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11. 发明申请

US20100280205A1 PROCESS FOR PREPARING (METH)ACRYLATES 有权
标题翻译：制备（甲基）丙烯酸酯的方法
公开(公告)号：US20100280205A1
公开(公告)日：2010-11-04
申请号：US12745703
申请日：2008-09-29
申请人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
发明人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
IPC分类号： C08F120/12 , C07C69/54
CPC分类号： C07C67/03 , C08F20/18 , C08F120/12 , C07C69/54
摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyses the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in litres of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.
摘要翻译：制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的具有6至22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应，催化反应和一定量的酚聚合抑制剂或两种或多种酚聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于特定的总氧气输入量小于或等于至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。

12. 发明授权

US09206270B2 Process for preparing (meth)acrylates 有权
标题翻译：（甲基）丙烯酸酯的制备方法
公开(公告)号：US09206270B2
公开(公告)日：2015-12-08
申请号：US12745703
申请日：2008-09-29
申请人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
发明人： Joachim Knebel , Ralf Merbach , Guido Protzmann , Klaus Gottmann , John Hirsh , Gerold Schmitt , Dieter Tessmer , Wilhelm Karnbrock , Wolfgang Klesse , Volker Kerscher
IPC分类号： C08F118/02 , C07C69/52 , C08F20/18 , C07C67/03 , C08F120/12
CPC分类号： C07C67/03 , C08F20/18 , C08F120/12 , C07C69/54
摘要： Process for preparing (meth)acrylates of the formula (I) CH2═C(R1)—CO—O—R2 (I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2═C(R1)—CO—OR3 (II) with an alcohol of the formula (III) HO—R2 (III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.0 l/kg, measured in liters of oxygen per kilogram of (meth)acrylate of the formula (I), where the volume of oxygen introduced is calculated at a temperature of 25° C. and a pressure of 101 325 pascal. The resulting (meth)acrylates can surprisingly be processed to particularly high molecular weight emulsion polymers which are, for example, outstandingly suitable for use as flow resistance reducers in mineral oil extraction.
摘要翻译：制备式（I）的（甲基）丙烯酸酯的方法，其中R 1是氢或甲基，R 2是饱和或不饱和的，直链或支链的脂族或环状的具有6-22个碳原子的烷基或（C 6 -C 14） - 芳基 - （C 1 -C 8） - 烷基; 通过使式II CH 2 = C（R 1）-CO-OR 3（II）的（甲基）丙烯酸酯与式（III）的醇HO-R 2（III）在一定量的合适的催化剂存在下反应，催化反应和一定量的酚聚合抑制剂或两种或多种酚类聚合抑制剂的组合，其足以抑制不期望的聚合; 反应是通过输入或引入反应混合物中进行的，所述反应混合物是由一定量的氧气或足够抑制不期望的聚合的氧气混合物的反应而产生的，并且该方法的特征在于，具体的总氧气输入量小于或等于至1.0l / kg，以公斤式（I）的（甲基）丙烯酸酯计，氧气的导入量在25℃，压力为101 325帕斯卡时计算。所得到的（甲基）丙烯酸酯可以令人惊奇地加工成特别高分子量的乳液聚合物，例如非常适合用作矿物油提取中的阻流剂。

13. 发明授权

US08389762B2 Method for purifying methacrylic acid 有权
标题翻译：甲基丙烯酸的纯化方法
公开(公告)号：US08389762B2
公开(公告)日：2013-03-05
申请号：US12812258
申请日：2009-01-13
申请人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
发明人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
IPC分类号： C07C57/065 , C07C57/07
CPC分类号： C07C51/06 , B01D3/105 , B01D17/0214 , C07C51/48 , C07C57/04
摘要： The present invention relates to a process for purifying methacrylic acid, wherein the reaction mixture obtained by a reaction of methacrylamide with water is cooled by mixing with an aqueous medium and then passed into a phase separator.The present invention further describes a system for performing the process according to the invention.
摘要翻译：本发明涉及一种纯化甲基丙烯酸的方法，其中通过与甲基丙烯酰胺与水的反应获得的反应混合物通过与水性介质混合而冷却，然后通入相分离器。本发明还描述了一种用于执行根据本发明的方法的系统。

