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11. 发明专利

CA735510A PRODUCTION OF 1,5-CYCLO-OCTADIENE FROM BUTADIENE 未知
公开(公告)号：CA735510A
公开(公告)日：1966-05-31
申请号：CA735510D
申请人： BASF AG
发明人： MEIER FRITZ , SEIBT HUBERTUS , KUTEPOW NIKOLAUS VON

12. 发明专利

CA721811A PROCESS FOR THE PRODUCTION OF POLYMERS OF .alpha.-OLEFINES 未知
公开(公告)号：CA721811A
公开(公告)日：1965-11-16
申请号：CA721811D
申请人： BASF AG
发明人： HOFMANN HERMANN P , KASTNING ERNST-GUENTHER , KUTEPOW NIKOLAUS VON , REIS HERMANN , BERDING CHRISTOPH , NAARMANN HERBERT

13. 发明专利

GB1009017A Production of oligomers of butadiene (1,3) 未知
公开(公告)号：GB1009017A
公开(公告)日：1965-11-03
申请号：GB3142462
申请日：1962-08-16
申请人： BASF AG
发明人： WITTENBERG DIETMAR , LAUTENSCHLAGER HANS , KUTEPOW NIKOLAUS VON , MEIER FRITZ , SEIBT HUBERTUS
IPC分类号： C07C2/46 , C07C2/52 , C07F9/02 , C07F9/145 , C07F9/6574
摘要： Cyclic olefins are obtained by the polymerization of butadiene in the presence of a catalyst prepared from (a) a compound of iron, cobalt or nickel; (b) a hydride or organo-compound of an element of Group Ia, IIa, IIb or IIIa (i.e. non-transitional elements of Group III) and (c) a phosphite having an aryl radical with a substituent ortho to the phosphite group or a condensed 6-membered ring ortho and meta to the phosphite group. The constituent (a) is preferably an inorganic or organic salt or a chelate compound of nickel or cobalt. The ortho substituent in the aryl phosphite, which may be derived from benzene, naphthalene or diphenyl, may be an alkyl, alkoxy, halogen or aryloxy or together with the aryl group may form a fused, six-membered, carbocyclic ring. The other two phosphite substituents may be the same or different. The mol ratio of (a) : (b) : (c) may be 1 : 0.5-20: 1-4, the amount by weight of (a) being 0.001-0.1 times that of butadiene. A hydrocarbon or ether solvent, including reaction products, may be present and the temperature may be 0-250 DEG C. with sufficient pressure to maintain liquid phase. Octadiene-1,5 is the principal product. Specification 917,103 is referred to.

14. 发明专利

FR1406194A 未知
公开(公告)号：FR1406194A
公开(公告)日：1965-07-16
申请号：FR984718
申请日：1964-08-10
申请人： BASF AG
发明人： KUTEPOW NIKOLAUS VON , BITTLER KNUT , NEUBAUER DIETER
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07C51/14

15. 发明专利

FR1364933A 未知
公开(公告)号：FR1364933A
公开(公告)日：1964-06-26
申请号：FR943019
申请日：1963-07-29
申请人： BASF AG
发明人： SEIBT HUBERTUS , KUTEPOW NIKOLAUS VON
IPC分类号： C07C2/40

