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    • 11. 发明申请
    • AMMONIA SYNTHESIS USING LITHIUM ION CONDUCTIVE MEMBRANE
    • 使用锂离子导电膜的氨合成合成
    • WO2012129472A3
    • 2013-03-14
    • PCT/US2012030264
    • 2012-03-23
    • CERAMATEC INCJOSHI ASHOKBHAVARAJU SAI
    • JOSHI ASHOKBHAVARAJU SAI
    • C01C1/04B01J23/745C07B61/00
    • C25B1/00C25B9/08C25B11/035C25B13/04
    • Ammonia is synthesized using electrochemical and non-electrochemical reactions. The electrochemical reactions occur in an electrolytic cell (110) having a lithium ion conductive membrane (112) that divides the electrochemical cell (110) into an anolyte compartment (114) and a catholyte compartment (116). The catholyte compartment (116) includes a porous cathode (120) closely associated with the lithium ion conductive membrane (112). The overall electrochemical reaction is: 6LiOH + N2-> Li3N (s) + 3H2O + 3/2O2. The nitrogen (128) may be produced by a nitrogen generator (130). The non-electrochemical reaction involves reacting lithium nitride with water and/or steam as follows: Li3N (s) + 3H2O-> 3LiOH + NH3 (g). The ammonia is vented and collected. The lithium hydroxide is preferably recycled and introduced into the anolyte compartment. The electrolytic cell (110) is shut down prior to reacting the lithium nitride with water. The cathode (120) is preferably dried prior to start up of the electrolytic cell (1 10) and electrolyzing Li+ and N2 at the cathode (120).
    • 使用电化学和非电化学反应合成氨。 电化学反应发生在具有将电化学电池(110)分成阳极电解液室(114)和阴极电解液隔室(116)的锂离子传导膜(112)的电解槽(110)中。 阴极电解液隔室(116)包括与锂离子传导膜(112)紧密相关的多孔阴极(120)。 整个电化学反应为:6LiOH + N2-> Li3N(s)+ 3H2O + 3 / 2O2。 氮气(128)可以由氮气发生器(130)产生。 非电化学反应包括使氮化锂与水和/或蒸汽反应如下:Li 3 N(s)+ 3H 2 O-→3LiOH + NH 3(g)。 将氨排出并收集。 优选将氢氧化锂再循环并引入阳极电解液室。 在使氮化锂与水反应之前关闭电解池(110)。 阴极(120)优选在电解槽(110)启动之前被干燥并在阴极(120)处电解Li +和N 2。
    • 12. 发明申请
    • ELECTROCHEMICAL CONVERSION OF ALKALI SULFATE INTO USEFUL CHEMICAL PRODUCTS
    • 碱金属硫酸盐电化学转化为有用的化工产品
    • WO2012103529A3
    • 2012-12-13
    • PCT/US2012023044
    • 2012-01-27
    • CERAMATEC INCJOSHI ASHOKBHAVARAJU SAI
    • JOSHI ASHOKBHAVARAJU SAI
    • C25B1/20C01B17/02C01B32/40C01D1/04C10L3/00C25B1/00
    • C25B1/00C25B1/02C25B1/20
    • Electrochemical processes to convert alkali sulfates into useful chemical products, such as syngas, alkali hydroxide, and sulfur are disclosed. An alkali sulfate is reacted with carbon to form carbon monoxide and alkali sulfide. In one embodiment, the alkali sulfide is dissolved in water and subjected to electrochemical reaction to form alkali hydroxide, hydrogen, and sulfur. In another embodiment, the alkali sulfide is reacted with iodine to form alkali iodide sulfur in a non-aqueous solvent, such as methyl alcohol. The alkali iodide is electrochemically reacted to form alkali hydroxide, hydrogen, and iodine. The iodine may be recycled to react with additional alkali sulfide. The hydrogen and carbon monoxide from both embodiments may be combined to form syngas. The alkali hydroxide from both embodiments may be recovered as a useful industrial chemical.