14. 发明申请

US20120004460A9 METHOD FOR PRODUCING METHACRYLIC ACID 有权
标题翻译：生产甲基丙烯酸的方法
公开(公告)号：US20120004460A9
公开(公告)日：2012-01-05
申请号：US12864985
申请日：2009-01-13
申请人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
发明人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
IPC分类号： C07C57/065 , B01J19/00
CPC分类号： C07C51/06 , C07C57/04
摘要： The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
摘要翻译：本发明涉及通过使甲基丙烯酰胺与水反应生产甲基丙烯酸的方法，其中所述反应在管式反应器中连续进行，并且在所述管式反应器内的反应混合物的流动方向上存在压差。此外，本发明公开了一种用于实施本发明的方法的设备。

15. 发明授权

US06340778B1 Process for catalytic aldol condensations by means of a multiphase reaction 有权
标题翻译：通过多相反应催化醛醇缩合的方法
公开(公告)号：US06340778B1
公开(公告)日：2002-01-22
申请号：US09694350
申请日：2000-10-24
申请人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann , Juergen Koch
发明人： Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann , Juergen Koch
IPC分类号： C07C4572
CPC分类号： B01J8/06 , B01J2208/00265 , C07C45/74 , C07C47/21
摘要： The invention relates to a process for the catalytic aldol condensation of aldehydes by means of a multiphase reaction in a tube reactor, wherein the catalyst is present in the continuous phase and at least one aldehyde is present in a dispersed phase and the loading factor B of the tube reactor is equal to or greater than 0.8; the aldol condensation products obtained in this way can be used for preparing alcohols or carboxylic acids.
摘要翻译：本发明涉及在管式反应器中通过多相反应催化醛醛缩合的方法，其中催化剂存在于连续相中，并且至少一种醛存在于分散相中，负载因子B为管式反应器等于或大于0.8; 以这种方式获得的醛醇缩合产物可用于制备醇或羧酸。

16. 发明申请

US20150247297A1 NEW TYPE OF ROAD MARKINGS FOR SUPPORTING THE ENVIRONMENT DETECTION OF VEHICLES 有权
标题翻译：支持车辆环境检测的新型道路标示
公开(公告)号：US20150247297A1
公开(公告)日：2015-09-03
申请号：US14422483
申请日：2013-11-06
申请人： Guido Protzmann , Joern Kiwitt , Dominik Kiefer , Guenter Schmitt , Marita Kaufmann , Michael Olapoju
发明人： Guido Protzmann , Joern Kiwitt , Dominik Kiefer , Guenter Schmitt , Marita Kaufmann , Michael Olapoju
IPC分类号： E01F9/00 , C09D5/33 , E01C11/00 , E01C7/35 , E01F9/04 , E01C9/00
CPC分类号： C09D5/004 , E01C7/356 , E01C9/001 , E01C11/00 , E01F9/30 , E01F9/506 , E01F9/518 , E01F9/524 , Y10T428/12014 , Y10T428/12028 , Y10T428/2993 , Y10T428/2998
摘要： The present invention encompasses an innovative concept for the marking of trafficways, more particularly roads. The application qualities and lifetime of these new markings are comparable with those of the prior art. The markings also possess properties comparable with those of the prior art in respect of night visibility, back-in-service time, and surface quality. An additional contribution of the markings of the present invention, however, is that they can be used to support modern driver assistance systems and autonomous driving. With this in mind, the present invention relates more particularly to road markings which, building on established systems, are equipped with additional reflection capacity for electromagnetic radiation, more particular for microwaves and/or infrared radiation.
摘要翻译：本发明包括用于标记交通道路，特别是道路的创新概念。这些新标记的应用质量和使用寿命与现有技术相当。在夜视能见度，服役时间和表面质量方面，标记也具有与现有技术相当的特性。然而，本发明的标记的另外的贡献是它们可以用于支持现代驾驶员辅助系统和自主驾驶。考虑到这一点，本发明更具体地涉及在建立在已建立的系统上的道路标线上配备有用于电磁辐射的附加反射能力，更特别地用于微波和/或红外辐射。