16. 发明专利

GB922374A Production of alcohols 未知
公开(公告)号：GB922374A
公开(公告)日：1963-03-27
申请号：GB820761
申请日：1961-03-07
申请人： BASF AG
发明人： KUTEPOW NIKOLAUS VON , KINDLER HUBERT , EISFELD KARL , DETTKE KARL , JENNE HELMUT , DETZER HANS
摘要： Catalysts used for the reaction between olefines, carbon monoxide and water to produce alcohols comprise an iron carbonyl, preferably iron pentacarbonyl, an amine, preferably a tertiary amine such as N-n-butylpyrrolidine, water and an optionally substituted ether, thioether, nitrile, lactam, carboxylic acid amide, a compound containing a sulphoxide group or two or more of such compounds. The additives are preferably present in an amount of 1-20% by weight based on the total weight of the three components forming the catalyst.ALSO:Alcohols having 3-7 carbon atoms are obtained from olefines having 2-6 carbon atoms, carbon monoxide and water at a temperature of 60-130 DEG C. in the presence of a complex catalyst consisting of iron carbonyl, an amine and water and an optionally substituted ether, thioether, nitrile, lactam, carboxylic acid amide, a compound containing a sulphoxide group or two or more of such compounds. The amine is preferably a tertiary one, e.g. N-n-butyl pyrrolidine. Among suitable additives specified are those of formula R1XR2, in which X is oxygen or sulphur and R1 and R2 are aliphatic, cycloaliphatic, araliphatic or aromatic radicals containing 1-12 carbon atoms substituted, for example, by esterified carboxylic groups, etherified hydroxy groups, esterified hydroxy groups, carboxylic groups, hydroxy groups and nitrile groups, and compounds of formula R3COYR4, in which Y is oxygen or a group NR5 in which R5 is hydrogen, an aliphatic, cycloaliphatic, araliphatic or aromatic radical both hetero atoms being members of a heterocyclic ring having 5-13 atoms as ring members and R3 and R4 together represent a polymethylene radical with 3-11 carbon atoms which together with -CO-Y- form a heterocyclic ring having 5-13 ring members. Suitable compounds of formula R3COYR4 are, for example, pyrrolidone, caprolactam, caprylic lactam, lauric lactam, N-methylpyrrolidone, and N-butylcaprolactam. Other suitable additives are N-mono- and N-disubstituted carbonamides, e.g. dimethyl and diethyl formamide, N.N-dimethyl acetamide, N.N-diethylbutyramide and benzoic and dimethyl amide. The additives are usually present in an amount of 1-20% by weight based on the total of the three components forming the catalyst and may be added during or after the formation of the catalyst. In the examples propylene is reacted with carbon monoxide and water in the presence of a catalyst comprising iron pentacarbonyl, N-butyl pyrrolidine and various additives as specified above to give a mixture of butanols. Specification 704,136 is referred to.

17. 发明专利

FR1266980A 未知
公开(公告)号：FR1266980A
公开(公告)日：1961-07-17
申请号：FR838098
申请日：1960-09-08
申请人： BASF AG
发明人： HIMMELE WALTER , KUTEPOW NIKOLAUS VON
IPC分类号： C07C51/12

18. 发明专利

CA850153A PRODUCTION OF PROPARGYL ALCOHOL 未知
公开(公告)号：CA850153A
公开(公告)日：1970-08-25
申请号：CA850153D
申请人： BASF AG
发明人： NEUBAUER DIETER , KUTEPOW NIKOLAUS VON

19. 发明专利

GB1137163A Production of carboxylic acids 未知
公开(公告)号：GB1137163A
公开(公告)日：1968-12-18
申请号：GB1655966
申请日：1966-04-15
申请人： BASF AG
发明人： KUTEPOW NIKOLAUS VON , BITTLER KNUT , MEIER FRITZ , NEUBAUER DIETER
IPC分类号： C07C51/145
摘要： 1,137,163. Carboxylic acids. BADISCHE ANILIN- & SODA-FABRIK A.G. 15 April, 1966 [17 April, 1965], No. 16559/66. Heading C2C. Carboxylic acids are prepared from olefinically unsaturated compounds, carbon monoxide, and water at elevated temperature in the presence of palladium and/or a palladium compound and an oxidizing agent with an oxidation potential of more than 0À1 volt, at from 30‹ to 210‹ C. Unsaturated compounds may be ethylene, vinyl chloride, propene, butene-(2), hexene-(3), dodecene-(1), 2-ethylhexene-(1), propenylbenzene, vinylcyclohexene-(3), cyclohexene, cyclooctene, cyclododecene, butadiene-(1,3), isoprene, piperylene, cyclooctadiene-(1,5), octatriene- (2,4,6), methylheptatriene, cycloheptatriene- (1,3,5), cyclododecatriene - (1,5,9), 1 - chlorocyclododecadiene - (5,9), cyclooctatetraene, ethyl acrylate, acrylonitrile, acrylamide, allyl alcohol, allyl chloride, oleic acid, ricinoleic acid, undecylenic acid, methyl allyl ether, cyclohexadienes and acrolein. The oxidizing agent may be iodine, peroxides, persulphates, lead dioxide, manganese dioxide, copper (II) chloride, potassium permanganate, potassium dichromate, benzoquinone, oxygen, or the oxidation may be by electro-chemical means with an anode at the appropriate potential. Examples describe the preparation of propionic acid, cyclododecadiene- (5,9)-monocarboxylic acid-(1) which may be hydrogenated to cyclododecane monocarboxylic acid, and butene-(2) carboxylic acid-(1).

20. 发明专利

CA773587A CARBONYLATION OF OLEFINICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS 未知
公开(公告)号：CA773587A
公开(公告)日：1967-12-12
申请号：CA773587D
申请人： BASF AG
发明人： REIS HERMANN , NEUBAUER DIETER , KUTEPOW NIKOLAUS VON , BITTLER KNUT

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