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11. 发明专利

DE10055497A1 未知
公开(公告)号：DE10055497A1
公开(公告)日：2002-05-29
申请号：DE10055497
申请日：2000-11-09
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F4/54 , C08F2/38 , C08F4/00 , C08F36/00 , C08F36/04 , C08F297/04 , C08K5/06 , C08F236/10 , B60C1/00
摘要： Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers (I). Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers of formula (I): R , R = 1-10C alkyl, 5-8C cycloalkyl, 6-10C aryl or 7-15C aralkyl; X = (CH2)pNR R ; R , R = groups as defined for R and R ; and m, n = 1-6.

12. 发明专利

PL350542A1 ANIONIC POLUMERISATION MODIFYING AGENTS, THEIR APPLICATION, POLYMERS BASED ON CONJUGATED DIENES AND APPLICATION OF SUCH POLYMERS 未知
公开(公告)号：PL350542A1
公开(公告)日：2002-05-20
申请号：PL35054201
申请日：2001-11-07
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F4/54 , C08F2/38 , C08F4/00 , C08F36/00 , C08F36/04 , C08F297/04 , C08K5/06 , C08F2/26 , C08F236/04
摘要： Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers (I). Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers of formula (I): R , R = 1-10C alkyl, 5-8C cycloalkyl, 6-10C aryl or 7-15C aralkyl; X = (CH2)pNR R ; R , R = groups as defined for R and R ; and m, n = 1-6.

13. 发明专利

DE10217800B4 Coupled and electrophilically-modified diene polymers, useful in tire manufacture or as rubber reinforcement in ABS or HIPS, are obtained by reaction of living polymer in situ with polyfunctional compound 未知
公开(公告)号：DE10217800B4
公开(公告)日：2006-04-13
申请号：DE10217800
申请日：2002-04-22
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F8/00 , C08C19/44 , C08F8/30 , C08L19/00
摘要： A coupled and electrophilic group-modified polymer is claimed which is obtained by reaction of a specified polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing at least 3 coupling groups and at least 1 electrophilic modifying group. - A coupled and electrophilic group-modified polymer obtained by reaction of a polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing at least 3 coupling groups and at least 1 electrophilic modifying group is such that (i) the polymer has mol. wt. distribution (Mw/Mn) 1.0-2.1, Mw at least 50,000, Tg -100 to -10 deg. C, a vinyl group content 5-90% (based on diene units and coupling number at least 2 and (ii) the amount of electrophilic modifying groups based on the amount of the alkali-terminated polymer anion intermediate used to prepare the product is 3-33 mol.%. - An INDEPENDENT CLAIM is also included for the preparation of the coupled and modified polymer.

14. 发明专利

DE10242942A1 未知
公开(公告)号：DE10242942A1
公开(公告)日：2004-03-18
申请号：DE10242942
申请日：2002-09-16
申请人： BAYER AG
发明人： GRUEN MICHAEL , MUECKE SYLVIA , WRANA CLAUS
IPC分类号： B60C1/00 , C08C19/44 , C08F8/00 , C08F36/04 , C08L15/00 , C08F236/04 , C08F236/06 , C08J3/24 , C08K5/151 , C08F4/46
摘要： Branched and coupled polymers are based on optionally conjugated dienes and vinyl aromatic compounds as well as polyfunctional organic compounds having at least 4 groups capable of coupling whereby at least 60% of the coupled polymers have a degree of branching of greater than 2 with the proviso that amount of polymer having at least 4-fold branching is greater than the amount having 3-fold branching. Branched and coupled polymers (I) are based on optionally conjugated dienes and vinyl aromatic compounds as well as polyfunctional organic compounds having at least 4 groups capable of coupling whereby the polymers (I) have a mol. wt. ratio (Mw/Mn) of 1.0-3.0, a weight average mol. wt. of 400,000-2,000,000, a glass transition temperature of -50 to -10degreesC, a 1,2-vinyl group content of 40-80% (with respect to diene groups), a degree of coupling of at least 45% whereby at least 60% of the coupled polymers (I) have a degree of branching of greater than 2 with the proviso that amount of polymer having at least 4-fold branching (with respect to 100 g polymer) is greater than the amount having 3-fold branching and the difference in solution viscosity before and after coupling is 100-400 (measured as a solution of 0.5 g polymer in 100 ml tolune at 25 degreesC using a Ubbelohde visometer). An Independent claim is included for a process for the production of polymers (I) by conventional polymerization of dienes with vinyl aromatic compounds in the presence of inert organic solvents and organic alkali metal compounds and reaction of the alkali metal terminated polymer anions that are formed with organic polyfunctional compounds that have at least 4 groups capable of coupling whereby the molar ratio of polyfunctional compounds to alkali-metal terminated polymer anions is 0.1-0.28:1.

