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    • 11. 发明授权
    • Use of silicon oxynitride ARC for metal layers
    • 氧氮化硅ARC用于金属层
    • US06326231B1
    • 2001-12-04
    • US09207562
    • 1998-12-08
    • Ramkumar SubramanianBhanwar SinghSanjay K. YedurMarina V. PlatChristopher F. LyonsBharath RangarajanMichael K. Templeton
    • Ramkumar SubramanianBhanwar SinghSanjay K. YedurMarina V. PlatChristopher F. LyonsBharath RangarajanMichael K. Templeton
    • H01L2100
    • H01L21/32139H01L21/0276H01L21/3143H01L21/3145
    • In one embodiment, the present invention relates to a method of forming a silicon oxynitride antireflection coating over a metal layer, involving the steps of providing a semiconductor substrate comprising the metal layer over at least part of the semiconductor substrate; depositing a silicon oxynitride layer over the metal layer having a thickness from about 100 Å to about 150 Å; and forming an oxide layer having a thickness from about 5 Å to about 50 Å over the silicon oxynitride layer to provide the silicon oxynitride antireflection coating. In another embodiment, the present invention relates to a method of reducing an apparent reflectivity of a metal layer having a first reflectivity in a semiconductor structure, involing forming a silicon oxynitride antireflection coating over the metal layer; wherein the silicon oxynitride antireflection coating formed over the metal layer has a second reflectivity and is formed by depositing silicon oxynitride on the metal layer by chemical vapor deposition and forming an oxide layer over the oxynitride, and the difference between the first reflectivity and the second reflectivity is at least about 60%.
    • 在一个实施方案中,本发明涉及在金属层上形成氮氧化硅抗反射涂层的方法,包括以下步骤:在半导体衬底的至少一部分上提供包括金属层的半导体衬底; 在所述金属层上沉积厚度为约至约的氧氮化硅层; 并在氮氧化硅层上形成厚度约为5-20埃的氧化物层,以提供氮氧化硅抗反射涂层。 在另一个实施方案中,本发明涉及一种在半导体结构中减少具有第一反射率的金属层的表观反射率的方法,包括在金属层上形成氮氧化硅抗反射涂层; 其中形成在所述金属层上的所述氧氮化硅抗反射涂层具有第二反射率,并且通过化学气相沉积在所述金属层上沉积氧氮化硅并在所述氧氮化物上形成氧化物层,并且所述第一反射率和所述第二反射率之间的差异 至少约60%。
    • 13. 发明授权
    • Nozzle arm movement for resist development
    • 喷嘴臂运动用于抗蚀剂开发
    • US06541184B1
    • 2003-04-01
    • US09655979
    • 2000-09-06
    • Ramkumar SubramanianKhoi A. PhanBharath RangarajanBhanwar SinghMichael K. TempletonSanjay K. Yedur
    • Ramkumar SubramanianKhoi A. PhanBharath RangarajanBhanwar SinghMichael K. TempletonSanjay K. Yedur
    • G03C556
    • H01L21/6715G03F7/3028
    • A system and method is provided that facilitates the application of a uniform layer of developer material on a photoresist material layer. The system includes a multiple tip nozzle and a movement system that moves the nozzle to an operating position above a central region of a photoresist material layer located on a substrate, and applies a volume of developer as the nozzle scan moves across a predetermined path. The movement system moves the nozzle in two dimensions by providing an arm that has a first arm member that is pivotable about a first rotational axis and a second arm member that is pivotable about a second rotational axis or is movable along a translational axis. The system also provides a measurement system that measures the thickness uniformity of the developed photoresist material layer disposed on a test wafer. The thickness uniformity data is used to reconfigure the predetermined path of the nozzle as the developer is applied. The thickness uniformity data can also be used to adjust the volume of developer applied along the path and/or the volume flow rate.
    • 提供了一种有助于在光致抗蚀剂材料层上施加均匀的显影剂材料层的系统和方法。 该系统包括多个尖端喷嘴和运动系统,该运动系统将喷嘴移动到位于基板上的光致抗蚀剂材料层的中心区域上方的操作位置,并且当喷嘴扫描移动穿过预定路径时施加一定体积的显影剂。 移动系统通过提供具有第一臂构件的臂来移动喷嘴,该臂具有可围绕第一旋转轴线枢转的第一臂构件和可围绕第二旋转轴线枢转或可沿着平移轴线移动的第二臂构件。 该系统还提供了测量设置在测试晶片上的显影的光致抗蚀剂材料层的厚度均匀性的测量系统。 当施加显影剂时,厚度均匀性数据用于重新配置喷嘴的预定路径。 厚度均匀性数据也可用于调节沿路径施加的显影剂的体积和/或体积流量。
    • 14. 发明授权
    • Developer soluble dyed BARC for dual damascene process
    • 开发可溶染色的BARC用于双镶嵌工艺
    • US06455416B1
    • 2002-09-24
    • US09706967
    • 2000-11-06
    • Ramkumar SubramanianBhanwar SinghBharath RangarajanMichael K. Templeton
    • Ramkumar SubramanianBhanwar SinghBharath RangarajanMichael K. Templeton
    • H01L214763
    • H01L21/76808G03F7/091H01L21/31144
    • One aspect of the present invention relates to a method of processing a semiconductor structure, involving the steps of providing a substrate having an insulation layer thereover; forming a first antireflection coating over the insulation layer; patterning a first resist over the antireflection coating; forming a plurality of vias in the insulation layer and the first antireflection coating, the vias having a first width; filling the via with a second antireflection coating, the second antireflection coating comprising a dye and a film forming material; patterning a second resist over the structure and removing the second antireflection coating from the via; forming a trench over the plurality of vias in the insulation layer, the trench having a width that is larger than the average width of the vias; and filling the trench and vias with a conductive material. The present invention provides improved dual damascene methods for substrates by using a developer soluble ARC containing a dye to facilitate the formation of trenches directly over the previously formed vias.
