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    • 12. 发明申请
    • CYCLIC PROCESS FOR WET-CHEMICALLY PRODUCING LITHIUM METAL PHOSPHATES
    • 用于湿法生产锂金属磷酸盐的循环方法
    • US20090117022A1
    • 2009-05-07
    • US11908832
    • 2006-03-17
    • Gerhard NusplChristian VoglerJosefine Zuber
    • Gerhard NusplChristian VoglerJosefine Zuber
    • C01B25/30
    • C01B25/45C01B25/37
    • The invention relates to a method for producing lithium metal phosphates of a formula LiMPO4, wherein M is at least one type of bivalent metal, preferably selected from the first transition metal range. The inventive method consists in reacting a lithium phosphate with a metal salt and an acid phosphate source in a polar solvent for converting into a corresponding M-containing phosphate, in adding a basic lithium source for obtaining a precursor mixture for a desired lithium metal phosphate, in converting and separating the thus obtained mixture, preferably in hydrothermal conditions, in such a way that a desired final product is obtained, thereby receiving a lithium-containing filtrate. The addition of the basic lithium source initiates a lithium ion precipitation in the form of a lithium phosphate. The thus obtainable lithium phosphate can be reused in the form of a raw material, whereby said cycle enables lithium to be highly reusable.
    • 本发明涉及一种制备式LiMPO 4的锂金属磷酸盐的方法,其中M是至少一种二价金属,优选选自第一过渡金属范围。 本发明的方法包括在添加碱性锂源以获得所需的锂金属磷酸盐的前体混合物的同时使极性溶剂中的磷酸锂与酸性磷酸盐源反应,以转化成相应的含M磷酸盐, 在如此获得的混合物中,优选在水热条件下以获得所需最终产物的方式转化和分离,从而接收含锂滤液。 碱性锂源的添加引发锂离子沉淀形式的磷酸锂。 由此得到的锂磷酸盐可以以原料的形式重复使用,由此所述循环使得锂能够高度可重复使用。
    • 15. 发明申请
    • METHOD FOR REMOVING A PARTICULATE CONTAMINANT MATERIAL FROM A PARTICULATE MIXED LITHIUM METAL PHOSPHATE MATERIAL
    • 从颗粒状混合的锂金属磷酸盐材料中去除颗粒污染物质的方法
    • US20130001335A1
    • 2013-01-03
    • US13502265
    • 2010-10-13
    • Christian VoglerPeter BauerChristophe Michot
    • Christian VoglerPeter BauerChristophe Michot
    • B07B1/00B02C23/08
    • C01B25/37B02C23/08B07B15/00
    • The present invention relates to a method for removing a particulate contaminant material from a particulate mixed lithium metal phosphate material, comprising the steps of providing a particulate mixed lithium metal phosphate material, including a particulate contaminant material and a fine particulate mixed lithium metal phosphate, having the mass x*m, feeding the particulate mixed lithium metal phosphate material into a fluidizing stage containing particulate mixed lithium metal phosphate material of mass m, and fluidizing it in the fluidizing stage, feeding the fluidized particulate mixed lithium metal phosphate material to a sifting stage and passing it through the sifting stage, discontinuing the feed of the particulate mixed lithium metal phosphate material into the fluidizing stage after 10 to 100 times of the mass m have been fed into the fluidizing stage, fluidizing and sifting the material present in the fluidizing stage after discontinuing the feed, until the mass of the material present in the fluidizing stage becomes 10% to 100% of the mass m, and removing the remaining material from the fluidizing stage, wherein the sequence of steps b) to f) is repeated until the total mass x*m has been processed.