    • 公开了将碱金属硫酸盐转化为有用的化学产品如合成气,碱金属氢氧化物和硫的电化学方法。 碱金属硫酸盐与碳反应形成一氧化碳和碱金属硫化物。 在一个实施方案中,将碱金属硫化物溶解在水中并进行电化学反应以形成碱金属氢氧化物,氢和硫。 在另一个实施方案中,碱金属硫化物与碘反应以在非水溶剂如甲醇中形成碱金属碘化物硫。 碱金属碘化物发生电化学反应形成碱金属氢氧化物,氢和碘。 碘可以被再循环以与额外的碱金属硫化物反应。 来自两个实施方案的氢气和一氧化碳可以结合形成合成气。 来自两个实施方案的碱金属氢氧化物可作为有用的工业化学品回收。
    • 14. 发明申请
    • APPARATUS AND METHOD FOR DELIVERING BENEFICIAL LIQUIDS AT STEADY RATE
    • 以稳定的速度提供有益液体的装置和方法
    • WO2010025412A3
    • 2010-06-10
    • PCT/US2009055432
    • 2009-08-28
    • MICROLIN LLCGORDON JOHNJOSHI ASHOKWOLD TRUMANBHAVARAJU SAI
    • GORDON JOHNJOSHI ASHOKWOLD TRUMANBHAVARAJU SAI
    • B01D61/00B01D63/00
    • A01M1/2044A61L9/12Y10T137/2931
    • An apparatus (1) for delivering a beneficial agent (2) is disclosed in one embodiment of the invention as including a water collection chamber. A water-transporting membrane (5) is provided to communicate with the water collection chamber (8). An extraction chamber receives water (9) through the water-transporting membrane (5), expanding the extraction chamber. A dispensing chamber, containing a beneficial agent (2), is configured to contract upon expanding the extraction chamber. This causes the dispensing chamber to expel the beneficial agent (2) through a subterranean delivery channel, such as a rigid hollow spike. In certain embodiments, a rate adjustment mechanism (6a, 6b) may control the rate that water (9) is received through the water-transporting membrane (5), thereby controlling the rate the beneficial agent (2) is expelled. The water-transporting membrane (5) has features that repel osmagent from passing through to the water collection chamber (8). The apparatus (1) features steady rate performance without refreshing the water chamber (8) and low temperature sensitivity.
    • 在本发明的一个实施例中公开了用于输送有益药剂(2)的设备(1),其包括水收集室。 提供一个水输送膜(5)以与水收集室(8)连通。 提取室通过输水膜(5)接收水(9),使提取室膨胀。 包含有益药剂(2)的分配腔室构造成在扩张提取腔室时收缩。 这导致分配室通过地下输送通道例如刚性空心钉将有益试剂(2)排出。 在某些实施方案中,速率调节机构(6a,6b)可控制通过水输送膜(5)接收水(9)的速率,从而控制有益剂(2)排出的速率。 输水膜(5)具有排斥渗透到水收集室(8)的特征。 该设备(1)具有稳定的速率性能而不需要刷新水室(8)和低温敏感性。
    • 19. 发明申请
    • APPARATUS AND METHOD FOR DELIVERING BENEFICIAL AGENTS TO SUBTERRANEAN LOCATIONS
    • 将受益人送到下属地点的装置和方法
    • WO2009126729A3
    • 2010-01-21
    • PCT/US2009039940
    • 2009-04-08
    • MICROLIN LLCWOLD TRUMANJOSHI ASHOKBHAVARAJU SAI
    • WOLD TRUMANJOSHI ASHOKBHAVARAJU SAI
    • A01G29/00
    • A01G27/006A01G29/00
    • An apparatus for delivering a beneficial agent to a subterranean location is disclosed in one embodiment of the invention as including a water collection chamber (20) having a substantially open end (30). A water-transporting membrane (26) is provided to communicate with the water collection chamber (20). An extraction chamber (22) receives water through the water-transporting membrane (26), expanding the extraction chamber (22). A dispensing chamber (24), containing a beneficial agent such as fertilizer, is configured to contract upon expanding the extraction chamber (22). This causes the dispensing chamber (24) to expel the beneficial agent through a subterranean delivery channel (38), such as a rigid hollow spike (38). In certain embodiments, a rate adjustment mechanism may control the rate that water is received through the water-transporting membrane (26), thereby controlling the rate the beneficial agent is expelled from the subterranean delivery channel (38).
    • 在本发明的一个实施例中公开了一种用于将有益剂递送到地下位置的装置,包括具有基本开口端(30)的集水室(20)。 水输送膜(26)设置成与集水室(20)连通。 提取室(22)通过水输送膜(26)接收水,使提取室(22)膨胀。 包含有益剂如肥料的分配室(24)构造成在膨胀提取室(22)时收缩。 这使得分配室(24)通过地下输送通道(38)例如刚性中空尖钉(38)排出有益剂。 在某些实施例中,速率调节机构可以控制通过水输送膜(26)接收水的速率,从而控制有益剂从地下输送通道(38)排出的速率。