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11. 发明申请

WO2020096761A1 UV PATTERNABLE POLYMER BLENDS FOR ORGANIC THIN-FILM TRANSISTORS 审中-公开
公开(公告)号：WO2020096761A1
公开(公告)日：2020-05-14
申请号：PCT/US2019/057301
申请日：2019-10-22
申请人： CORNING INCORPORATED
发明人： DENG, Huayun , HE, Mingqian , LI, Xin , LI, Yang , NIU, Weijun , WALLACE, Arthur Lawrence , WANG, Hongxiang
IPC分类号： C08G61/12 , H01L51/00 , H01L51/05
摘要： A cross-bred organic semiconductor (OSC) polymer, includes a diketopyrrolopyrrole (DPP)-fused thiophene polymeric material, such that: the DPP-fused thiophene polymeric material comprises a first linear alkyl-substituted DPP portion and a second branched alkyl-substituted DPP portion, the cross-bred OSC polymer comprises a repeat unit having both the first linear alkyl-substituted DPP portion and the second branched alkyl-substituted DPP portion, and the fused thiophene is beta-substituted.

12. 发明申请

WO2014197372A1 SYNTHESIS OF POLYFUNCTIONAL POLYOL ACRYLATES 审中-公开
标题翻译：多官能聚丙烯酸酯的合成
公开(公告)号：WO2014197372A1
公开(公告)日：2014-12-11
申请号：PCT/US2014/040508
申请日：2014-06-02
申请人： CORNING INCORPORATED
发明人： MCCARTHY, Kevin Robert , NIU, Weijun , SCHISSEL, David Neal , WALLACE, Arthur Lawrence
IPC分类号： C08F2/00
CPC分类号： C08G65/3322
摘要： A method of synthesizing urethane-free polyfunctional acrylate compounds. The method includes reaction of a polyol with acrylic acid in the presence of an inhibitor. A catalyst may also be present. The catalyst may be an acid and the inhibitor may be a substituted phenol compound. Excess acid may be removed by adding a salt and excess water may be removed by adding a drying agent. The reaction converts alcohol groups of the polyol to acrylate groups to provide a radiation-curable polyfunctional acrylate compound. The reaction is applicable to polyols generally and provides a scalable high yield process for forming urethane-free polyfunctional acrylates over a wide range of molecular weights. Coatings made from the acrylate products exhibit modulus and tensile strength characteristics favorable for primary fiber coatings.
摘要翻译：一种合成无氨基甲酸酯的多官能丙烯酸酯化合物的方法。该方法包括在抑制剂存在下，多元醇与丙烯酸的反应。催化剂也可以存在。催化剂可以是酸，抑制剂可以是取代的酚化合物。可以通过加入盐除去过量的酸，并且可以通过加入干燥剂除去过量的水。该反应将多元醇的醇基转化为丙烯酸酯基团，以提供可辐射固化的多官能丙烯酸酯化合物。该反应通常适用于多元醇，并提供可扩展的高收率方法，用于在宽范围的分子量下形成无氨基甲酸酯的多官能丙烯酸酯。由丙烯酸酯产品制成的涂料显示出对初级纤维涂层有利的模量和拉伸强度特性。

13. 发明公开

EP3036245A1 BORON ESTER FUSED THIOPHENE MONOMERS 审中-公开
标题翻译：硼酸酯稠合噻吩单体
公开(公告)号：EP3036245A1
公开(公告)日：2016-06-29
申请号：EP14766021.1
申请日：2014-08-20
申请人： Corning Incorporated
发明人： HE, Mingqian , MATTHEWS, James Robert , NIU, Weijun , WALLACE, Arthur Lawrence
IPC分类号： C07F5/02 , C08L65/00 , G02F1/15 , H01B1/12 , C08G61/00 , H01L51/00
CPC分类号： C07F5/02 , C07D495/14 , C07D495/22 , C07F5/025 , C08G61/124 , C08G61/126 , C08G2261/1412 , C08G2261/3243 , C08G2261/344 , C08G2261/411 , C08L65/00 , H01L51/0036 , H01L51/0043 , H01L51/0053 , H01L51/0068 , H01L51/0074 , H01L51/008 , H01L51/0545 , H01L51/4253
摘要： A compound of formula (I), formula (II), or a combination thereof, and salts thereof is described. Each A may be independently an optionally substituted conjugated species or an optionally substituted aromatic species. Each R may be independently an optionally substituted C1-C40 linear alkyl chain, an optionally substituted branched alkyl chain, an optionally substituted alkyl chain containing heteroatoms, substituted alkyl chains, or H. Each R2 may be independently an optionally substituted C1-C40 linear alkyl chain, an optionally substituted branched alkyl chain, an optionally substituted alkyl chain containing heteroatoms, substituted alkyl chains, H, or part of a cyclic boronate ester with an other R2. Each n may be independently less than or equal to 3 and greater than or equal to 1. Each x may be independently less than or equal to 3.
摘要翻译：将硼酯稠合的噻吩单体和式（I）或（II）的盐与直接用硼酯取代到稠合噻吩上的方法一起描述，以及制备聚合物和由其延长缀合小分子的方法。该方法允许Suzuki偶联用于代替Stille偶联以形成稠合的噻吩基聚合物和延伸的小分子。所描述的硼化合物通常具有比锡化合物更低的毒性，例如先前针对基于稠合噻吩的甲壳素单体所识别的那些化合物。（1），（11）。可用这些二硼化物种获得的聚合物具有以下结构：（VIII）

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