15. 发明专利

DE10217800A1 Coupled and electrophilically-modified diene polymers, useful in tire manufacture or as rubber reinforcement in ABS or HIPS, are obtained by reaction of living polymer in situ with polyfunctional compound 未知
公开(公告)号：DE10217800A1
公开(公告)日：2003-03-06
申请号：DE10217800
申请日：2002-04-22
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08C19/44 , C08L19/00 , C08F8/00 , C08F8/30
摘要： A coupled and electrophilic group-modified polymer is claimed which is obtained by reaction of a specified polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing >=3 coupling groups and >=1 electrophilic modifying group. A coupled and electrophilic group-modified polymer obtained by reaction of a polymer based on a conjugated diene (and optionally also vinylaromatics) with a polyfunctional compound containing >=3 coupling groups and >=1 electrophilic modifying group is such that (i) the polymer has mol. wt. distribution (Mw/Mn) 1.0-2.1, Mw >=50,000, Tg -100 to -10[deg]C, a vinyl group content 5-90% (based on diene units and coupling number >=2 and (ii) the amount of electrophilic modifying groups based on the amount of the alkali-terminated polymer anion intermediate used to prepare the product is 3-33 mol.%. An independent claim is also included for the preparation of the coupled and modified polymer.

16. 发明专利

CA2444713A1 MODIFIED POLYMERS WITH A HIGH PROPORTION OF CIS-POSITION DOUBLE BONDS, METHOD FOR THE PRODUCTION AND USE THEREOF 未知
公开(公告)号：CA2444713A1
公开(公告)日：2002-10-31
申请号：CA2444713
申请日：2002-04-11
申请人： BAYER AG
发明人： BRAUBACH WILFRIED , KNAUF THOMAS , GRUEN MICHAEL
IPC分类号： B60C1/00 , C08C19/00 , C08C19/26 , C08C19/42 , C08F36/00 , C08F36/04 , C08J5/00 , C08F2/06 , C08F36/06 , C08F12/08 , C08F4/44
摘要： The invention relates to polymers which are modified along a polymer chain o n the basis of conjugated dienes or conjugated dienes and vinyl aromatic compounds having a proportion of vinyl aromatic compounds of up to 60 wt. %, a proportion of cis-position double bonds of >= 92 %, an average molecular weight of between 50 000 - 1 500 000 g/mol and a gel content of

17. 发明专利

BR0105079A 未知
公开(公告)号：BR0105079A
公开(公告)日：2002-06-25
申请号：BR0105079
申请日：2001-11-08
申请人： BAYER AG
发明人： GRUEN MICHAEL , KNAUF THOMAS , BRAUBACH WILFRIED
IPC分类号： C08F4/54 , C08F2/38 , C08F4/00 , C08F36/00 , C08F36/04 , C08F297/04 , C08K5/06 , C08F2/60
摘要： Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers (I). Modifiers for the anionic polymerization of conjugated dienes, or of conjugated dienes and vinylaromatic compounds, comprise amino ethers of formula (I): R , R = 1-10C alkyl, 5-8C cycloalkyl, 6-10C aryl or 7-15C aralkyl; X = (CH2)pNR R ; R , R = groups as defined for R and R ; and m, n = 1-6.

18. 发明专利

DE10057508A1 Rubber mixture for production of low-damping tires or tire tread, based on a polyether-diolefin block copolymer in which the polyether component is incorporated into the polymer chain 未知
公开(公告)号：DE10057508A1
公开(公告)日：2002-05-23
申请号：DE10057508
申请日：2000-11-21
申请人： BAYER AG
发明人： SCHOLL THOMAS , OBRECHT WERNER , BRAUBACH WILFRIED , GIEBELER ELLEN , GRUEN MICHAEL , MUELLER AXEL , GRAF MABEL
IPC分类号： B60C1/00 , C08C19/44 , C08F2/00 , C08G65/337 , C08G81/02 , C08K3/00 , C08L15/00 , C08L71/02 , C08L9/06 , C08C19/34
摘要： Polyether/diolefin rubbers in which the polyether is incorporated into the polymer chain. Rubber mixtures (I) based on polyether/diolefin rubber, containing 49.99-99.99 wt.% polymerized diolefin, 0-50 wt.% vinylaromatic compounds and 0.01-5 wt.% polyether which is incorporated into the polymer chain (total 100 wt.%), plus 10-500 parts by weight (pts. wt.) filler to 100 pts. wt. rubber. An Independent claim is also included for polyether/diolefin rubbers used in (I), obtained by reacting a living polymer anion (made by polymerization of diolefin(s) and optionally vinylaromatic compounds using an anionic initiator) at -100 to +150 deg C with a reactive polyether of formula (II). A = 1- to 4-valent 1-24C alkyl residue, a 1- to 3-valent 6-24C aryl residue or a 1- to 3-valent 7-24C alkylaryl residue; R , R = H, methyl, ethyl, propyl or butyl; X = halogen, 1-24C alkoxy, 6-24C aryloxy or 7-24C alkylaryloxy, with the proviso that at least one group X is halogen; m = 4-30; and q = 1-4.

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