17. 发明申请

US20100331572A1 METHOD FOR PRODUCING METHACRYLIC ACID 有权
标题翻译：生产甲基丙烯酸的方法
公开(公告)号：US20100331572A1
公开(公告)日：2010-12-30
申请号：US12864985
申请日：2009-01-03
申请人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
发明人： Udo Gropp , Stefanie Sohnemann , Guido Protzmann , Thomas Mertz
IPC分类号： C07C57/065 , B01J19/00
CPC分类号： C07C51/06 , C07C57/04
摘要： The present invention relates to a method for producing methacrylic acid by reacting methacrylamide with water, wherein said reaction is performed continuously in a tube reactor and a pressure differential exists in the flow direction of the reaction mixture inside said tube reactor. Furthermore, the present invention discloses a facility for carrying out the method according to the invention.
摘要翻译：本发明涉及通过使甲基丙烯酰胺与水反应生产甲基丙烯酸的方法，其中所述反应在管式反应器中连续进行，并且在所述管式反应器内的反应混合物的流动方向上存在压差。此外，本发明公开了一种用于实施本发明的方法的设备。

18. 发明授权

US06627782B2 Preparation of 1-olefins 有权
公开(公告)号：US06627782B2
公开(公告)日：2003-09-30
申请号：US10067924
申请日：2002-02-08
申请人： Alfred Kaizik , Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
发明人： Alfred Kaizik , Wilfried Bueschken , Klaus-Diether Wiese , Guido Protzmann
IPC分类号： C07C100
CPC分类号： C07C29/145 , C07C11/02 , C07C45/74 , C07C49/203 , C07C31/125 , C07C31/10
摘要： A multi-stage synthesis is effective for preparing 1-olefins from aldehydes. The aldehyde is condensed with acetone to form an &agr;,&bgr;-unsaturated ketone. The unsaturated ketone is hydrogenated to yield a saturated alcohol. By dehydrating the saturated alcohol a 1-olefin is obtained. The olefin can be isolated in high yield and purified.

19. 发明授权

US06603047B2 Condensation of aldehydes with ketones by multiphase reaction 失效
公开(公告)号：US06603047B2
公开(公告)日：2003-08-05
申请号：US10068955
申请日：2002-02-11
申请人： Klaus-Diether Wiese , Wilfried Buschken , Guido Protzmann
发明人： Klaus-Diether Wiese , Wilfried Buschken , Guido Protzmann
IPC分类号： C07C4573
CPC分类号： C07C45/74 , C07C29/172 , C07C45/62 , C07C49/203 , C07C31/20
摘要： A process for conducting multiphase reactions, especially the preparation of &agr;,&bgr;-unsaturated ketones by condensation of aldehydes with ketones.

20. 发明授权

US06482992B2 Multistage process for the preparation of oxo aldehydes and/or alcohols 有权
标题翻译：用于制备羰基醛和/或醇的多步法
公开(公告)号：US06482992B2
公开(公告)日：2002-11-19
申请号：US09904893
申请日：2001-07-16
申请人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
发明人： Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C29/16 , C07C31/125 , C07C47/02
摘要： Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.
摘要翻译：烯烃被加氢甲酰化以在多个加氢甲酰化阶段中产生醇和/或醛，其各自包括：a）在反应器中的钴或铑催化剂存在下，碳原子含量为6至24个碳原子的烯烃加氢甲酰化到烯烃反应物转化为产物的程度为20至98％; b）从从反应器排出的所得液体中除去催化剂; c）将所得液体加氢甲酰化混合物分离成包含烯烃和链烷烃的低沸点馏分，以及包含醛和/或醇的底部馏分; 和在下列工艺阶段中存在的低沸点馏分中存在的烯烃反应，包括步骤a，b和c，并组合所有工艺步骤的工艺步骤c）的底部馏分。

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