    • 本发明的一个方面涉及一种处理半导体结构的方法,包括以下步骤:提供其上具有绝缘层的基板; 在所述绝缘层上形成第一抗反射涂层; 在抗反射涂层上图案化第一抗蚀剂; 在所述绝缘层和所述第一抗反射涂层中形成多个通孔,所述通孔具有第一宽度; 用第二抗反射涂层填充通孔,第二抗反射涂层包含染料和成膜材料; 在所述结构上形成第二抗蚀剂并从所述通孔去除所述第二抗反射涂层; 在所述绝缘层中的多个通孔上形成沟槽,所述沟槽的宽度大于所述通孔的平均宽度; 并用导电材料填充沟槽和通孔。 本发明通过使用含有染料的显影剂可溶性ARC来促进直接在先前形成的通孔上形成沟槽,从而为衬底提供改进的双镶嵌方法。
    • 16. 发明授权
    • Nozzle arm movement for resist development
    • 喷嘴臂运动用于抗蚀剂开发
    • US06248175B1
    • 2001-06-19
    • US09430001
    • 1999-10-29
    • Ramkumar SubramanianKhoi A. PhanBharath RangarajanBhanwar SinghMichael K. TempletonSanjay K. Yedur
    • Ramkumar SubramanianKhoi A. PhanBharath RangarajanBhanwar SinghMichael K. TempletonSanjay K. Yedur
    • B05C1100
    • H01L21/6715G03F7/3021
    • A system and method is provided that facilitates the application of a uniform layer of developer material on a photoresist material layer. The system includes a nozzle adapted to apply a predetermined volume of developer material on a photoresist material layer along a linear path having a length approximately equal to the diameter of the photoresist material layer. A movement system moves the nozzle to a first position offset from a central region of the photoresist material layer for applying a first predetermined volume of developer material to the photoresist material layer while the developer material is spin coated. The movement system also moves the nozzle to a second position offset from the central region for applying a second predetermined volume of developer material to the photoresist material layer while the developer is spin coated. The first position is located on an opposite side of the central region with respect to the second position. A method of adjusting the offset position and/or volume of developer material applied at the first and second position is also provided. The method utilizes developed photoresist material layer thickness data provided by a measurement system to adjust the offset position and/or volume of the developer.
    • 提供了一种有助于在光致抗蚀剂材料层上施加均匀的显影剂材料层的系统和方法。 该系统包括适于沿着具有大致等于光致抗蚀剂材料层的直径的直线路径的光致抗蚀剂材料层上施加预定体积的显影剂材料的喷嘴。 移动系统将喷嘴移动到偏离光致抗蚀剂材料层的中心区域的第一位置,以在旋转涂覆显影剂材料的同时将第一预定体积的显影剂材料施加到光致抗蚀剂材料层。 移动系统还将喷嘴移动到偏离中心区域的第二位置,以在显影剂被旋涂时施加第二预定体积的显影剂材料到光致抗蚀剂材料层。 第一位置相对于第二位置位于中心区域的相反侧。 还提供了一种调节在第一和第二位置施加的显影剂材料的偏移位置和/或体积的方法。 该方法利用由测量系统提供的显影的光致抗蚀剂材料层厚度数据来调节显影剂的偏移位置和/或体积。
    • 17. 发明授权
    • Growing copper vias or lines within a patterned resist using a copper seed layer
    • 使用铜种子层在图案化抗蚀剂中生长铜通孔或线
    • US06905950B2
    • 2005-06-14
    • US09893198
    • 2001-06-27
    • Ramkumar SubramanianMichael K. TempletonBhanwar SinghBharath Rangarajan
    • Ramkumar SubramanianMichael K. TempletonBhanwar SinghBharath Rangarajan
    • H01L21/768H01L21/3205
    • H01L21/76885H01L21/76879
    • The present invention involves a method for fabricating interconnecting lines and vias. According to the invention, copper is grown within the openings in a patterned coating. The patterned coating can be a resist coating or a dielectric coating. Either type of coating can be formed over a copper seed layer, whereby the seed layer is exposed within the pattern gaps. The copper seed layer can also be provided within the pattern gaps after patterning. Copper features are grown within the pattern gaps by plating. Where the patterned coating is a resist, the resist is stripped leaving the copper features in the inverse pattern image. The copper features can be coated with a diffusion barrier layer and a dielectric. The dielectric is polished to leave the dielectric filling the spaces between copper features. The invention provides copper lines and vias without the need for a dielectric or metal etching step. Another benefit of the invention is that lines widths can be increased by trimming the patterned coating prior to growing the copper features.
    • 本发明涉及制造互连线和通孔的方法。 根据本发明,铜在图案化涂层的开口内生长。 图案化的涂层可以是抗蚀剂涂层或介电涂层。 任何一种类型的涂层可以在铜籽晶层上形成,从而种子层在图案间隙内露出。 图案化之后也可以在图案间隙内提供铜籽晶层。 铜特征通过电镀在图案间隙内生长。 在图案涂层是抗蚀剂的情况下,剥离抗蚀剂,留下逆向图案图案中的铜特征。 铜的特征可以涂覆有扩散阻挡层和电介质。 电介质被抛光以留下电介质填充铜特征之间的空间。 本发明提供铜线和通孔,而不需要电介质或金属蚀刻步骤。 本发明的另一个好处是通过在生长铜特征之前修整图案化涂层可以增加线宽。