-5.0质量%链烯基的链烯基,并且具有总共 R1 2R2SiO1 / 2和R1 3SiO1 / 2单元的摩尔数相对于1摩尔的SiO 4/2单元在0.70至1.10的范围内; (B)含有至少0.9质量%硅键合氢的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂,并且提供具有硬度在80至95范围内的弯曲耐受性和高度透明的固化的硅氧烷材料,在200℃下的平行光透射率为至少99 25℃平行透光率的百分比。
    • 19. 发明申请
    • CURABLE SILICONE COMPOSITION THAT PROVIDES A HIGHLY TRANSPARENT CURED SILICONE MATERIAL
    • 提供高度透明的固化硅材料的可固化硅胶组合物
    • WO2010087523A1
    • 2010-08-05
    • PCT/JP2010/051661
    • 2010-01-29
    • DOW CORNING TORAY CO., LTD.HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • HASEGAWA, ChiichiroYOSHITAKE, MakotoAKITOMO, Hiroshi
    • C08L83/04C09D183/04
    • C08L83/04C08G77/12C08G77/20C09D183/04C08L83/00C08K5/56
    • A curable silicone composition characteristically comprises (A) (A-1) a dialkylpolysiloxane that has at least two alkenyl groups in each molecule and a viscosity of at least 1,000 mPa•s to not more than 50,000 mPa•s and (A-2) an alkenyl-containing, resin-form organopolysiloxane that comprises the SiO 4/2 unit, R 1 R 2 SiO 1/2 unit, and R 1 3 SiO 1/2 unit wherein R 1 is alkyl and R 2 is alkenyl and that contains the alkenyl group in the range from at least 0.5 mass% to less than 3.5 mass%; (B) an organopolysiloxane that has at least three silicon-bonded hydrogen atoms; and (C) a hydrosilylation reaction catalyst and provides a highly transparent cured silicone material that characteristically has a hardness is in the range from at least 30 to not more than 80, the parallel light transmittance at 25 °C is at least 90%, and the parallel light transmittance at 200 °C is a value that is at least 99% of the parallel light transmittance at 25 °C.
    • 可固化的有机硅组合物特征在于包含(A)(A-1)在每个分子中具有至少两个烯基的二烷基聚硅氧烷和至少1,000mPa·s至50,000mPa·s以下的粘度和(A-2) 包含SiO 4/2单元,R1R2SiO1 / 2单元和R1 3SiO1 / 2单元的含烯基的树脂形式的有机聚硅氧烷,其中R1是烷基,R2是链烯基并且含有至少0.5质量% %至小于3.5质量%; (B)具有至少三个与硅键合的氢原子的有机聚硅氧烷; 和(C)氢化硅烷化反应催化剂,并且提供特征在于硬度在至少30至不大于80的范围内的高度透明的固化的硅氧烷材料,25℃下的平行透光率为至少90%,以及 在200℃下的平行透光率是在25℃下的平行光透射率的至少99%的值。