    • 本发明涉及一种从颗粒状混合锂金属磷酸盐材料中除去颗粒污染物质的方法,包括以下步骤:提供颗粒状混合锂金属磷酸盐材料,其包括颗粒状污染物质和细粒状混合锂金属磷酸盐,其具有 质量x * m,将颗粒状混合锂金属磷酸盐物质进料到含有质量m的颗粒状混合锂金属磷酸盐物质的流化阶段中,并在流化阶段将其流化,将流化颗粒状混合锂金属磷酸盐物质进料到筛分级 并将其通过筛选阶段,在质量m的10〜100倍之后停止将粒状混合的锂金属磷酸盐物质进料到流化阶段中,将其进料到流化阶段,流化和筛选流化阶段中存在的物质 在停止饲料后,直到马的质量 在流化阶段中的特征存在于质量m的10%至100%,并且从流化阶段除去剩余的材料,其中重复步骤b)至f)的顺序,直到总质量x * m已经被处理。
    • 16. 发明授权
    • Binary, ternary and quaternary lithium phosphates, method for the production thereof and use of the same
    • 二元,三元和四元磷酸锂,其制备方法和用途
    • US08168150B2
    • 2012-05-01
    • US10474555
    • 2002-04-10
    • Reinhard P. HemmerGiesela ArnoldChristian VoglerMargret Wohlfahrt-Mehrens
    • Reinhard P. HemmerGiesela ArnoldChristian VoglerMargret Wohlfahrt-Mehrens
    • H01M4/58C01B25/30
    • H01M4/136C01B25/45H01M4/5825H01M10/052
    • The invention relates to binary, ternary and quaternary lithium phosphates of general formula Li(FexM1yM2z)PO4 wherein M1 represents at least one element of the group comprising Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, and La; M2 represents at least one element of the group comprising Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, and La; x=between 0.5 and 1, y=between 0 and 0.5, z=between 0 and 0.5, provided that x+y+z=1, or x=0, y=1 and z=0. The said lithium phosphates can be obtained according to a method whereby precursor compounds of elements Li, Fe, M1 and/or M2 are precipitated from aqueous solutions and the precipitation product is dried in an inert gas atmosphere or a reducing atmosphere at a temperature which is between room temperature and approximately 200° C. and tempered at a temperature of between 300° C. and 1000° C. The inventive lithium phosphates have a very high capacity when used as cathode material in lithium accumulators.
    • 本发明涉及通式为Li(FexM1yM2z)PO4的二元,三元和四价磷酸锂,其中M1代表包括Sc,Ti,V,Cr,Mn,Co,Ni,Cu,Zn,Be, Mg,Ca,Sr,Ba,Al,Zr和La; M2表示包括Sc,Ti,V,Cr,Mn,Co,Ni,Cu,Zn,Be,Mg,Ca,Sr,Ba,Al,Zr和La中的至少一种元素; x = 0.5和1之间,y = 0和0.5之间,z = 0和0.5之间,条件是x + y + z = 1或x = 0,y = 1和z = 0。 所述磷酸锂可以按照以下方法获得,其中元素Li,Fe,M1和/或M2的前体化合物从水溶液中沉淀出来,沉淀产物在惰性气体气氛或还原气氛中在温度为 在室温和约200℃之间,并在300℃和1000℃之间的温度下回火。当用作锂蓄电池中的阴极材料时,本发明的磷酸锂具有非常高的容量。
    • 18. 发明授权
    • Method for removing a particulate contaminant material from a particulate mixed lithium metal phosphate material
    • 从颗粒状混合锂金属磷酸盐材料中除去颗粒污染物质的方法
    • US09550675B2
    • 2017-01-24
    • US13502265
    • 2010-10-13
    • Christian VoglerPeter BauerChristophe Michot
    • Christian VoglerPeter BauerChristophe Michot
    • B02C23/08C01B25/37B07B15/00
    • C01B25/37B02C23/08B07B15/00
    • A method for removing a particulate contaminant material from a particulate mixed lithium metal phosphate material is provided. The method includes feeding the particulate mixed lithium metal phosphate material into a fluidizing stage containing particulate mixed lithium metal phosphate material of mass m, feeding the fluidized particulate mixed lithium metal phosphate material through a sifting stage, discontinuing the feed of the particulate mixed lithium metal phosphate material into the fluidizing stage after 10 to 100 times of the mass m have been fed into the fluidizing stage, fluidizing and sifting the material present in the fluidizing stage after discontinuing the feed until the mass of the material present in the fluidizing stage becomes 10% to 100% of the mass m, and removing the remaining material from the fluidizing stage.
    • 提供了从颗粒状混合锂金属磷酸盐材料中除去颗粒状污染物质的方法。 该方法包括将颗粒状混合锂金属磷酸盐物质进料到含有质量m的颗粒状混合锂金属磷酸盐物质的流化阶段,通过筛选阶段供给流化颗粒状混合锂金属磷酸盐物质,停止颗粒状混合锂金属磷酸盐 进入流化阶段的材料的质量m的10至100倍之后的材料已经进料到流化阶段,在停止进料之后流化和筛选存在于流化阶段中的材料,直到流化阶段中存在的材料的质量达到10% 至质量m的100%,并且从流化阶段除去剩余的材料。